editorial dyes and pigments

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Editorial Since the on-line submission system for Dyes and Pigments came into operation almost two years ago, of those papers that were reviewed and for which a decision made, a little over 60% con- cerned dye removal (via adsorption/degradation) and associated sorbent synthesis and preparation. This very high proportion of sub- mitted dye removal articles clearly reflects the importance of dye removal as a subject of study; that such papers were received from authors around the globe also shows that dye removal re- search is truly of worldwide interest. However, of this very large number of submitted dye removal manuscripts, an alarmingly high proportion were deemed unacceptable for publication. In- deed, in terms of the breakdown between accepted and rejected papers, of the above mentioned papers for which a decision was made and which concerned dye removal, only 8% were accepted and 92% were rejected. This rejection rate is considerably higher than that enjoyed by the other subject areas covered in the journal (e.g. dye synthesis, pigments and intermediates, their physical or chemical properties, etc.). Although the rejection of manuscripts is, unfortunately, both necessary and unavoidable for any peer-reviewed publication, the very high proportion of these dye removal manuscripts being rejected warrants attention. The situation is further exacerbated by the fact that the trend towards a high submission of dye removal papers seems set to continue, insofar as of the submitted papers currently under review, some 60% concern dye removal. Having read all submitted papers as well as all reviewers’ com- ments, it is clear that the rejected dye removal manuscripts have several common features and are remarkably similar in their pre- sentation and organisation. Typical, commonly repeated reviewers’ comments include the observations that: many authors are not familiar with dye usage, dye classification and the concept of C.I. Generic Name; a reasoned argument was not put forward as to why a particular dye was selected for study; old, commercially unimportant (commonly cationic) dyes have been selected for study; authors do not recognise that real dye wastewater is often a complex mixture of dyes, proprietary dyeing additives, elec- trolytes, etc. and that the use of an aqueous (often distilled wa- ter) solution of one dye does not mimic the conditions likely to be encountered in real waste water; many authors do not realise that as many commercial dyes are mixtures of dyes and diluents, multi-solute adsorption may arise; whilst optimum conditions for adsorbent preparation are claimed, these often are far from optimised; although traditional sorbent characterisation techniques are used, the characterisation results are not related to sorbent performance; adsorption experiments invariably record the effect of pH, ad- sorbent concentration, temperature, contact time, etc.; equilibrium data have been correlated only with conventional isotherm expressions (Freundlich and Langmuir, with a few others); kinetic data have been analysed along conventional lines; the results obtained using one dye on one adsorbent do not con- stitute a mechanism that is applicable to all similar types of dye on similar types of adsorbent; The reason for writing this editorial is not to discourage people from carrying out dye removal studies and submitting their results to Dyes and Pigments for publication; indeed, because of its intrinsic environmental and economic importance, dye removal is of significant importance and I look forward to receiving well-prepared manuscripts on this subject. However, I wanted to bring to the attention of readers of the Journal and especially to individuals engaged in dye removal studies, the reasons for the comparatively low number of published papers that concern dye removal. Contents lists available at ScienceDirect Dyes and Pigments journal homepage: www.elsevier.com/locate/dyepig 0143-7208/$ – see front matter Ó 2008 Published by Elsevier Ltd. doi:10.1016/j.dyepig.2008.04.002 Dyes and Pigments 79 (2008) iii

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Editorial

Since the on-line submission system for Dyes and Pigmentscame into operation almost two years ago, of those papers thatwere reviewed and for which a decision made, a little over 60% con-cerned dye removal (via adsorption/degradation) and associatedsorbent synthesis and preparation. This very high proportion of sub-mitted dye removal articles clearly reflects the importance of dyeremoval as a subject of study; that such papers were receivedfrom authors around the globe also shows that dye removal re-search is truly of worldwide interest. However, of this very largenumber of submitted dye removal manuscripts, an alarminglyhigh proportion were deemed unacceptable for publication. In-deed, in terms of the breakdown between accepted and rejectedpapers, of the above mentioned papers for which a decision wasmade and which concerned dye removal, only 8% were acceptedand 92% were rejected. This rejection rate is considerably higherthan that enjoyed by the other subject areas covered in the journal(e.g. dye synthesis, pigments and intermediates, their physical orchemical properties, etc.).

Although the rejection of manuscripts is, unfortunately, bothnecessary and unavoidable for any peer-reviewed publication, thevery high proportion of these dye removal manuscripts beingrejected warrants attention. The situation is further exacerbatedby the fact that the trend towards a high submission of dye removalpapers seems set to continue, insofar as of the submitted paperscurrently under review, some 60% concern dye removal.

Having read all submitted papers as well as all reviewers’ com-ments, it is clear that the rejected dye removal manuscripts haveseveral common features and are remarkably similar in their pre-sentation and organisation. Typical, commonly repeated reviewers’comments include the observations that:

� many authors are not familiar with dye usage, dye classificationand the concept of C.I. Generic Name;

� a reasoned argument was not put forward as to why a particulardye was selected for study;

� old, commercially unimportant (commonly cationic) dyes havebeen selected for study;

� authors do not recognise that real dye wastewater is oftena complex mixture of dyes, proprietary dyeing additives, elec-trolytes, etc. and that the use of an aqueous (often distilled wa-ter) solution of one dye does not mimic the conditions likely tobe encountered in real waste water;

� many authors do not realise that as many commercial dyes aremixtures of dyes and diluents, multi-solute adsorption mayarise;

� whilst optimum conditions for adsorbent preparation areclaimed, these often are far from optimised;

� although traditional sorbent characterisation techniques areused, the characterisation results are not related to sorbentperformance;

� adsorption experiments invariably record the effect of pH, ad-sorbent concentration, temperature, contact time, etc.;

� equilibrium data have been correlated only with conventionalisotherm expressions (Freundlich and Langmuir, with a fewothers);

� kinetic data have been analysed along conventional lines;� the results obtained using one dye on one adsorbent do not con-

stitute a mechanism that is applicable to all similar types of dyeon similar types of adsorbent;

The reason for writing this editorial is not to discouragepeople from carrying out dye removal studies and submittingtheir results to Dyes and Pigments for publication; indeed, becauseof its intrinsic environmental and economic importance, dyeremoval is of significant importance and I look forward to receivingwell-prepared manuscripts on this subject. However, I wanted tobring to the attention of readers of the Journal and especially toindividuals engaged in dye removal studies, the reasons for thecomparatively low number of published papers that concern dyeremoval.

Contents lists available at ScienceDirect

Dyes and Pigments

journal homepage: www.elsevier .com/locate/dyepig

0143-7208/$ – see front matter � 2008 Published by Elsevier Ltd.doi:10.1016/j.dyepig.2008.04.002

Dyes and Pigments 79 (2008) iii