Transcript
Page 1: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

The Quantum Atom

Weirder and Weirder

Page 2: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Wave-Particle Duality

Louis de Broglie (1892-1987)

Page 3: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Wave-Particle Duality

Louis de Broglie (1892-1987) De Broglie Hypothesis: Any moving particle

has an associated wave nature (1924). E

k=hf true for electrons and all matter

Page 4: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Wave-Particle Duality

De Broglie Hypothesis: Any moving particle has an associated wave nature (1924).

Ek=hf true for electrons and all matter

This means that light is not the only weird thing, all matter is weird

De Broglie's Hypothesis tested in 1927 by Cliffton Davisson and Lester Germer of Bell Laboratories. They document electron diffraction

Page 5: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Nobel Prize

De Broglie won in 1929 for his work

Davisson and Germer won in 1937 for their work

Page 6: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

The Impact

De Broglie's hypothesis meant it was possible to predict the behavior of matter (including subatomic particles) using wave equations

Page 7: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

The Impact

De Broglie's hypothesis meant it was possible to predict the behavior of matter (including subatomic particles) using wave equations

This idea was crucial for the development of quantum mechanics

Page 8: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Werner Heisenberg

Electrons interact with photons because they have similar wavelengths.

Page 9: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Werner Heisenberg

Electrons interact with photons because they have similar wavelengths.

Photons are used to detect electrons

Page 10: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Werner Heisenberg

Electrons interact with photons because they have similar wavelengths.

Photons are used to detect electrons Because of the relationship, any attempt to find

the velocity and position of an electron causes those quantities to change (the Heisenberg uncertainty principle)

Page 11: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Werner Heisenberg

Electrons interact with photons because they have similar wavelengths.

Photons are used to detect electrons Because of the relationship, any attempt to find

the velocity and position of an electron causes those quantities to change (the Heisenberg uncertainty principle)

Nobel prize in Physics 1932

Page 12: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Erwin Schrödinger

1926 used the dual particle-wave nature to develop wave equations that predicted where electrons were

Page 13: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Erwin Schrödinger

1926 used the dual particle-wave nature to develop wave equations that predicted where electrons were

Only waves of specific energies (particular frequencies) fit the equation—this corresponds to the energy levels that Bohr proposed

Page 14: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Erwin Schrödinger

1926 used the dual particle-wave nature to develop wave equations that predicted where electrons were

Only waves of specific energies (particular frequencies) fit the equation—this corresponds to the energy levels that Bohr proposed

Nobel prize in Physics 1933

Page 15: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Quantum Mechanics

Based on the work of de Broglie, Heisenberg, Schrödinger, Born, Einstein and others

Page 16: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Quantum Mechanics

Based on the work of de Broglie, Heisenberg, Schrödinger, Born, Einstein and others

All matter behaves with both particle and wave nature

Page 17: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Quantum Mechanics

Based on the work of de Broglie, Heisenberg, Schrödinger, Born, Einstein and others

All matter behaves with both particle and wave nature

The smaller a particle is, the more closely its behavior approaches a wave

Page 18: The Quantum Atom Weirder and Weirder. Wave-Particle Duality Louis de Broglie (1892-1987)

Quantum Mechanics

Based on the work of de Broglie, Heisenberg, Schrödinger, Born, Einstein and others

All matter behaves with both particle and wave nature

The smaller a particle is, the more closely its behavior approaches a wave

Quantum wave equations give probability of finding an electron in a particular energy level (orbital)


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