1998 organo-tin compounds

organo-tin compoundsS 4800

23 - 181Organophosphorus Compounds. Part 125. Hydrostannylation ofPhosphaalkynes. — The hydrostannylation of phosphaalkynes (II) affords1,2-dihydro-1,3-diphosphetes (III) or phosphanes, such as (IV), depending onthe stoichiometry employed. The compounds (III) react with W or Fe carbonylsto complexes of one or both P atoms. — (SCHMITZ, M.; GOELLER,R.; BERGSTRAESSER, U.; LEININGER, S.; REGITZ, M.; Eur. J. Inorg.Chem. (1998) 2, 227-235; Fachbereich Chem., Univ. Kaiserslautern, D-67663Kaiserslautern, Germany; EN)

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