2008

Organo-phosphorus compoundsS 0080 Mild Synthesis of Organophosphorus Compounds: Reaction of Phosphorus-Con-

taining Carbenoids with Organoboranes. — The reaction of various organoboranes with phosphorus-containing carbenoids proceeds smoothly under mild conditions and, in the case of unsymmetrically substituted boranes, with good chemoselectivity. The phosphonite—borane complexes (III) can be used as synthons for phosphinic esters (IV) and (VI). — (ANTCZAK, M. I.; MONTCHAMP*, J.-L.; Org. Lett. 10 (2008) 5, 977-980; Dep. Chem., Tex. Christian Univ., Fort Worth, TX 76129, USA; Eng.) — Mischke

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2008