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Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS AFTER INCORPORATION OF VEGETABLE CROP RESIDUES: A FIELD STUDY Georges Hofman Barbara Chaves Stefaan De Neve Pascal Boeckx Oswald Van Cleemput

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Page 1: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Department of Soil Management and Soil CareDepartment of Applied Analytical and Physical Chemistry

INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

AFTER INCORPORATION OF VEGETABLE CROP RESIDUES: A

FIELD STUDY

Georges Hofman Barbara Chaves Stefaan

De NevePascal Boeckx Oswald Van

Cleemput

Page 2: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Outline

Introduction Materials and methods Results Discussion Conclusion

Page 3: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Introduction

The Netherlands

The Walloon Region

Problems with NOProblems with NO33---N leaching-N leaching

= Vegetable region= Vegetable region

Page 4: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Introduction

Crop Crop residues

Large amounts crop residues (up to 60 t fresh material ha-1) High N content (2 - 4% N on dry matter) Large and fast N release from crop residue (up to 150 kg N ha-1) High risk of NO3

- leaching

Page 5: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Objective

Can nitrification inhibitors (DCD and

DMPP) reduce nitrification and NO3-

leaching after incorporation of vegetable

crop residues?

Page 6: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Materials and methods

Block 3

Block 2

Block 1

Randomised block design with 3 replicatesRandomised block design with 3 replicatesSilt loamSilt loam

Cauliflower residuesCauliflower residues~ 452 kg N ha~ 452 kg N ha-1 -1 sandy loamsandy loam

DMPP ~ 1,9 kg a.c. haDMPP ~ 1,9 kg a.c. ha-1-1

DCD ~ 19 kg a.c. haDCD ~ 19 kg a.c. ha-1-1

Cauliflower

SoilCauliflower + DCD

Cauliflower + DMPP

Page 7: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Materials and methods

6 sampling dates • with an auger • to a depth of 90 cm in 3 layers: 0-30 cm, 30-60 cm, 60-90 cm

Mineral N • extraction with (1N) KCl• continuous flow autoanalyser

Page 8: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

NH4+-N and NO3

--N

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0tim e (d ay s)

-2 0

0

2 0

4 0

6 0

8 0

1 0 0

1 2 0

1 4 0

1 6 0

NH

4+ c

onte

nt (

kg N

ha-

1 )

u n am en d ed so ilcau lif lo w er o n lyD C DD M P P

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0tim e (d ay s)

0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

9 0

1 0 0

NO

3- co

nten

t (kg

N h

a-1 )

u n am en d ed so ilcau lif lo w er o n lyD C DD M P P

Page 9: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Mineral N

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0tim e (d ay s)

0

1 0

2 0

3 0

4 0

5 0

6 0

7 0

8 0

min

eral

N (

kg N

ha-

1 )

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0tim e (d ay s)

0

2 0

4 0

6 0

8 0

1 0 0

1 2 0

1 4 0

1 6 0

1 8 0

2 0 0

min

eral

N (

kg N

ha-

1 )

u n am en d ed so ilcau lif lo w er o n lyD C DD M P P

0 2 0 4 0 6 0 8 0 1 0 0 1 2 0 1 4 0 1 6 0 1 8 0 2 0 0tim e (d ay s)

5

1 0

1 5

2 0

2 5

3 0

3 5

4 0

4 5

min

eral

N (

kg N

ha-

1 )

Page 10: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Discussion

0-30 cmMineral N in DCD > mineral N in cauliflower only

N release from DCD itself (67% N = 13 kg N ha-1)

priming effect induced by DCD (Gioacchini et al., 2002;

Chaves et al., 2006 )

30-60 cm and 60-90 cmMineral N in DMPP < mineral N in cauliflower only and DCD

Only DMPP reduced NO3- leaching

Page 11: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Conclusions

DMPP and DCD

Increased NH4--N in top 30 cm

Reduced NO3--N in top 30 cm

DMPP

Reduced NO3--N in 30-90 cm layer

DMPP can reduce NO3- leaching

DCD

Increased mineral N in 0-30 cm layer (N release from

DCD and priming effect)

No reduction in NO3- leaching

Page 12: Department of Soil Management and Soil Care Department of Applied Analytical and Physical Chemistry INFLUENCE OF NITRIFICATION INHIBITORS ON SOIL N DYNAMICS

Thank you for your attention!!