DEMOCRITUS DALTONTHOMSONRUTHERFORDBOHRDeBROGLIE

The Greeks - Democritus• 450 B.C.• Believes there is a

fundamental particle that cannot be broken. ( won’t subdivide to smaller components)

• The particle is invisible / indivisible

• Coins the term “atomos”

John Dalton• 1810• Believes atoms are invisible

and indivisible.• All atoms of the same element

are alike in every respect –especially mass.

• Atoms of different elements are different in every respect – especially mass.

• -- combine in whole number ratios

• --Billiard Ball Theory

Early symbols representingcompounds in various simpleratios. Dalton

J.J. Thomson• 1897• An atom consists of a positively charged globule.• Negative particles, called electrons, are embedded in the

globule.• These electrons move about in the globule.• Jellied salad or raisin bun theory.

(Cathode Ray Tube)

electrons

Positive mass

JJ Thomson’s model of the atom

Positive charged mass with embedded electron particles

RUTHERFORD EXPT

Ernest Rutherford / Nuclear model

• 1908• Performs his famous scattering experiment

HYPOTHETICAL

Observations

- Most alpha particles pass through the foil as if there

was nothing there

- A few veer off as they are slightly deflected

- A very few bounce back at the alpha gun

Conclusions

- Atoms are mainly empty space (over 99.9 %)

-The mass of the atom is concentrated in a core or

nucleus which is positively charged.

- Electrons, which are negative move about in a large

region of space outside the nucleus

Rutherford ModelNegative Electron

Positive Nucleus

Quantum Mechanical Model OR the Nuclear Atom

1. Atoms have a very dense core called the nucleus.The nucleus contains two sub-atomic particles:

A) Protons which have a positive charge

B) Neutrons which do not carry a charge (neutral)

2. The electrons, which carry a negative charge, are in a state of constant motion in a relatively large region of space away from the nucleus.

3. Atoms are mainly empty space. (over 99.9 %)

I. General Information

NUCLEAR MODEL

RUTHERFORD- DISCOVERED NUCLEUS-POSITIVE CHARGED PROTON-ELECTRONS ORBIT OUTSIDE

Described as - - SOLAR MODEL

Neils Bohr

Energy LevelsElectrons are locatedat different energy levels due to energy of the electrons

Orbitals s p d fs – 2 electronsp – 6 electronsd – 10 electronsF – 14 electronsQuantum model

[ Electron configuration ]

Neils Bohr

ENERGY LEVELS - 7 Levels for 7 periods

Electron orbits / electron configuration

s p d f orbits / electron location

ELECTRON LOCATION

• Electrons are located in specific energy levels• These energy levels can be thought of as globe shaped

regions of space surrounding the nucleus.• Electrons in the inner level have the lowest amount of

energy and energy increases as the levels move outward.

• Electrons enter and fill these levels in order and each level has a limit to how many electrons it can hold.

• Level 1 holds 2 electrons• Level 2 holds 8 electrons• Level 3 holds 8 electrons• Level 4 holds 18 electrons• Level 5 hold 18 electrons• Level 6 holds 32 electrons• Level 7 holds 32 electrons

Shows the 3 orbitals and how they overlap

DUST CLOUD MODEL

De Broglie - Model

Probability of finding electrons atdifferent levels

Electrons are particles / bundles of Energy.

Dual principle theory – wave mechanics / particle theory

PROBABILITY OF ELECTRON LOCATION (DOTS)

II. Summary of Atomic Particles

Particle Symbol Relative

Mass

Relative

charge

Location

Proton

neutron

electron

Hor p+

n e

or n

or e-1

1

1

0

+1

0

-1

Nucleus

NucleusConstant motion outside nucleus

Relative => means with respect to each other

About 1864 ( 2000) electrons = 1 proton

III. Atomic Number

• This is used to identify the element(name and/or symbol)• This number ALWAYS tells us the how many protons are

in the nucleus of atoms of that element.

• NO EXCEPTIONS

• Examples: Carbon atoms (atomic # of 6) => 6 protons Sodium atoms ( atomic # 11 ) => 11 protons Osmium atoms ( ? ) => ? Protons ?????? Atoms (atomic # 47) => 47 protons

IV. Nuclear Charge

• This is the total positive charge present on the nucleus.

• It is always positive because the protons are the only charged particle in the nucleus.

• Therefore, the nuclear charge is equal to the number of protons in the atom or ion. (equal to the atomic number)

• Examples:

The nuclear charge on K is + 19

The nuclear charge on Ni + 28

V. ATOMIC MASS

• The mass number is the total mass in grams for a constant and specific number of atoms of each element.

• This number is very large (because atoms are very small) and is known as the mole number.

• 1.0 mole is equal to 6.02 x 1023 particles.

Examples:

The mass of one mole of Hydrogen atoms is 1.01 g. Therefore 1.01 g/mol is the mass number for Hydrogen.

ATOMIC MASS OF Zr 91.22 g / mol

MASS NUMBER - ATOMIC MASS ROUNDED TO A WHOLE NUMBER.

ATOMIC MASS ROUNDED MASS NUMBER

CARBON - ATOMIC MASS OF 12.01 => 12 amu

SILVER - ATOMIC MASS OF 107.87 => 108 amu

ANTIMONY - ATOMIC MASS OF 121.75 => 122 amu

THE NUMBER OF NEUTRONS IS CALCULATED AS:

MASS NUMBER - ATOMIC NUMBER = NEUTRONS

VI. Number of Neutrons• Since only protons and neutrons contribute to the mass

of an atom, the sum of these two particles must be equal to the mass number.

• To calculate the number of neutrons in a given atom:

MASS NUMBER – # OF PROTONS = # OF NEUTRONS

Examples:How many neutrons are in each of the following?

1. A carbon atom?

12 – 6 = 6

2. A zinc atom?

65 – 30 = 35

3. 44.96 Sc 21 Scandium has 45 – 21 = 24 neutrons

Hydrogen 1 Hydrogen 2 Hydrogen 3

VII. ISOTOPES

11H

Isotopes - 2 or more atoms of the same element that have (same atomic number and same number of protons)

Different number of neutrons ===> Different mass

All atoms of the same element are not identical.

31H

21H

1 proton0 neutrons

1 proton1 neutron

1 proton2 neutrons

Occur naturally Man-made / synthetic

Protium Deuterium Tritium

A carbon isotope has 8 neutrons. What is its mass number?

Answer: 14

An isotope of zinc has a mass number of 62. How many neutrons does it have?

Answer: 32

A given isotope has a mass number of 52 and contains 26 neutrons. What element is it?

Answer: Iron (Fe)

Please do these in your NOTE BOOK !!

VIII. WRITING ISOTOPES

AZ X

2 methods to represent the different isotopes of an element

1.) X(Y) where ‘X’ is the element symbol and ‘Y’ is the mass number of that particular isotope.

Examples: H(1) H(2) H(3)

C(12) C(14) U(238) Zn(64)

2.) where ‘X’ is the element symbol, ‘A’ is the mass number of the isotope and ‘Z’ is the atomic number

Examples: 14 65 238 906 30 92 38, , , .C Zn U Sr etc

IX. CALCULATING AVERAGE MASS• An example: A theoretical element• Element J has 4 known isotopes. Their mass distribution

in nature is as follows:

1) J(40) = 30.0%

2) J(43) = 40.0% ( largest % in nature)

3) J(44) = 10.0% ( smallest % in nature)

4) J(50) = 20.0%

Calculate the average mass of this element ( J )

Take the % of each mass and add the results together to get a total.

Each Isotope may occur in different % in nature

30/100 x 40g = 12.0 g

40/100 x 43g = 17.2 g

10/100 x 44g = 4.4g

20/100 x 50.0g = 10.0g

43.6 g

The average mass of element J is 43.6 g / mol

Remember – the total percent of any element must be 100%. If you are given numbers like 20% and 40% for 2 of the 3 isotopes… 100 – ( 20 + 50) = 30 % for the third isotope.

IMPORTANT****when completing tables and answering

questions on atomic theory,ALWAYS USE THE GIVEN DATA FROM THE

QUESTION.The values from the periodic table are used if

no other information is available.

X. NUMBER OF ELECTRONS

• In any neutral element , the number of electrons is equal to the number of protons. (equal to the atomic number)

• That is: [ p + = e - ]

XI. IONS

Species where the number of protons is NOT equal to the number of electrons.

That is: [ p+ = e - ]

These are charged particles known as ions

Type: II

It is also possible to remove one or more electrons from an atom or ion. This will result in the formation of a positive ion.

Na + energy →

Energy must be supplied in order to remove each electron.

Na+ + e-

Al + energy → Al 3+ + 3e-

This kind of reaction is known as an OXIDATION reaction

Mg + energy → Mg 2+ + 2e-

OIL <-> RIG

REACTANTS PRODUCTS

**All ions are formed by the addition or removal of electrons. NEVER CHANGE THE NUMBER OF PROTONS.**

Type I:

It is possible for an atom to gain one or more electrons. This results in the formation of a negative ion.

Examples:

F + e- → F- + energy

S + 2e- → S2- + energy

N + 3e- → N3- + energy

Energy is released as each electron is accepted.

This kind of reaction is known as a REDUCTION reaction.

To help remember oxidation and reduction !! (1 WAY)

OIL RIG

OXIDATION IS LOSS

OF ELECTRONS

REDUCTION IS GAIN

OF ELECTRONS

My name is

LEO the lion says GER

2 ND WAY

Oxidation - ReductionLeft side is reactants Right side is products

Na becomes what type of ion ? ( + or - ) Na +

That indicates that it lost electrons….which are the products

Losing electrons means gaining Energy Energy is a reactant

Na + Energy == > Na + + 1 e -

Sodium plus energy == > sodium ion and 1 electron

Predicting Ion Formation

• Stability in ions is represented by the total number of electrons present.

• The stable numbers are those found in atoms of the inert gases. (2, 10, 18, 36, 54, 86) These are unreactive – that is they are stable.

• All other atoms will gain (become reduced) or lose (undergo oxidation) in order to achieve one of these numbers.

Predict the ion that each of the following atoms would form in order to become stable. Write out the oxidation or reduction reaction.

• K• Cl• O• P• Ca• Ga• Cs• N• Br

ANSWERS

K + energy → K+ + e-

Cl + e- → Cl- + energyO + 2e- → O2- + energyP + 3e- → P3- + energyCa + energy → Ca2+ + 2e-

Ga + energy → Ga3+ + 3e-

Cs + energy → Cs+ + e-N + 3e- → N3- + energyBr + e- → Br- + energy

Dmitri Mendeleyev given credit for the first working

periodic table

1. The periodic table is arranged in horizontal rows and vertical columns.

2. Each horizontal row is called a PERIOD or SERIES.

3. Each vertical column is known as a GROUP or FAMILY. ( same chemical characteristics)

Label the following on your blank table:- Families (show numbers & Roman numerals)- Periods (show number of each period)- Alkali metals ------ - -- - - ( group 1A )- Alkali earth metals - - - - ( group 2A)- Transition elements - - - - ( group B )- Halogens ------ -- -- -- -- -- - - - (group 7A )- Inert gases (noble gases)- - (group 8A )

VALENCE ELECTRONS

• All of the electrons located in the outermost (highest) energy level are called valence electrons.

• For all ‘A’ elements, the group number equals the number of valence electrons. Group I A to VIII A

• Carbon is in group IVA and therefore has 4 valence electrons.

• All transition (B family) elements have 2 valence electrons.

Metallic Properties

Metallic properties decrease as we move left to right across the table.

Metallic properties increase as we move from top to bottom in the table.

The most metallic element is in the bottom – left of the table and the least metallic element is in the top right.

ATOMIC SIZE

IN ANY FAMILY

As atomic number increases – Atomic size increases

This is due to more energy levels holding electrons. Eg. Cs atoms are larger than Na atoms because Na atoms have electrons in 3 energy levels holding electrons and Cs has 6 energy levels holding electrons

IN ANY PERIODAs atomic number increases – Atomic size decreases

This is due to increased nuclear attraction on electrons in the same energy level. Eg. A Br atom is smaller than a Ca atom. 35 protons pulling on outer electrons vs 20 protons pulling on outer electrons.

THE ELECTRON AFFINITY

ADDITION OF AN ELECTRON TO AN ATOM

ELECTRON ADDED / ENERGY IS LOST

MOVIE 1 MOVIE 2

IONIZATION ENERGYThis is the amount of energy required to remove an electron(s) from an atom or ion. (See formation of a positive ion..)

IN ANY FAMILY

As atomic number increases – ionization energy decreases

This is a function of size. The outermost electrons are further and further from the nucleus and are easier to remove.

IN ANY PERIOD

As atomic number increases – ionization energy increases

This is due to increased nuclear attraction on electrons in the same energy level.

BACKGROUND / Electron Configuration

1] Electrons are located in specific energy levels surrounding the nucleus. These are numbered consecutively from 1 – 7, starting from the nucleus and working outward.

2] Each energy level has a specific maximum capacity for holding electrons.

3] Energy levels can be sub-divided into sub-levels (or sub-shells). These are identified with letters: s, p, d, f…etc.

4] These sub-levels also have maximum capacities.

5] Each sub-level are, in turn, divided into orbitals that hold 2 electrons each.

6] Levels and sub-levels fill systematically with electrons starting from the inside (lowest energy) and working outward (highest energy).

ELECTRON CONFIGURATION• That is: level one completely fills before level 2 starts

filling…level 2 before level 3….etc.

• Note: Not all energy levels contain all sub-levels.

• Capacities: s – 2 electrons – 1 orbital 1 (2electrons)

p – 6 electrons – 3 orbitals 3 (2electrons)

d – 10 electrons – 5 orbitals 5 (2electrons)

f – 14 electrons – 7 orbitals 7 (2electrons)

1s2 / 2s22p6 / 3s23p6 / 4s23d104p6 / 5s24d105p6 / 6s24f145d106p6 / 7s25f146d107p6

1 2 3 4 5 6 7

ENERGY LEVELS

2 8 8 18 18 32 32 Number of electrons in each energy level

Notation

1 s 2 2 s 2 2 p 6 3s 2 3p 6

1 2 3

Energy levels

Prime quantum number/ energy level(refer to period on periodic table)

Orbitals / sublevel

electrons

Writing Electron Configurations / Review

H: 1s1

He: 1s2

Li: 1s2 2s1

Ca: 1s2 2s2 2p6 3s2 3p6 4s2

Ag: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d9

U: 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14

5d10 6p6 7s2 5f4

N:

Na:

Br:

Your turn --- make my day

1s2 2s2 2p3

1s2 2s22p6 3s1

1s2 2s22p6 3s23p6 4s23d104p5

VALENCE ELECTRONS Electrons in the last energy level / max 8

Bonding electrons / octets - only 8

F - 1s2 2s2 2p5 look at the last energy level

F – 1s2 2s2 2p5

Filled up 2 electrons

[ count only the s and p electrons

5 electrons+ = 7

Cl - has 7 valence electrons

Cl - will gain 1 electron to become stable

Cl becomes Cl 1- [ valence of 1- ]

Other Topics

• Last electron added (valence electrons)• How to remember the sequence (two methods)• Grouping quantum numbers• Configurations of ions

Short Cut Version / Noble Gas Method(Only use when instructions allow it)

Write the symbol for the last complete inert gas and then continue the configuration from the next energy level.

Example: Write the Noble Gas configuration for Ra.

Ra: 86Rn – [ 7s2 ]

Using this format, write configurations for:

Au:

Ga:

Cf:

Sc:

54Xe – [ 6s2 4f14 5d9 ]

18Ar – [ 4s2 3d10 4p1 ]

86Rn – [ 7s2 5f10 ]

18Ar – [ 4s2 3d1 ]

Questions for Periodic Table ReviewWhich Element?

• Is an alkali metal?• Is chemically inert?• Is in group IV A?• Is in period 2?• Has the largest mass number?• Is a transition element?• Forms a 3 – ion?• Forms a 2+ ion? • Tends to lose one electron?• Tends to gain 2 electrons?• Is Lithium?• Has a nuclear charge of + 20?• has 2 valence electrons?

• Are chemically similar?• Has the largest radius?• Has the lowest ionization

energy?• Has valence e- in period 3?• Last e- added was d1?• Is the most metallic?• Configuration ends in 4p2?• Has 22 protons in nucleus?• Has e- in 3 energy levels only?