de-broglie or matter wave
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when physicists Lester Germerand Clinton Davisson fired electrons at a crystalline nickeltarget and the resulting diffraction pattern was found to match the predicted values.
[2]In de
Broglie's equation an electron's wavelength is a function ofPlanck's constant (6.6261034
joule-seconds) divided by the object's momentum (nonrelativistically, its mass multiplied by
its velocity). When this momentum is very large (relative to Planck's constant), then anobject's wavelength is very small. This is the case with every-day objects, such as a person;
given the enormous momentum of a person compared with the very tiny Planck constant, thewavelength of a person would be so small (on the order of 1035 nanometer or smaller) as to
be undetectable by any current measurement tools. On the other hand, many small particles(such as typical electrons in everyday materials) have a very low momentum compared to
macroscopic objects. In this case, the de Broglie wavelength may be large enough that the
particle's wave-like nature gives observable effects.
The wave-like behavior of small-momentum particles is analogous to that of light. As an
example, electron microscopes use electrons, instead of light, to see very small objects. Since
electrons typically have more momentum than photons, their de Broglie wavelength will be
smaller, resulting in better spatial resolution.
[edit] The de Broglie relations
The de Broglie equations relate the wavelength and frequency to the momentum andkinetic energy , respectively, as
and
where is Planck's constant. The two equations are also written as
where is the reduced Planck's constant (also known as Dirac's constant,
pronounced "h-bar"), is the angular wavenumber, and is the angular frequency.
Using results from special relativity, the equations can be written as
and
where is the particle's rest mass, is the particle's velocity, is the Lorentz factor, and
is the speed of light in a vacuum.
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See t e arti le on group velocit for detail on t e argument and derivation oft e de Broglierelations. Group velocit (equalto t e particle's speed) should not be confused withphase
velocit (equalto the product ofthe particle's frequency and its wavelength).
[edi E perimental nfirmati n
[edit] Elementary parti les
In 1927 atBell Labs, Clinton Davisson and Lester Germerfired slow-moving electrons at a
crystallinenickeltarget. The angular dependence ofthe reflected electron intensity was
measured, and was determined to have the same diffraction pattern as those predicted by
Bragg forx-rays. Before the acceptance ofthe de Broglie hypothesis, diffraction was aproperty that was thoughtto be only exhibited by waves. Therefore, the presence of any
diffraction effects by matter demonstrated the wave-like nature of matter. When the deBroglie wavelength was inserted into the Bragg condition, the observed diffraction pattern
was predicted, thereby experimentally confirming the de Broglie hypothesis for electrons.
This was a pivotal resultin the development ofquantum mechanics. Just as ArthurComptondemonstrated the particle nature oflight, the Davisson-Germer experiment showed the wave-
nature of matter, and completed the theory ofwave-particle duality. Forphysiciststhis ideawas important because it means that not only can any particle exhibit wave characteristics,
butthat one can use wave equationsto describe phenomena in matterif one uses the de
Broglie wavelength.
Since the original Davisson-Germer experiment for electrons, the de Broglie hypothesis has
been confirmed for otherelementary particles.
The wavelength of a thermali ed electron in a non-metal at room temperature is about
8 nm.[cit ti
]
[edit] Neutral atoms
Experiments with Fresnel diffraction[3] and specular reflection
[4][5] of neutral atoms confirm
the application ofthe de Broglie hypothesis to atoms, i.e. the existence of atomic waves
which undergo diffraction, interference and allow quantum reflection by the tails ofthe
attractive potential.[6]
Advances in laser cooling have allowed cooling of neutral atoms down
to nanokelvin temperatures. Atthese temperatures, the thermal de Broglie wavelengths comeinto the micrometre range. Using Bragg diffraction of atoms and a Ramsey interferometry
technique, the de Broglie wavelength of cold sodium atoms was explicitly measured andfound to be consistent with the temperature measured by a different method.[7]
This effect has been used to demonstrate atomic holography, and it may allow the
construction of an atom probe imaging system with nanometer resolution.[8][9]
The description
ofthese phenomena is based on the wave properties of neutral atoms, confirming the de
Broglie hypothesis.
[edit] Waves ofmolecules
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Recent experiments even confirm the relations for molecules and even macromolecules,which are normally considered too large to undergo quantum mechanical effects. In 1999, a
research team in Vienna demonstrated diffraction for molecules as large as fullerenes.[10]
Theresearchers calculated a De Broglie wavelength ofthe most probable C60 velocity as 2.5pm.
More recent experiments proofthe quantum nature of molecules with a mass up to 6910
amu.[11]
In general, the De Broglie hypothesis is expected to apply to any wellisolated object.
[edit] Spatial Zeno effect
The matter wave leads to the spatial version ofthe Zeno effect. If an object (particle) is
observed with frequency in a half-space (say,y < 0), then this observation prevents
the particle, which stays in the half-spacey > 0 from entry into this half-spacey < 0. Suchan "observation" can be reali ed with a set of rapidly moving absorbing ridges, filling one
half-space. In the system of coordinates related to the ridges, this phenomenon appears as aspecular reflection of a particle from a ridged mirror, assuming the grazing incidence (small
values ofthe grazing angle). Such a ridged mirroris universal; while we considertheidealised "absorption" ofthe de Broglie wave atthe ridges, the reflectivity is determined by
wavenumberkand does not depend on other properties of a particle.[5]