Coking 101Coking 101An Introduction to Delayed Coking

Prepared By:

Jack Adams,Adams Project Managers, Inc.Email: APMI.Jack@gmail.com

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Delayed Coker Process & Systems OverviewDelayed Coker Process & Systems Overviewy yy y

This presentation provides an overview of the delayed coking system found in modern refineriesin modern refineries.

I. Process schematics (various sources)II Typical feedstock and productsII. Typical feedstock and products

III. The Coker Fractionator unitIV. The Coker Furnace

V. The Coke DrumsVI. Coke Drum Opening

VII Coke Drum Cutting Coke HandlingVII. Coke Drum Cutting, Coke HandlingVIII. Coke Drum Cycle Time

comparison

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I. I. Delayed Coker Process SchematicsDelayed Coker Process Schematicsyy

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II. Delayed Coker Feed MaterialII. Delayed Coker Feed Materialyy

Delayed Coker (Coker)Delayed Coker (Coker) feedstock is material from the refinery vacuum unit, which is otherwise used as road asphalt. The objective of the Coker is to process the asphalt-like material to produce higher value productsproduce higher value products, such as gasoline, diesel fuel, LPG, and petroleum coke.

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III. Delayed Coker III. Delayed Coker FractionatorFractionatoryy

The Coker Fractionator receives and separates the f d t k d k dfeedstock and sour cracked gas and liquids from the operating Coke Drum and Coker Furnace.

Fuels Gas and LPG are recovered for fuel or other productsproducts.

Naptha is recovered and sent to the other refinery units for gasoline production.

Light Coker Gas Oil (LCGO) and Heavy Coker Gas Oiland Heavy Coker Gas Oil (HCGO) are sidedraws from the Fractionator and are sent to hydrotreating for processing into diesel and other products.

The Coker Gas Plant further separates the productsseparates the products.

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IV. Delayed Coker FurnaceIV. Delayed Coker Furnaceyy

The Coker Furnace heats the heavy liquid material from the bottom of the Fractionator to about 900 to 945o F. (482 to 507o C). This heating causes the heavy liquid material to crack or change into a combination of smaller molecule gas and liquid products. Steam is injected to minimize the cracking until it is in the Coke Drum.

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V. Delayed Coker Coke DrumsV. Delayed Coker Coke Drumsyy

The Coker typically has 2 or more Coke Drums which operate in pairs in a semi-batch mode:batch mode:

In the Operating Coke Drum, the material from the Coker Furnace, at high temperature and low pressure, is injected into the bottom of the drum and is further cracked into (1)and is further cracked into (1) gaseous products which are returned to the Fractionator for product recovery and (2) into the petroleum coke that solidifies in the drum.

The other offline drum isThe other offline drum is steamed, vented, and cooled prior to the drum being opened to atmosphere. After the drum is opened, the petroleum coke is cut from the drum using high pressure water. Petroleum coke or simply coke is similarcoke or simply coke is similar to coal and is typically used for fuel in power plants.

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VI. Coke Drum OpeningVI. Coke Drum Openingp gp g

The modern Coker has automatic deheading valves on the top and bottom coke drum flanges to allow the coke drums to be opened safely fordrums to be opened safely for cutting the coke from the drum. Historically, the flanges were opened manually.

Several images are shown in the following slides showing the automated slide valvesthe automated slide valves. Schematics also following showing key valves in the system and safety interlocks which are common and allow the opening of one Coke Drum while having the other one in operation at the same timeoperation at the same time.

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Before DeltaGuard

Safe Unheading Totally enclosed system from the topof the coke-drum to the drain pit railof the coke-drum to the drain pit, railcar or sluice way Eliminate exposure risk topersonnel, equipment, andthe unheading deck Remotely operated fromcontrol room All safety interlocks incorporated

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Reference: Automation and Improved Safety of the Delayed Coking Process using Modern Delayed Coking De-Heading TechnologyBy: Ruben Lah, VP / CTOCurtiss-Wright Oil and Gas Systems Division

All safety interlocks incorporated Isolation of a tarry drum Isolation or control of a drum dump

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Pi t / N l Pi t / N l D lt G dD lt G dPicture / Nozzle Picture / Nozzle DeltaGuardDeltaGuard

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I D l d C kiI D l d C kiI. Delayed CokingI. Delayed Coking

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I t l kI t l kInterlocksInterlocks

Reference: Shot Coke: Design & OperationsBy John D. Elliott, Foster Wheeler USA Corporation

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VII. Coke Drum Cutting, Coke HandlingVII. Coke Drum Cutting, Coke Handlingg, gg, g

As the coke is cut by the high pressure water nozzle, the coke and water flow onto a Coke Pad or into the Coke Pit, where the water is separated and recycled back to the cutting water system.

C k i d f h i bCoke is moved from the pit by either a bridge crane or a front end loader for shipment .

Additional schematics and images follow show various components of the system.

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VII. Coke Drum CuttingVII. Coke Drum Cuttinggg

Drill assembly

Drill Assembly

Cutting BitDrill Stem Guide

Top Slide Valve

Bottom Slide Valve

The Jet Water Pump produces high pressure water to cut the coke

Cutting Deck

Bottom Slide Valve

from the drums.

Switch Valve

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FLOWSERVE FLOWSERVE A t ShiftA t Shift C tti T lC tti T lFLOWSERVE FLOWSERVE AutoShiftAutoShift Cutting ToolCutting Tool

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C k H dli CC k H dli CCoke Handling CraneCoke Handling Crane

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VIII. Coke Drum Cycle Time ComparisonVIII. Coke Drum Cycle Time Comparisony py p

Reference: DELAYED COKER REVAMPS: REALIZATION OF OBJECTIVES AM-04-69 -- By John D. Elliott, Foster Wheeler USA Corporation

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Additional Reading on Delayed CokingAdditional Reading on Delayed Cokingg y gg y g

We hope this very basic presentation has been informative. Additionalsuggested reading materials are listed below and provide more detail on the subject of delayed coking. We hope you will contact theAPMI/PROCESS Team when a coker revamp study is needed.y

Tutorial: Delayed Coking Fundamentals by Paul J. Ellis and Christopher A. Paul of the Great Lakes Carbon Corporation. u o a e ayed Co g u da e a s by au J s a d C s op e au o e G ea a es Ca bo Co po a oPresented at the 1998 AIChE Spring National Meeting in New Orleans, LA.

Coking Chapter 5 by _________of the Colorado School of Mines. Presented at _____________.

Petroleum Coke Petrography web page by Prof. John C. Crelling, Coal Research Center and Department of Geology, Southern Illinois University Carbondale.

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