Flame RetardantsProduct Guide

Great Lakes Solutions:A Global Leader in Flame Retardants

Contents

Introduction 4-5

Flame retardants selection guide 6

Technical data: Bromine-based @ame retardants 10

Technical data: Phosphorus-based @ame retardants 12

Technical data: Antimony, synergists & smoke suppressants 13

Great Lakes Solutions:Innovative. Reliable. Sustainable.

Resulting from decades of hard work, innovationand lessons learned, the Great Lakes Solutionsof today is positioned to be our customers bestpartner for bromine, phosphorus and antimony-based @ame retardant needs, both today andfar into the future. For almost a century, wehave helped our customers to meet their @ameretardant needs with a broad portfolio ofproducts and solutions. In late 2010, Chemturaintroduced the Great Lakes Solutions business witha mission to build on its well-established heritage,by introducing dierentiated, innovative products,and greener, sustainable solutions whilemaintaining performance and quality. We areproud of our history, and look forward to helpingour customers meet future performance, safetyand compliance requirements by constantlyimproving our portfolio with new and improvedproducts for maximum sustainability.

Flame RetardantsSaving Lives

Fire kills thousands of people each year through-out the world, but many are spared because Wresare slowed or never start due to the use of Xameretardants. Great Lakes Solutions is a global leaderin Xame retardant products and solutions for usein applications such as furniture foam, electroniccomponents, electrical enclosures, buildingproducts and more.

Great Lakes Solutions believes the public shouldnot be forced to choose between environmentaland Wre safety and that we must have both. Ourbusiness demands the highest standards of bothWre retardancy performance and environmentalsustainability. To meet these increasingly complexchallenges, Great Lakes Solutions oers a widerange of Xame retardant solutions that allow OEMsthe versatility to meet their individual needs.

Brominated Xame retardants are used in avariety of applications from electronic housingsto printed circuit boards and electrical connectorsto Xexible and rigid polyurethane foam. BrominatedXame retardants provide optimal processing whilemaintaining outstanding physical properties in acost eective manner.

Phosphorus Xame retardants are popular forelectronic housings and where improved UVstability is important. Our phosphorus Xameretardants are used extensively in a wide varietyof applications. Antimony trioxide is used as asynergist in many polymers when combinedwith brominated Xame retardants and can beused alone as a Xame retardant in PVC. Ourantimony-based synergists are used in polymers,paints, textiles, polyesters, coatings, elastomersand rubber compounds.

76

Flame Retardants Selection Guide

Recommended Suitable

Bromine Based Flame RetardantsPDBS-80 Firemaster CP-HF Firemaster PBS-6HW PHT- PHT-Diol DP- BA-9P PE-68 Firemaster BZ- Firemaster BZ- HP Firemaster 0 Firemaster Firemaster 600 Firemaster 60 CD-7P SP-7 BC- BC-8 DE-8R Firemaster 00R PH-7FF

Reactive Xame retardant used during polymerization. Products not registered for sale in Europe.

98

Recommended Suitable

Flame Retardants Selection Guide

Phosphorous Based Flame RetardantsReofos Reofos 0 Reofos 6 Reofos 9 Kronitex CDP Kronitex TCP Kronitex TXP Reofos RDP Reofos BAPP

Antimony Based SynergistsTMS/ Timonox Red Star/Fireshield H /

Thermoguard STrutint/ Fireshield L / Thermoguard L MicroWne/ UltraWne II Pyrobloc SAP / Thermoguard FR

Other Synergists / Smoke SuppressantsZinc Borate ZB- Zinc Borate ZB-67 Smokebloc/ BFR- Ongard LSFRTM Thermoguard CPA

Reactive Xame retardant used during polymerization. Products not registered for sale in Europe.

0

Bromine-Based Flame Retardants

Viscosity/ Volatility TypicalMelting TGA, Wt. Loss SpeciWc Bulk Density SolubilityRange C @ Temp Gravity g/ml (g/00 g solvent @ C)

PDBS-80 % @ 68C Water

Phosphorus-Based Flame Retardants

Viscosity/ Volatility TypicalMelting TGA, Wt. Loss SpeciWc Bulk Density SolubilityRange C @ Temp Gravity g/ml (g/00 g solvent @ C)

Reofos 35 % @ 7C Water InsolubleTriaryl Phosphates Isopropylated 7 mm/s 0% @ C Dichloromethane CPhosphorus Content: 8.6% @C 0% @ 87C .8 Toluene C

Methanol CCAS No. 6897--7 MEK C

Reofos 50 % @ 6C Water InsolubleTriaryl Phosphates Isopropylated -6 mm/s 0% @ C Dichloromethane CPhosphorus Content: 8.% @C 0% @ 8C .7-.8 Toluene C

Methanol CCAS No. 6897--7 MEK C

Reofos 65 % @ C Water InsolubleTriaryl Phosphates Isopropylated 6-76 mm/ss 0% @ 9C Dichloromethane CPhosphorus Content: 8.% @C 0% @ 8C .6 Toluene C

Methanol CCAS No. 6897--7 MEK C

Reofos 95 % @ C Water InsolubleTriaryl Phosphates Isopropylated 00- mm/s 0% @ C Dichloromethane CPhosphorus Content: 7.6% @C 0% @ 96C . Toluene C

Methanol CCAS No. 6897--7 MEK C

Kronitex CDP % @ 7C Water InsolubleCresyl Diphenyl Phosphate -8 mm/s 0% @ 6C Dichloromethane CPhosphorus Content: 9.% @C 0% @ 8C . Toluene C

Methanol CCAS No. 6-9- MEK C

Kronitex TCP % @ C Water InsolubleTriaryl Phosphates Butylated 7-68 mm/s 0% @ 9C Dichloromethane CPhosphorus Content: 8.% @C 0% @ 89C .7 Toluene C

9% @C Methanol CCAS No. 0-78- MEK C

Kronitex TXP % @ C Water InsolubleTriaryl Phosphate Butylated -6 mm/s 0% @ 0C Dichloromethane CPhosphorus Content: 7.8% @0C 0% @ 98C . Toluene C

Methanol CCAS No. -- MEK C

Reofos RDP % @ 07C Water InsolubleResorcinol Bis-(Diphenyl Phosphate) 00-800 mm/s 0% @ 7C Dichloromethane CPhosphorus Content: 0.8% @C 0% @ 0C . Toluene C

Methanol CCAS No. 78--7 MEK C

Reofos BAPP % @ 7C Water InsolubleBisphenol A Bis-(Diphenyl Phosphate) 90- mm/s 0% @ 97C Dichloromethane CPhosphorus Content: 8.9% @80C 0% @ C .6 Toluene C

Methanol CCAS No. 808-79- MEK C

Notes: TGA: Bulk Density: Solubility:0 mg @ 0C/min., N L denotes loose C denotes complete solubility (00 g/00 ml)

P denotes packed P denotes partial solubility

AntimonyTrioxide*

Typical Values: Antimony Oxide Arsenic Iron content Lead content Av. Particle sizeContent content (as Fe) (max) (asPb) (max) (Typical Values)(as Sb 0) (as As) (max)

TMS / TIMONOX RED STAR /FIRESHIELD H/ THERMOGUARDS 99.% 0.% 0.00% 0.0% .0-. m

TMS / TIMONOXWHITE STAR 99.% 0.% 0.00% 0.07% .0-. m

TMS-HP / TIMONOX BLUE STARPOLYMER GRADE / FIRESHIELD H-HPM /FIRESHIELD HB / THERMOGUARD HPM 99.% 0.09% 0.00% 0.0% 0.9-. m

TRUTINT 50 99.% 0.0% 0.00% 0.0% . m

FIRESHIELD L / THERMOGUARD L 99.% 0.0% 0.00% 0.0% .0-. m

MICROFINE A05 / MICROFINE A03 /ULTRAFINE II 99.% 0.0% 0.00% 0.0% 0.-0.9 m

* Many products are available in forms with improved Health, Safety & Environmentalcharacteristics, including damped powders, concentrates, small packs and inclusion bags.

Sodium Antimonate

Typical Values: Antimony Oxide Arsenic Iron content Lead content Av. Particle sizeContent content (as Fe) (max) (asPb) (max) (Typical Values)(as Sb 0) (as As) (max)

PYROBLOC SAP-2 / THERMOGUARD FR 60. 0.09% 0.00% 0.09% m

Zinc BorateTypical Values: Stoichiometry TGA Av. Particle Size

(C, % mass loss)

ZB-223 ZnO.B.O.HO 00C % mC %8C 0%

ZB-467 Zn0.6B.O.7HO 80C % m80C %0C 0%

Synergists & Smoke Suppressants

SMOKEBLOC / BFR Series of products with combined Xame retardants and / or afterglow and / or smoke suppressing properties.Used as partial or complete replacement for antimony oxide in PVC formulations.

ONGARD 2 Proprietary Zinc/Magnesium Complex, eective smoke suppressant for PVC with excellent heat aging properties.Cost Eective Antimony Oxide replacement for stringent Rigid PVC applications.

FIRESHIELD LSFR Flame retardant synergist for PVC with low smoke performance.Used as partial or complete replacement for antimony oxide in PVC applications.

THERMOGUARD CPA Flame retardant synergists for PVC with low smoke performance.Used as partial or complete replacement for antimony oxide in PVC applications.

Antimony, Synergists & Smoke Suppressants

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Great Lakes SolutionsUnited States and Canada

Headquarters, Customer Service,Sales and Technical Service80 US Highway WestWest Lafayette, Indiana 7906Phone: -800-8-797 or -76-97-60Fax: -76-6-88

Latin America

Customer ServiceChemtura Industria Quimicado Brasil LimitadaAv Brasil Disrito Industrial Rio ClaroSao Paolo, Brazil, CEP: 0-600Phone: +-9--000Fax: +-9-7-09

Customer ServiceChemtura Corporation Mexico,S. de R.L. de C.V.Calzada de Guadalupe No. 0Col. El CerritoCuautitlan, Estado de MexicoPhone: +--00-600Fax: +--00-6

Europe, Middle East and Africa

Customer ServiceChemtura Manufacturing UK Ltd.Tenax Road - Trafford ParkManchester M WTUnited KingdomPhone: +-6-87-800Fax: +-6-87-90

Sales Office and Technical ServiceChemtura Europe GmbHBahnhofplatz 6CH-800 FrauenfeldSwitzerlandPhone: +--7--00Fax: +--7--99

Sales OfficeChemtura Moscow LLCA Tverskaya Str, Bld. Moscow 009 RussiaPhone: +7 (9) 80 777Fax: +7 (9) 9960

Asia/Pacific

Application Development Centerand Technical ServiceChemtura Chemicals NanjingLimited Company Xing Jian RoadNanjing Economic & TechnologicalDevelopment Zone006 PR ChinaPhone: +86 () 7 6666Fax: +86 () 87 969

Sales Office and Customer ServiceChemtura Shanghai Co. Ltd.Room 70-70China Fortune TowerNo. 68 Century AvenuePudong District, Shanghai 000,PR ChinaPhone: +86 () 866 6688Fax: +86 () 6876 077

Sales Office and Customer ServiceChemtura Japan LimitedShimbashi SY Bldg. F--, Nishi-Shimbashi, Minato-kuTokyo, Japan 0-000Phone: +8--0-7000Fax: +8--0-700

Sales Office and Customer ServiceChemtura Korea Inc.6th floor, Sooil Bldg., -, Nonhyun-dong,Gangnam-gu,Seoul, Korea -8Phone: +8---00Fax: +8---90

Sales Office and Customer ServiceChemtura Singapore Pte Ltd7 Science Park Drive#0-0 Cintech ISingapore 8Phone: +6-6770-0Fax: +6-677-

For more informationor to email us, visit uson the web at:www.greatlakes.com

The information contained herein iscorrect to the best of our knowledge.Your attention is directed to the pertinentMaterial Safety Data Sheets for theproducts mentioned herein.

All sales are subject to Chemturasstandard terms and conditions of sale,copies of which are available uponrequest and which are part of Chemturasinvoices and/or acknowledgements.Except as expressly provided inChemturas standard terms andconditions of sale, no warranty expressor implied, including warranty ofmerchantability or Wtness for a particularpurpose, is made with respect to theproduct described herein. Nothingcontained herein shall constitutepermission or recommendation topractice any invention covered by apatent without license from the ownerof the patent.

The tradenames in this brochure areregistered trademarks of ChemturaCorporation and/or its subsidiaries.

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