cheminform abstract: enantioselective radical addition to ketimines: a synthetic route towards...
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Amino acidsU 0400 DOI: 10.1002/chin.201112195
Enantioselective Radical Addition to Ketimines: A Synthetic Route Towards α,α-Disubstituted α-Amino Acids. — The title reaction provides a general route for the synthesis of α,α-disubstituted α-amino acids under metal-free conditions. The chi-ral environment results from interaction of the catalyst with the ketimine through hy-drogen bonding and π—π stacking. — (KIM, S. Y.; KIM, S. J.; JANG*, D. O.; Chem. Eur. J. 16 (2010) 44, 13046-13048, http://dx.doi.org/10.1002/chem.201002071 ; Dep. Chem., Yonsei Univ., Wonju 220-710, S. Korea; Eng.) — Kieslich
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ChemInform 2011, 42, issue 12 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim