cheminform abstract: copper-catalyzed synthesis of alkynylphosphine derivatives: unprecedented use...

ChemInform 2011, 42, issue 28 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Organo-phosphorus compounds S 0080 DOI: 10.1002/chin.201128182 Copper-Catalyzed Synthesis of Alkynylphosphine Derivatives: Unprecedented Use of Nucleophilic Phosphorus Compounds. — A new and efficient access to various alkynylphosphine derivatives is developed using Cu-catalyzed cross-coupling reactions of secondary phosphine boranes with alkynyl bromides. — (BERNOUD, E.; ALAYRAC, C.; DELACROIX, O.; GAUMONT*, A.-C.; Chem. Commun. (Cambridge) 47 (2011) 11, 3239-3241, http://dx.doi.org/10.1039/c0cc04645k ; Lab. Chim. Mol. Thio-Org., CNRS, Ec. Natl. Super. Ing., Univ. Caen, F-14050 Caen, Fr.; Eng.) — K. Wilckens 28- 182

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Page 1: ChemInform Abstract: Copper-Catalyzed Synthesis of Alkynylphosphine Derivatives: Unprecedented Use of Nucleophilic Phosphorus Compounds

Organo-phosphorus compoundsS 0080 DOI: 10.1002/chin.201128182

Copper-Catalyzed Synthesis of Alkynylphosphine Derivatives: Unprecedented Use of Nucleophilic Phosphorus Compounds. — A new and efficient access to various alkynylphosphine derivatives is developed using Cu-catalyzed cross-coupling reactions of secondary phosphine boranes with alkynyl bromides. — (BERNOUD, E.; ALAYRAC, C.; DELACROIX, O.; GAUMONT*, A.-C.; Chem. Commun. (Cambridge) 47 (2011) 11, 3239-3241, http://dx.doi.org/10.1039/c0cc04645k ; Lab. Chim. Mol. Thio-Org., CNRS, Ec. Natl. Super. Ing., Univ. Caen, F-14050 Caen, Fr.; Eng.) — K. Wilckens

28- 182

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