cheminform abstract: an expedient stereocontrolled synthesis of 7-cis-retinoids
TRANSCRIPT
2001 vitamins
vitaminsU 0900
47 - 231An Expedient Stereocontrolled Synthesis of 7-cis-Retinoids. — Anefficient synthesis of (7Z)-retinal (IV) involving the Pd-catalyzed cross-couplingof cyclohexenyl boronate derived from (I) with geometrically homogeneoustetraenyl iodide (II) as the key step is described. — (ALVAREZ, ROSANA;DOMINGUEZ, BEATRIZ; DE LERA, ANGEL R.; Synth. Commun. 31 (2001)13, 2083-2087; Dep. Quim. Org., Univ. Vigo, E-36200 Vigo, Spain; EN)
1