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Chem 301 Descriptive Inorganic Chemistry Spring 2018 3 Credits Syllabus Meeting Time: MWF 9:10 -10:00 Room: Troy G005 Prerequisite: Chem 106 with a C or better Instructor: Jeremy Lessmann Office location: Fulmer 311 Phone: 335-2098 Email: [email protected] Office Hours: W 10-11, Tu 9:30-10:30 Course website: The course will use the Blackboard learning management system Course Materials: Required text: Descriptive Inorganic Chemistry, Geoff Rayner-Canham and Tina Overton, 6 th Ed., Freeman, 2014 (ISBN : 978-1-4641-2557-7) Student Learning Outcomes At the end of this course, students should be able to: Course Topics/Dates Evaluation of Outcome: This outcome will be evaluated primarily by: 1. Describe the organization of the elements in the periodic table based on electron configuration, atomic radii, ionization energies, and electron affinities. 2. Describe and apply bonding concepts in terms of the Lewis model and the ionic model, predict shapes of molecules based on the VSEPR model, and describe ionic compounds using the basic ideas of crystal packing 3. Apply thermodynamic principles, including lattice and bond energies, to evaluate the stability of inorganic compounds 4. Distinguish and apply acid-base theories to predict the outcome of inorganic reactions 5. Apply concepts and data relating oxidation-reduction reactions to predict the outcome of inorganic reactions 6. Describe the periodic trends in reactivity. 7. Describe the predominant features of the elements based on their position in the periodic table (hydrogen, Groups 1, 2, 13, 14, 15, 16, 17, and 18) 8. Describe and name the structures commonly observed for transition metal complexes. 9. Describe the predominant structural features and reactivity of the compounds of the 3d transition metals. 10. Describe the predominant structural features and reactivity of the compounds of the 4d and 5d transition metals. 11. Describe the predominant structural features and reactivity of the compounds of the Group 12 metals. 12. Recognize common, stable organometallic transition metal compounds. Week 1 Weeks 2 and 3 Week 4 Week 5 Week 6 Weeks 7-11 Week 12 Week 12 and 13 Weeks 13 and 14 Week 14 Week 14 Exam 1 and Quiz 1 Exam 1 and Quiz 2 Exam 1 and Quiz 3 Exam 1 and Quiz 4 Exam 1 and Quiz 5 Exam 2 and Quizzes 6-10 Exam 2 and Quiz 11 Exam 2 and Quiz 12 Exam 2 and Quiz 12 Final Exam Final Exam All topics will be re-evaluated by the final exam.

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Chem301DescriptiveInorganicChemistry

Spring2018 3Credits

Syllabus

MeetingTime:MWF9:10-10:00 Room:TroyG005

Prerequisite:Chem106withaCorbetter

Instructor:JeremyLessmann Officelocation:Fulmer311 Phone:335-2098

Email:[email protected] OfficeHours: W10-11,Tu9:30-10:30

Coursewebsite:ThecoursewillusetheBlackboardlearningmanagementsystem

CourseMaterials:Requiredtext:DescriptiveInorganicChemistry,GeoffRayner-CanhamandTinaOverton,6thEd.,Freeman,2014(ISBN:978-1-4641-2557-7)

StudentLearningOutcomesAttheendofthiscourse,studentsshouldbeableto:

CourseTopics/Dates

EvaluationofOutcome:Thisoutcomewillbeevaluatedprimarilyby:

1.Describetheorganizationoftheelementsintheperiodictablebasedonelectronconfiguration,atomicradii,ionizationenergies,andelectronaffinities.2.DescribeandapplybondingconceptsintermsoftheLewismodelandtheionicmodel,predictshapesofmoleculesbasedontheVSEPRmodel,anddescribeioniccompoundsusingthebasicideasofcrystalpacking3.Applythermodynamicprinciples,includinglatticeandbondenergies,toevaluatethestabilityofinorganiccompounds4.Distinguishandapplyacid-basetheoriestopredicttheoutcomeofinorganicreactions5.Applyconceptsanddatarelatingoxidation-reductionreactionstopredicttheoutcomeofinorganicreactions6.Describetheperiodictrendsinreactivity.7.Describethepredominantfeaturesoftheelementsbasedontheirpositionintheperiodictable(hydrogen,Groups1,2,13,14,15,16,17,and18)8.Describeandnamethestructurescommonlyobservedfortransitionmetalcomplexes.9.Describethepredominantstructuralfeaturesandreactivityofthecompoundsofthe3dtransitionmetals.10.Describethepredominantstructuralfeaturesandreactivityofthecompoundsofthe4dand5dtransitionmetals.11.DescribethepredominantstructuralfeaturesandreactivityofthecompoundsoftheGroup12metals.12.Recognizecommon,stableorganometallictransitionmetalcompounds.

Week1Weeks2and3Week4Week5Week6Weeks7-11Week12Week12and13Weeks13and14Week14Week14

Exam1andQuiz1Exam1andQuiz2Exam1andQuiz3Exam1andQuiz4Exam1andQuiz5Exam2andQuizzes6-10Exam2andQuiz11Exam2andQuiz12Exam2andQuiz12FinalExamFinalExamAlltopicswillbere-evaluatedbythefinalexam.

AssignmentsTherewillbeungradedin-classexercisesandfollow-upassignments.TheanswerkeysforthesewillbepostedonBlackboardbuttheywillnotbegraded.Therewillbetwoin-classhourexamsandtwelvein-classquizzesaswellasacomprehensivefinal. Ofthetwelvequizzes,tenwillcounttowardsthefinalgradewithlowesttwoscoresdropped.Therewillbenomakeupsquizzes.Therewillbeten(14?)homeworkassignmentsthatwillcomeprimarilyfromthetextbookandtheywillbedueonWednesdayandcoverthematerialthroughthepreviousFriday.ThequizzesonthesamematerialwillbeonthefollowingFriday.

GradingPolicy 2HourExams 2X150 300points 10BestHomework 10X25 250

10BestQuizzes 10X20 200 Final 250 250 Total 1000points

GradesarebasedonthetotalpointsandwillbenolowerthananAfor90-100%,aBfor80-90%,aCfor70-80%andaDfor60-70%.Therewillalsobe+and-grades.

Weektoweekcourseoutlinewithtopicsandassignments(Sincethisisthefirsttimethiscoursehasbeentaughtsometopicsmayshiftorbechangedasneeded.)

Week Readingtopics AssignmentsandExams1:Jan.8–12 Chptr.1TheElectronicStructureoftheAtom:A

ReviewChptr.2TheStructureofthePeriodicTable

None

2:Jan.15*-19 Chptr.3CovalentBondingandMolecularSpectroscopy

Homework1(W),Quiz1(F)

3:Jan.22–26 Chptr.4MetallicBondingandAlloys(4.1,4.3,4.4)andChptr.5:IonicBondingandSolid-StateStructures(5.1-5.4)

Homework2(W),Quiz2(F)

4:Jan.29–Feb.2 Chptr.6WhyCompoundsExist-InorganicThermodynamics

Homework3(W),Quiz3(F)

5:Feb.5–9 Chptr.7SolventSystemsandAcid-BaseBehavior Homework4(W),Quiz4(F)6:Feb.12–16 Chptr.8OxidationandReduction(8.1–8.9) Homework5(W),Quiz5(F)7:Feb.19*–23 Chptr.9PeriodicPatterns

Chptr.10HydrogenChptr.11TheGroup1Elements:TheAlkaliMetals(11.1–11.6)

Homework6(W),Exam1(Chapters1through8)(F)

8:Feb.26–March2 Chptr.11TheGroup1Elements:TheAlkaliMetals(11.7–11.14)Chptr.12TheGroup2Elements:TheAlkalineEarthMetalsChptr.13TheGroup13Elements(13.1–13.5)

Homework7(W),Quiz6

9:March5–9 Chptr.13TheGroup13Elements(13.6–13.11)Chptr.14TheGroup14Elements

Homework8(W),Quiz7(F)

March12–16 SpringVacation 10:March19–23 Chptr.15TheGroup15Elements:ThePnictogens

Chptr.16TheGroup16Elements:TheChalcogens(16.1–16.8)

Homework9(W),Quiz8(F)

11:March26–30 Chptr.16TheGroup16Elements:TheChalcogens(16.9–16.22)

Homework10(W),Quiz9(F)

Chptr.17TheGroup17Elements:TheHalogensChptr.18TheGroup18Elements:TheNobleGases

Week Readingtopics AssignmentsandExams12:April2–6 Chptr.19TransitionMetalComplexes(19.1–19.5,

19.14-19.15)Chptr.20The3dTransitionMetals(20.1–20.10)

Homework11(W),Quiz10(F)

13:April9–13 Chptr.20The3dTransitionMetals(20.11–20.13)Chptr.21The4dand5dTransitionMetals(21.1–21.6)

Homework12(W),Exam2(Chapters9through20.10)(F)

14:April16-20 Chptr.21The4dand5dTransitionMetals(21.7–21.12)Chptr.22TheGroup12Elements

Homework13(W),Quiz11(F)

15:April23-27 Chptr23OrganometallicChemistry(selectedtopics)andReview

Homework14(W),Quiz12(F)

16:May1 Tuesday8-10 ComprehensiveFinalExam

*Jan.15istheMartinLutherKingholiday,February19isthePresident’sDayholiday

AttendancepolicyRegularattendanceisexpectedinordertobesuccessfulinthiscourse.Ifyouknowthatyouwillmissanexam,quiz,inclassproblem,ortheduedateforahomeworkassignmentforreasonsbeyondyourcontrol,youareexpectedtomakearrangementsinadvanceforanyaccommodationthatmaybepossible.Ingeneral,lateexamsorquizzesarenotavailable.

StudentswithDisabilitiesReasonableaccommodationsareavailableforstudentswithadocumenteddisability.Ifyouhaveadisabilityandneedaccommodationstofullyparticipateinthisclass,pleaseeithervisitorcalltheAccessCenter(WashingtonBuilding217;509-335-3417)toscheduleanappointmentwithanAccessAdvisor.AllaccommodationsMUSTbeapprovedthroughtheAccessCenter.FormoreinformationcontactaDisabilitySpecialist.

AcademicIntegrityIencourageyoutoworkwithclassmatesonassignments.However,eachstudentmustturninoriginalwork.Nocopyingwillbeaccepted.StudentswhoviolateWSU'sStandardsofConductforStudentswillreceiveazeroontheassignmentandmayreceiveanFasafinalgradeinthiscourse,andwillbereportedtotheOfficeStudentStandardsandAccountability.CheatingisdefinedintheStandardsforStudentConductWAC504-26-010(3).Itisstronglysuggestedthatyoureadandunderstandthesedefinitions.

SafetyandEmergencyNotificationWashingtonStateUniversityiscommittedtoenhancingthesafetyofthestudents,faculty,staff,andvisitors.ItishighlyrecommendedthatyoureviewtheCampusSafetyPlan(http://safetyplan.wsu.edu/)andvisittheOfficeofEmergencyManagementwebsite(http://oem.wsu.edu/)foracomprehensivelistingofuniversitypolicies,procedures,statistics,andinformationrelatedtocampussafety,emergencymanagement,andthehealthandwelfareofthecampuscommunity.