alchemy then and now

7/29/2019 Alchemy Then and Now

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Alchemy: Then and Now

Ruth Kassinger--The Washington Post--March 22, 1999

Sir Isaac Newton: mathematician, physicist, astronomer, alchemist.

Yes, the man who invented calculus and derived the law of universal gravitation also practiced alchemy, the

ancient and secretive pseudo-science of turning base metals into gold. Newton spent years working at his furnacewith dangerous and smelly combinations of the raw materials of alchemy -- mercury, silver, lead and sulfur.

He was convinced that not only could gold be made but also that ancient alchemists had done so. Their secretknowledge, he believed, although largely lost, might be teased from 2,000 years of accumulated ancient Greek,Egyptian and Arab writings, many of which he had read and copied.

After one experiment, Newton wrote in an unpublished manuscript that he thought he had the "great secret ofAlchemy," a sort of "living" mercury that "makes gold begin to swell . . . . and also to spring forth in sproutsand branches." The process didn't pan out, but the secret, he felt, was nearly within his grasp.

t wasn't. But mercury can, indeed, be turned into gold. The secret lies in understanding the structure of theatom's nucleus and the technology of accelerating atomic particles. That knowledge wouldn't arrive, however,ntil 250 years after Newton and 20 centuries after alchemists first sought the recipe for gold.

WHY GOLD?

Gold is soft enough to cut with a knife, so it has never been useful as a material for tools. Although itsmalleability makes it easy to shape into jewelry, it also dents and scratches easily, which is why even aigh-quality, 18-karat "gold" ring is 25 percent other metals.

Gold is extremely heavy. A gold bar is twice as heavy as the same-sized bar made of lead. After plundering Persiaof its gold in 334 B.C., Alexander the Great decided to bury portions of the treasure along the trail to lightenhe burden on his soldiers. Nonetheless, many early civilizations treasured gold and silver for its value as

ornamentation.

But about 3500 B.C., when people in the new towns of ancient Mesopotamia began to use the metals as money toacilitate trade, gold and silver took on new value. Until then, families were largely self-sufficient in food

and bartered for foodstuffs or objects that they didn't grow or make.

But as more people lived in towns and became less self-sufficient, the need to trade increased. Instead ofaccepting a herd of goats in exchange for his cloth and then trading the goats for the sheep he really wanted, a

raftsman could accept silver and, knowing that his neighbors valued the silver as he did, buy sheep directly.

At first, the gold and silver were traded in chunks that merchants had to weigh, but by about 2800 B.C.,

Mesopotamians had formed it into rings of standard weights.

Gold didn't tarnish like copper or silver or rust like iron and wasn't damaged by heat. In fact, until medievalalchemists concocted the acid known as aqua regia, gold was considered indestructible.

Moreover, gold is rare, about six times rarer than silver. On average, to extract an ounce of gold from Earth'srust, one must smash and process about three tons of rock. People who held their wealth in gold did not oftennd their riches suddenly diluted by appearance of a large new supply.

The desirability of gold has always been enhanced by associations that people make with it. Because it seemedmperishable, the ancient Chinese thought that gold might convey its immortality to its owners. Gold coins

eminded people of the golden sun with its warming, life-giving qualities.

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Bernard Trevisan, a medieval Italian alchemist, wondered, "Is not gold merely [the sun's] beams condensed to aolid yellow?" Anthropologist Kaj Arhem notes that the Makuna people of Brazil believe that "gold contains theght of the sun and stars."

AN ANCIENT PEDIGREE

Newton and many of his contemporaries, including chemist Robert Boyle and philosopher John Locke, were amonast of a long line of intellectuals who believed in alchemical transmutation of base metals.

The Adam of the lineage was Aristotle. He believed that all materials in the physical world were made of four

elements -- water, earth, air and fire -- and that the proportion of the elements in any substance determinedwhat the substance was.

Although he never tried to prove it, Aristotle predicted that one material could be transformed into another by

altering the mix of its elements.

He also believed, as did most people of the time, that metals grew in the ground, like plants, although much more

lowly. Just as seeds grew into more "perfect" plants and children grew into more "perfect" adults, so all metalseventually would attain the ideal form of metals, gold, he believed.

When Alexander the Great marched into Egypt, he took the ideas of his tutor, Aristotle, with him. The Egyptians

drew on sophisticated goldsmiths' techniques and other chemical knowledge gained in glassmaking and dyeing to putting Aristotle's ideas to practical use.

Through elaborate mixing and heating procedures, they attempted to make gold by changing the proportion of

elements in base metals or hurrying "natural growth" of these metals into gold.

One of the earliest alchemists whose identity has survived was a Jewish woman who is known as "Marie," lived in

Egypt about 100 A.D. and conducted experiments with mercury, which was tantalizing silver-colored, and sulfur,

whose yellow hue seemed related to gold.

n her work, she invented several devices for heating her ingredients. One is used today -- the double-boiler,

known in French as a bain-Marie, or "Marie's bath."

By 300 A.D., perhaps from lack of success, Egyptian alchemists turned increasingly to mystical approaches.Zosimos, whose recipes sometimes came to him in dreams, wrote that "the soul of copper must be purified until it

eceives the sheen of gold and turns into the royal sun-metal."

The mystics' recipes, filled with symbols based on magic and astrology, would intrigue alchemists until Newton's

me.

ALCHEMY DISSOLVED

After Egypt came under Roman control with the defeat of Cleopatra in the 1st century B.C., alchemy did not farewell.

Diocletian, emperor of Rome from 284 to 305 A.D., ordered destruction of all Egyptian alchemical writings,oncerned that alchemists' gold would fund a rebellion.

When Constantine made Christianity the official religion of the Roman Empire in the middle of the 4th century,alchemy and other Hellenistic thought was suppressed for its pagan associations. However, many of the forbidden

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manuscripts were saved by a sect of dissident Christians, called Nestorians, who took them to Persia about 400.

Between 640 and 720, followers of the prophet Mohammed conquered an empire that stretched from India to Spaincluded Egypt. Arab alchemists, too, adopted Aristotle's ideas, from Nestorians and Egyptians.

During crusades to Jerusalem in the 12th century, Europeans rediscovered the store of alchemical and otherlassical works by Arabs. To the mix of Aristotelian philosophy, Egyptian mysticism and the Arabs' practicalhemical knowledge, Europeans added concepts of religious transformation from Christianity.

f bread and wine could change into the body and blood of Christ, some alchemists thought that, with God's help,a man of pure spirit might turn lead to gold. Because the Roman Catholic Church came to support Aristotle's basicdeas, with an added role for God, alchemy no longer was anathema. In fact, many European alchemists of the

medieval era were clerics.

APPARENT SUCCESS

t may seem odd that alchemy survived for so many centuries without producing gold. One reason is that the earlyalchemists believed they had done so.

One ancient Egyptian recipe for "diplosis" (doubling) of gold called for a heated mixture of two parts goldwith one part each of silver and copper. Indeed, twice as much of a golden material results.

Egyptian alchemists believed that the gold acted as a seed in the copper and silver. The seed grew, eating theopper and silver as food, until the whole mixture was full-grown gold. Today, we know that, because the silver

gives the gold a greenish tint and the copper gives it a reddish tint, mixing both hardly changes the color ofhe gold.

Early alchemists also believed that they were making gold because, at the time, it wasn't clear what gold was.Gold found in nature often is combined, or alloyed, with other minerals or metals, so the standard for gold was

mprecise. If a metal looked like gold and felt like gold, it might as well be gold.

Even when people knew that what looked like gold actually could be a mix of gold and another metal, it wasdifficult to determine whether a sample was pure gold.

A hard, black stone known as a touchstone was an ancient device for determining the quality of gold. Scraping apiece of gold across it left a streak of gold. Depending on the brightness of the streak, an expert couldestimate how much gold was in the sample. Unfortunately, a touchstone wasn't precise and couldn't determine

whether the gold was only a coating on a metal of lesser value.

As early as 1500 BC, Mesopotamians discovered a method for purifying gold called "cuppellation," which involved

eating impure gold in a porcelain cup called a cuppel. Impurities were absorbed by the porcelain, leaving a puregold button.

Later alchemists used cuppellation to prove that their transmutations were successful. They would put lead on

which they had experimented into the cuppel and heat it.

When a small bit of gold appeared in the bottom, they wrote in all good faith that their alchemy worked, citinghe bit of gold as evidence that the lead was on its way to becoming all gold. They didn't know that most lead

ore has a little gold or silver in it. That was what they had found.

Alchemists also were encouraged by amazing substances they did make, including nitric, hydrochloric and sulfuric

acids. With a hiss and some smoke, these ate through all kinds of metals.

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n about 1100, alchemists made aqua regia, a combination of nitric and hydrochloric acids that could destroy gold.

Alchemists assumed that the ability to destroy gold would be followed quickly by their ability to create it.

THE NEW ALCHEMY

Alchemists, of course, never could make gold. Gold is an "element," a substance composed entirely of one kind ofatom and not further divisible by chemical processes into other kinds of atoms.

Not until the late 18th century, when chemists Joseph Priestly, Henry Cavendish and Antoine Lavoisierexperimented with air and fire, did it became clear that some substances are elements and others are compounds.Compounds are made of two or more elements. Water, for example, is a combination of hydrogen and oxygen.

Throughout the 19th century, through experimentation, scientists compiled a growing list of elements.

ust before World War I, British physicist Ernest Rutherford and others developed a model of the atom as compose

of a nucleus containing a tightly bound cluster of positively charged protons and electrically neutral neutronsand surrounded at a distance by orbiting, negatively charged electrons.

n an electrically neutral atom, the number of electrons is equal to that of protons.

Why couldn't alchemists transform one element into another?

An atom of any element is determined by the number of protons in its nucleus. The simplest atom, hydrogen, hasone positive proton in its nucleus and one negative electron circling it. The element with two protons is helium,and the element with three protons is lithium.

n the nucleus of an atom of gold are 79 protons and 79 electrons. Changing one element into another requireshanging the number of protons in the nucleus, a very difficult procedure.

Any proton aimed at a nucleus is repulsed by the positive charge of the nucleus. The only way to insert a proton

s to sling it with enough energy to overcome that electrical repulsion.

n 1919, Rutherford bombarded nitrogen atoms, with their seven protons and seven neutrons, with alpha particles.

These are helium nuclei containing two protons and two neutrons. The helium protons penetrated the nucleus of thitrogen atoms and produced an isotope of oxygen (eight protons and nine neutrons) and hydrogen (one proton).

Rutherford was first to transmute an element successfully.

Still, the transmutation was not entirely man-made. Rutherford worked his magic by taking advantage of naturallyoccurring radioactivity to achieve the energy to break into a nucleus.

n 1932, British physicists J. D. Cockcroft and E.T.S. Walton developed a device for accelerating protons andaimed a beam of protons at a sample of lithium. One more proton joined lithium's nucleus of three protons andour neutrons, which transmuted into two atoms of helium, each with two protons and two neutrons. This was therst time anyone had transmuted one element into another artificially.

To be sure, new information and high technology were required to achieve what alchemists had attempted for 2,00ears. But a different approach to knowledge also was needed. We now call it the scientific method, whereby

experiment must confirm all ideas.

Failure of their experiments did not make alchemists question the ideas. They assumed that they had not fullynderstood the ideas or had failed to follow the recipe accurately.

ohn Maynard Keynes, the English economist who collected Newton's alchemical notes and manuscripts, called N

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the last of the magicians" who saw the world as a sort of philosopher's treasure hunt with clues scattered about

n the evidence of the heavens and in obscure writings and traditions passed through the ages.

MAN-MADE GOLD

Today, scientists use much more powerful accelerators and can accelerate nuclear particles with 1 million timeshe energy of the device used by Cockcroft and Walton.

n the late 1960s, Judith Temperley, a physicist at Edgewood Arsenal in Maryland, studied properties of variousmetals by bombarding them with high-energy neutrons.

n one experiment, the target metal was mercury, an element with 80 protons. Under these conditions, a neutronenters the nucleus, which ultimately causes destruction of a proton by a process called "electron capture." Theesult is an atom with only 79 protons, making it an atom of gold!

So the alchemists were correct: A base metal can be turned into gold, but only with extreme patience. Accumulatea penny's worth of gold from mercury in this fashion, says Barry L. Berman, a physicist at George WashingtonUniversity, will take about 1,000,000,000,000,000,000,000,000 years.

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