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Specialty Gas Catalog Molecules that Matter ALPHAGAZ Pures, SCOTT Mixtures and Equipment | 2009 Edition

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Specialty Gas CatalogMolecules that Matter

ALPHAGAZ Pures, SCOTT Mixtures and Equipment | 2009 Edition

As a leading world supplier of specialty and industrial gases, Air Liquide is all about molecules that matterOur technologies are carefully engineered to provide customers with meticulously analyzed measures of certain molecules in the form of pure or mixed gases and liquids. These molecules are in turn used as raw materials or end products in themselves, as is often the case in healthcare or food and beverage processing. Other times the molecules we provide are used to measure or test for the presence of other molecules, as in applications such as environmental monitoring, homeland security or process control. Our focus however, goes well beyond the refining and selling of molecules. It includes providing definable value that can be measured at the bottom line. About one third of Air Liquides product sales can be linked directly to applications that are helping to preserve our environment or ensure human safety. Other Air Liquide products and services involve helping our many customers keep pace with a challenging global economyby empowering them to improve efficiencies without sacrificing end product quality or analytical accuracy. Our commitment to safety, technology and innovation has kept Air Liquide at the forefront of the high-tech business of specialty and industrial gases for more than 100 years. Our presence of over 43,000 employees in 75 countries enables us to leverage the resources of a truly global enterprise with powerful, personalized service from our localized, customer-focused teams. Combined with innovative products and services, we believe this to be a winning formula that transforms molecules that matter into greater customer satisfaction, efficiency, growth and successplus a safer and cleaner environment for us all.

Table of ContentsIntroduction .......................................................................... iv Cylinder PackagingLow-Pressure ........................................................................... 2 High-Pressure Stainless Steel ................................................... 3 High-Pressure Aluminum .......................................................... 4 Cryogenic ................................................................................. 4 Dewars ..................................................................................... 5 Packs ....................................................................................... 5 Pistons ..................................................................................... 5 Tube Trailers ............................................................................. 5 SCANDINA ............................................................................ 6 SMARTOP ............................................................................ 6 ALTOP ................................................................................... 7 ALTOP Lab ............................................................................... 8 Halocarbon 134a .................................................................... 45 Halocarbon 218 ..................................................................... 46 Halocarbon C318 ................................................................... 47 Halocarbon C1418 ................................................................. 48 Halocarbon 2316 ................................................................... 49 Helium .................................................................................... 50 Hydrogen ............................................................................... 51 Hydrogen Bromide ................................................................. 52 Hydrogen Chloride ................................................................. 53 Hydrogen Fluoride .................................................................. 54 Hydrogen Sulfide .................................................................... 55 Isobutane ............................................................................... 56 Isobutylene ............................................................................. 57 Krypton .................................................................................. 58 Methane ................................................................................. 59 Neon ...................................................................................... 60 Nitric Oxide ............................................................................. 61 Nitrogen .................................................................................. 62 Nitrogen Dioxide ..................................................................... 65 Nitrogen Trifluoride .................................................................. 66 Nitrous Oxide .......................................................................... 67 Oxygen ................................................................................... 68 Phosphine .............................................................................. 69 Propane .................................................................................. 70 Propylene ............................................................................... 71 Silane ..................................................................................... 73 Sulfur Dioxide ......................................................................... 74 Sulfur Hexafluoride ................................................................. 75 Trisilane ................................................................................... 76 Tungsten Hexafluoride ............................................................ 77 Xenon ..................................................................................... 78

Pures and Other Support GasesALPHAGAZ Introduction ......................................................................... 10 Specifications ...................................................................... 11 Impurities Affecting Gas Detectors ...................................... 12 Other Available Pures .......................................................... 14 Acetylene ................................................................................ 16 Air ........................................................................................... 17 Ammonia ................................................................................ 19 Argon ..................................................................................... 20 Arsine ..................................................................................... 22 Boron Trichloride .................................................................... 23 Boron Trifluoride ..................................................................... 24 1,3-Butadiene ........................................................................ 25 n-Butane ................................................................................ 26 1-Butene ................................................................................ 27 cis-2-Butene ........................................................................... 28 trans-2-Butene ....................................................................... 28 Carbon Dioxide ...................................................................... 29 Carbon Monoxide ................................................................... 31 Chlorine .................................................................................. 33 Deuterium ............................................................................... 34 Dichlorosilane ......................................................................... 35 Disilane ................................................................................... 36 Ethane .................................................................................... 37 Ethylene ................................................................................. 38 Germane ................................................................................ 39 Halocarbon 14 ........................................................................ 40 Halocarbon 23 ........................................................................ 41 Halocarbon 32 ........................................................................ 42 Halocarbon 41 ........................................................................ 43 Halocarbon 116 ..................................................................... 44 Halocarbon 125 ...................................................................... 45

Gas MixturesIntroduction ............................................................................ 80 Unique SCOTT Technology ................................................. 84 Gas and Liquid Mixtures Typical Specifications ...................... 86 RATA and Compliance Class ............................................... 88 Reference Class .................................................................. 91 ACUBLEND Master Class ................................................... 93 Certified Class ..................................................................... 95 Custom Class ...................................................................... 98 Two-Component Mixtures ...................................................... 99 Acetaldehyde ...................................................................... 99 Acrylonitrile .......................................................................... 99 Ammonia .......................................................................... 100 Argon ................................................................................ 102 Benzene ........................................................................... 104 n-Butane ........................................................................... 105 Carbon Dioxide ................................................................. 106

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Table of Contents continuedCarbon Disulfide ............................................................... 108 Carbon Monoxide ............................................................. 109 Carbonyl Sulfide ................................................................ 111 Chlorine ............................................................................ 112 Dimethyl Disulfide .............................................................. 112 Dimethyl Sulfide ................................................................ 113 Ethane .............................................................................. 114 Ethanol ............................................................................. 115 Ethylene ............................................................................ 116 Ethylene Oxide .................................................................. 117 Formaldehyde ................................................................... 117 Halocarbon 12 .................................................................. 118 Helium .............................................................................. 119 n-Hexane .......................................................................... 120 Hydrogen .......................................................................... 121 Hydrogen Chloride ............................................................ 122 Hydrogen Cyanide ............................................................ 123 Hydrogen Sulfide .............................................................. 123 Isobutane .......................................................................... 125 Isobutylene ....................................................................... 126 Methane ........................................................................... 127 Methanol ........................................................................... 128 Methyl Mercaptan ............................................................. 129 Nitric Oxide ....................................................................... 130 Nitrogen ............................................................................ 131 Nitrogen Dioxide ............................................................... 132 Nitrous Oxide .................................................................... 134 Oxygen ............................................................................. 135 n-Pentane ......................................................................... 136 Propane ............................................................................ 137 Propylene .......................................................................... 139 Styrene ............................................................................. 140 Sulfur Dioxide .................................................................... 141 Sulfur Hexafluoride ............................................................ 143 Toluene ............................................................................. 144 Vinyl Chloride .................................................................... 145 Moisture Standards ........................................................... 146 Acid Rain CEM Zero Gases .................................................. 159 PROTOCOL ELEVEN Hydrogen Sulfide ............................ 159 Hydrogen Sulfide Multi-Component Mixtures ....................... 160 CEM DAILY STANDARDS ................................................. 161 Two-Component ............................................................... 161 Three-Component ............................................................ 163 Four-Component .............................................................. 164 Five-Component ............................................................... 167 Mercury Verification Product ................................................. 167 Method TO Calibration Standards ........................................ 168

Engine Emissions TestingIntroduction .......................................................................... 174 Program Compliance ........................................................... 174 Pure Air ................................................................................. 175 Pure Nitrogen ....................................................................... 176 Calibration Standards ............................................................ 177 Two-Component ............................................................... 177 Three-Component ............................................................ 178 Four-Component .............................................................. 179 Five-Component ............................................................... 180

Refining, Petrochemical and Natural GasIntroduction .......................................................................... 182 Liquid Mixtures ..................................................................... 183 Hydrocarbon Chromatographic Standards ........................... 185 PIANO Calibration Standards ............................................... 188 Natural Gas Standards ......................................................... 194 Moisture Standards .............................................................. 198

Process MixturesKill Gas ................................................................................. 200 Leak Detection Mixtures ....................................................... 201 Lighting Gases ..................................................................... 202 Molten Aluminum ................................................................. 204 Steel and Heat Treatment ..................................................... 205 Semiconductor Process Gases ............................................ 206

Environmental ComplianceIntroduction .......................................................................... 148 SCOTT EPA Protocol Methods ......................................... 149 EPA Protocol Gases ............................................................. 150 Two-Component ............................................................... 150 Three-Component ............................................................ 151 Four-Component .............................................................. 153 Five-Component ............................................................... 155 Low NOx EPA Protocol Gases ............................................. 156 Title V Ammonia Standards .................................................. 157 Hydrogen Chloride Mixtures ................................................. 158

Instrumentation ALPHAGAZ MIXElectron Capture .................................................................. 210 Flame Ionization Fuel ............................................................ 210 Furnace Gas ......................................................................... 211 Nuclear Counter ................................................................... 211 Spark Chamber Neon .......................................................... 212

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Table of Contents continuedSCOTTY Brand TransportablesIntroduction .......................................................................... 214 Cylinder Specifications ......................................................... 215 Recommended Regulators .................................................. 217 Calibration Kits ..................................................................... 218 Industrial Hygiene and Safety Applications ........................... 219 Two-Component ............................................................... 219 Three-Component ............................................................ 226 Four-Component .............................................................. 228 Five-Component ............................................................... 229 Laboratory Applications ........................................................ 230 Pure Gases ....................................................................... 230 Two-Component ............................................................... 231 Three-Component ............................................................ 238 Four-Component .............................................................. 239 Five-Component ............................................................... 240 Multi-Component Mixtures ............................................... 241 Lecture Bottle ................................................................... 294 SCOTTY ........................................................................ 296 Manifolds and Delivery Systems ........................................... 302 Cylinder Storage and Accessories ........................................ 312 Gas Distribution Panels ........................................................ 317 Flow Measurement ............................................................... 319 Valves ................................................................................... 328 Flexible Metal Hose .............................................................. 332 Traps .................................................................................... 333 Purifiers ................................................................................ 335 Filters .................................................................................... 336 Purge Assemblies ................................................................. 339 Heaters ................................................................................. 340 Flash Arresters ..................................................................... 340 Gauges ................................................................................ 341 Gas Detection ...................................................................... 343 Semiconductor and Electronics Applications ........................ 345

Services and Industry OfferingsIndustrial Gases .................................................................... 246 ARCAL ........................................................................... 246 BLUESHIELD ................................................................. 248 FLAMAL ......................................................................... 249 LASAL ........................................................................... 251 ALIGAL .......................................................................... 252 PHARGALIS .................................................................. 254 Additional Pure Gases ...................................................... 254 ISO/IEC 17025 Accreditation ............................................... 256 Solutions Center ................................................................... 256 SHOP@airliquide ............................................................... 257 SCOUT ............................................................................. 257 Global Cross Reference Service ........................................ 258 DATAL ............................................................................... 260 SCOTT Homeland Security ............................................... 260

Technical and Safety DataGas and Liquid Mixture Basics ............................................. 350 Compressed Gas Definitions ................................................ 355 Compressed Gas Categories ............................................... 356 Physical Properties of Gases ................................................ 360 Gas Compatibility ................................................................. 362 Special Precautions .............................................................. 365 Cylinder Storage, Handling and Usage ................................. 369 Returning Cylinders .............................................................. 371 Cylinder Valve Outlets and Connections ............................... 372 Conversion Factors .............................................................. 377 Periodic Table ....................................................................... 381

Glossary ............................................................................ 382 Sales Terms ...................................................................... 388 Index .................................................................................. 390

Gas Handling EquipmentIntroduction .......................................................................... 261 Cylinder Connections ........................................................... 262 Pressure Regulators ............................................................. 264 Single versus Two-Stage ................................................... 264 Performance Characteristics ............................................. 264 Regulator Selection ........................................................... 265 Regulator Selection Guide ................................................ 266 Maintenance Schedule ..................................................... 265 Brass ................................................................................ 268 Stainless Steel .................................................................. 271 Line ................................................................................... 274 Special Applications .......................................................... 275

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IntroductionEstablished in 1902, Air Liquide Group is the world leader in specialty, industrial and medical gases. With more than 43,000 employees and operating in 75 countries, we offer innovative solutions based on constantly enhanced technologies. Air Liquide maintains over 100 facilities in the United States and Canada. Our SCOTT gas and liquid mixtures are widely regarded as being the most accurate in the industry and our ALPHAGAZ pure gases have long been the global benchmark of quality. We also offer other exclusive brands of gas products for specialized industry applications such as semiconductor, food and beverage, pharmaceuticals, welding, auto emissions testing, laser cutting and many more. In addition to supplying the gases themselves, Air Liquide also offers related products and services to help our customers further improve their process control and achieve greater success in their respective marketplaces. Our SCOTT high-performance gas handling equipment provides years of trouble-free service, protects gas purity and integrity, and safely delivers it to your point-of-use. Other services such as SHOP@airliquide allow you simplify your purchasing and better manage your on-site cylinder inventory. Our Solutions Center stands ready to answer your technical questions or engineer custom products to solve unique applications challenges. Air Liquide operates numerous state-of-the-art specialty gas production facilities that are strategically located throughout North America to provide our customers with dependable, fast deliveryin most cases by our dedicated fleet of trucks. All of our specialty gas mixtures facilities are ISO 9001:2000 certified. Our laboratories are ISO/IEC 17025 accredited to assure our customers that our analytical and quality management procedures meet a universally prescribed level of proficiency and technical competency. Specialty Gases and related products and services

Air Liquides Delaware Research and Technology Center

Creating Innovative Technological Solutions Air Liquides global Research and Development network is at the forefront of our 100+ year commitment to innovation. Our recently constructed Research and Technology Center in Newark, Delaware (DRTC) is the eighth such facility to join our network that spans three continents and encompasses over 900 researchers and 10,000 patents. Cutting-edge research at our DRTC focuses on energy, sustainable environment, semiconductors, healthcare, agriculture, food and other industries in order to further strengthen our technological leadership.

Delivering true, measurable value to our customersDedicated Sales and Customer Service Staff We maintain a dedicated staff of localized, knowledgeable sales, business development and customer service team members who can answer questions, help you with problems and demonstrate to you how Air Liquide products and services can add measureable value to your bottom line. Technical Expertise We maintain a staff of scientific and technical team members who can answer technical questions and recommend Air Liquide products that will cost-effectively meet or exceed your application requirements. They will also help develop a custom product that meets unique applications needs. Safety and Product Information Resource We provide several venues for customers to obtain accurate and helpful safety and product information. Catalogs, brochures and datasheets are readily available in both printed and electronic form via our websites at www.us.airliquide.com and www.scottgas.com. We also periodically host webinars to provide safety and other timely information concerning various technical issues related to the use of specialty mixed and pure gases.

Emergency Response in US: 800.324.7814 in Canada: 514.878.1667Describe the nature of your problem and gases involved. We will have one of our emergency response coordinators contact you with information on how to safely handle the situation.

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AIR LIQUIDE AMERICA SPECIALTY GASES LLC

800.217.2688

SHOP@airliquide We offer an updated hybrid between eScott, the first and foremost cylinder management system pioneered by Scott Specialty Gases, and our own online purchasing/supply chain management system. We call this unique Internet-based management tool SHOP@airliquide. The end result goes far beyond mere online purchasing of the widest range of gas products available. SHOP provides tighter management control that helps you streamline administrative activities, provides resources to improve on-the-job safety, and boost profitability by eliminating excess cylinder inventory. For more information, visit [email protected] or see page 257. Packaging Alternatives Air Liquide delivers products in a wide range of sizes, from lecture bottles and nonreturnable, SCOTTY transportable cylinders to single and multi high-pressure cylinder packs, to tube trailers. Depending on your needs, we have packaging sizes that provide a costeffective quantity for any application. In addition, we offer exclusive innovations in specialty gas packaging, including our SCANDINA ergonomic cap, and SMARTOP and ALTOP valves that promote safety and improve ease-of-use. Due to safety issues and chemical characteristics, not all products are available in all forms of packaging. See pages 1 to 8 for available options. Cylinder Management Solutions We can provide total management of all cylinder activity at your site(s). This relieves you of the challenges of keeping track of cylinder stock and frees you to concentrate on other aspects of your business. Air Liquide cylinder management is linked to SHOP@airliquide and also can incorporate our DATAL wireless gas monitoring system. We can customize our program, resulting in substantial savings to you. Billing and Rental Options Air Liquide offers several different billing options that can save you time and money in reduced administrative costs. Electronic invoicing is particularly popular and cost-efficient. Cylinder rental options available include daily, monthly, or custom alternatives. In some cases and when safety considerations permit, we will even fill customer-owned cylinders so there are no rental charges. Global Cross Reference Program Comparing analytical results among a number of independent, separate laboratories yields true confirmation of accurate, analytical results. Air Liquide facilitates this confirmation by giving participating laboratories the opportunity to assess the accuracy of their measurements through comparison with other labs in the global community. Our Cross Reference Program, also known as Proficiency Testing (PT), promotes a high degree of confidence in the accuracy of your analyses as well as help identify potential problems in the accuracy of your analyses see page 258. ALNET Air Liquide maintains a network of distributor partners to extend the supply of our products to customers in areas where Air Liquide may not have an appropriate physical presence.

An Active Role in a New Energy Revolution Air Liquide has over 100 years of experience in hydrogen, starting with production and encompassing a wide range of hydrogen applications. This includes our active involvement in numerous transportrelated projects in both North America and Europe. Air Liquide contributes substantially to advancement of fuel storage and supply technologies, and to making cost-effective fuel cell-powered vehicles a reality.

Prototype vehicle refuels at Air Liquide hydrogen station

Cant find what you need? This catalog contains a reasonable representation of Air Liquide products and services that are commonly in demand. However, it does not reflect our total capabilities, nor does it reflect new products being developed as a result of emerging technologies and continued research and development. Thus, if you dont see what you need, if you are developing a new application that requires a new pure or mixed gas with unique characteristics, or even if you arent sure if one of our existing catalog products is what you need, call or email [email protected].

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Responsible CareThe American Chemistry Council launched Responsible Care in 1988 to respond to public concerns about the manufacture and use of chemicals. Air Liquide is committed to providing a safe, secure, and healthful workplace for its employees, and to being a good, environmentally friendly neighbor to the communities in which we operate and live.

We pledge to manage our business according to these principles

To recognize and respond to community concerns about chemicals and our operations. To develop and produce chemicals that can be manufactured, transported, used and disposed of safely. To make health, safety and environmental considerations a priority in our planning for all existing and new products and processes. To report promptly to officials, employees, customers and the public, information on chemical-related health or environmental hazards and to recommend protective measures. To counsel customers on the safe use, transportation and disposal of chemical products. To operate our plants and facilities in a manner that protects the environment and the health and safety of our employees and the public. To extend knowledge by conducting or supporting research on the health, safety and environmental effects of our products, processes and waste materials. To work with others to resolve problems created by past handling and disposal of hazardous substances. To participate with governmental and other regulatory bodies in creating responsible laws, regulations and standards to safeguard the community, workplace and environment. To promote the principles and practices of Responsible Care by sharing experiences and offering assistance to others who produce, handle, use, transport or dispose of chemicals. As a member of the American Chemistry Council, Air Liquide America is committed to support a continuing effort to improve the industrys responsible management of chemicals.

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PackagingCylinders for Every Application

Air Liquide provides a wide variety of cylinders selected to meet specific customer needs. In that we produce many gases with widely varying chemical characteristics, appropriate package offerings must be based on several key criteria. Safety The safety of each and every customer, as well as that of those who handle or transport our products, is of the utmost importance. Selection of the correct container and the proper valve is determined by guidelines from CGA, DOT and TC, as well as our own extensive experience and expertise. Stability Since specialty gases can be corrosive or reactive in nature, we carefully match cylinder and valve types in order to protect the integrity of the gas. To ensure gas mixture stability, reactive gases are only provided in cylinders treated with our exclusive suite of ACULIFE cylinder inerting processes see page 84 for more information. Customer Convenience For most gases, the choice of container depends upon your application requirements. We offer many different cylinders, as well as multi-cylinder packs, tube trailers or even cryogenic liquid containers for atmospheric and helium pure gases.

PACKAGINGCylinder Specifications

Cylinder SpecificationsThe following pages describe the many different cylinder options available for packaging of Air Liquide products. While most of our cylinders remain the property of Air Liquide, we also fill customer owned cylinders provided they meet all appropriate safety requirements.

Low-PressureCylinder Size 125 (formerly LG) 108 (formerly 110) 70 55 40LP (RS) 40LP AL(RS) 22LP (RS) 22LP AL(RS) 11LP (RS) 11LP AL(RS)* Without valve. ** With valve, nominal. Acetylene cylinder with acetone. Nominal. (RS) Resale cylinder only.

DOT Specification 4AA 4BA 8AL 4BA 4BA 4E 4BA 4E 4BA 4E

Service Pressure psig 480 260 250 300 240 240 240 240 240 240

Approximate Capacity Gas at STP cu. ft. 144 70 419 40 28 26 13 13 7 7 liters 4076 1982 11865 1121 786 722 368 368 200 200

Outside Diameter inches 15 15 12 10 12 12 12 12 9 10

Height* inches 54.5 45 42 51 32.5 32 18 21 17 16

Tare Weight** lbs. 159 73 182 56 34 21 22 14 16 11

Internal Water Volume cu. in. 7628 6712 4271 3356 2868 2624 1342 1342 732 732 liters 125 110 70 55 47 43 22 22 12 12

65" 60" 55" 50" 45" 40" 35" 30" 25" 20" 15" 10" 5" 125 2 125 108 108 7 70 55 40LP 40 40LP AL 40LP 0L 22 22LP 22LP 22LP AL 22LP 2 11LP 11 1LP 11LP AL P

Cylinder Comparison ChartAir Liquide 125 108 70 40LP 40LP AL 22LP 22LP AL 11LP 11LP AL Scott XG XL XF 5LP 5LP AL 2.5LP 2.5LP AL Airgas 400 350 380 25 Linde 126 350 110 L60 L20 Matheson 1K 1F 1B Praxair FS FX A8

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PACKAGINGCylinder Specifications

Cylinder Specifications continuedHP SteelCylinder Size 50 49 44 44H 44HH 16 7 3 LB/LBX (NR) DOT Specification 9809-1*** 3AA 3AA 3AA 3AA 3AA 3AA 3AA 3E Service Pressure psig 2900 2400 2265 3500 6000 2015 2015 2015 1800 Approximate Capacity cu. ft. 335 277 232 338 433 76 33 14 2 liters 9373 7844 6570 9571 12261 2152 934.6 396.5 53.8 Outside Diameter inches 9 9.25 9 10 10 7 6.25 4.25 2 Height* inches 58.2 55 51 51 51 32.5 18.5 16.75 12 Tare Weight** lbs. 130 143 133 189 303 63 28 11 3.5 Internal Water Volume cu. in. 3051 2990 2685 2607 2383 976 427 183 27 liters 50 49 44 44 43 16 7 3 0.4

* Without valve. ** With valve, nominal. *** UN/ISO specification. For N2 at 70F 1 atm. Nominal. (NR) Nonreturnable cylinder. Price of cylinder included in the price of gas. Note: LBX is an LB cylinder with a CGA valve other than 170 or 180.

65" 60" 55" 50" 45" 40" 35" 30" 25" 20" 15" 10" 5" 50 0 49 9 44 4 44H H 44HH 44HH 4 16 7 3 LB/ LB/LBX(NR)

Cylinder Comparison ChartAir Liquide 49 44 44H 44HH 16 7 3 LB LBX Scott K A B C LB Airgas 300 200 3HP 80 35 LB LX Linde 049 (T) 044 (K) 485 016 (Q) 007 (G) 3 LBR (LB) Matheson 1L 1A 1H 1U 2 3 4 LB 7X Praxair T/UT K/UK 3K 6K Q/UQ G/UG F LB/RB EB

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PACKAGINGCylinder Specifications

Cylinder Specifications continuedHP AluminumCylinder Size 47AL 30AL 16AL 7AL 3AL (RS) 1AL (RS)* Without valve. ** With valve, nominal. For N2 at 70F 1 atm. Nominal. (RS) Resale cylinder only.

DOT Specification 3AL 3AL 3AL 3AL 3AL 3AL

Service Pressure psig 2216 2015 2216 2216 2015 2216

Approximate Capacity cu. ft. 244 141 83 31 8 5 liters 6909 3993 2350 878 227 142

Outside Diameter inches 9.8 8 7.25 6.9 4.4 3.2

Height* inches 51.9 47.9 33 15.6 10.5 11.7

Tare Weight** lbs. 90 48 30 15 3.5 2.3

Internal Water Volume cu. in. 2831 1800 958 360 103 61 liters 46.4 29.5 15.7 5.9 1.7 1

65" 60" 55" 50" 45" 40" 35" 30" 25" 20" 15" 10" 5" 47AL L 30AL 30A AL 16AL 16A AL 7AL 7A AL 3 L 3AL(RS) 1A 1AL(RS) AL

Cylinder Comparison ChartAir Liquide 47AL 30AL 16AL 7AL 3AL 1AL Scott KAL AL BL CL Airgas 150A 80A 33A Linde A31 A16 A07 Matheson 1R 2R 3R Praxair AT AS AQ AG A3

CryogenicCylinder Size 230-VGL 180-VGL 160-VGL DOT Specification 4L 4L 4L

Service Pressure psig 230 230 230

Approximate Capacity cu. ft. 5921 4835 4486 liters 167665 136913 127030

Outside Diameter inches 26 20 20

Height inches 57 64 60

Tare Weight lbs. 324 260 250

Internal Water Volume cu. in. 14646 11961 10740 liters 240 196 176

Additional delivery pressures are available. Approximate gas volume for oxygen for VGLs.

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PACKAGINGCylinder Specifications

Cylinder Specifications continuedHelium DewarsDewar Size 500 250 100 60* Nominal.

DOT Specification N/A N/A N/A N/A

Service Pressure psig 12 12 12 12

Approximate Capacity, Liquid cu. ft. 18 9 4 2 liters 500 250 100 60

Outside Diameter inches 42 32 24 24

Height inches 71 67 59 50

Tare Weight* lbs. 480 348 212 184

Internal Water Volume* cu. in. 33563 17392 6957 4028 liters 550 275 110 66

PacksNumber of Cylinders 16 6* Nominal.

DOT Specification 3AA 3AA

Service Pressure psig 2400 2265

Approximate Capacity cu. ft. 4432 1392 liters 125501 39417

Width x Depth x Height inches 41 x 41 x 79 31 x 20 x 73

Tare Weight* lbs. 2650 870

Internal Water Volume* cu. in. 47843 16110 liters 784 264

PistonCylinder Size 300 500 1000* Nominal.

DOT Specification E-7657 E-7657 E-7657

Service Pressure psig 1800 1800 1800

Approximate Capacity cu. in. 18.3 30.5 61 liters 0.3 0.5 1

Outside Diameter inches 3 3 3

Width inches 12.8 17.2 30.7

Length inches 18 22.4 35.9

Internal Water Volume* cu. in. 18.3 30.5 61 liters 0.3 0.5 1

Tube TrailersNumber of Tubes 30 34 38 49 55 10 7 9

Tube Trailer Length feet 21 21 21 21 34 34 40 40

Tube Outside Diameter inches 9-5/8 9-5/8 9-5/8 9-5/8 9-5/8 22 22 22

Air SCF 46,361 51,438 57,270 74,486 136,852 116,122 149,149

Argon SCF 45,330 50,294 55,996 72,830 133,808 133,894 112,539 145,832

Helium SCF 43,670 48,453 53,947 70,164 128,910 128,993 109,383 140,494

Hydrogen SCF 43,038 47,751 53,165 69,147 127,043 127,124

Nitrogen SCF 45,623 50,619 56,359 73,302 134,675 134,761 114,275 146,776

Oxygen SCF 43,322 48,066 53,516 69,604 127,881 127,881 108,510 139,372

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PACKAGINGSMARTOP with SCANDINA Cap

Exclusive SMARTOPand SCANDINA CapSimplifies gas handling and improves safety. Available with ALPHAGAZ 1 and ARCAL gases. SCANDINA caps are available for EPA protocol gases.

Ergonomic design makes it easy to maneuver the cylinder Fixed shock-absorbing SCANDINA cap provides added safety during transport, service and use

ON/OFF lever closes quickly in an emergency and provides unmistakable indication of valve status

Improve Safety, Save Time and Money

Attach pressure regulator, flip up lever and you're ready to go

Positive ON/OFF lever prevents wasted gas due to partially closed traditional style valves. Visual reading of cylinder contents without having to attach a regulator prevents accidental return of half-full cylinders. Visual ID of valve status prevents valves left open during breaks and off business hours. Handle cylinder faster and more easily. Open and close valve with a single action. Permanent cylinder pressure/content display allows more efficient management of gas inventory.

View pressure of cylinder at a glance without use of a regulator Built-in flow restriction provides protection against accidental gas line breach

Built-in Residual Pressure Valve (RPV) prevents backflow contamination during use and storage Open design minimizes insect nesting

Eliminates the need to remove or replace cylinder caps no more lost or stuck caps.Accepts all SCOTT single and two-stage pressure regulators.

Air Liquide inspects and verifies proper function of SMARTOP at every cylinder refill.

SCOTT brand regulators work perfectly with our SMARTOP. See the Equipment section of this catalog for a complete selection of single-stage and two-stage pressure regulators in brass and stainless steel. All regulators may be purchased online, with same-day shipping on most.

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PACKAGINGALTOP for Industrial Gases

Exclusive ALTOPWith Built-In Regulator for Industrial GasesFor ARCAL pure argon and argon mixtures, the unique Air Liquide ALTOP features a fixed ergonomic safety cap with a fully integrated pressure regulator and easy-to-use ON/OFF lever-activated valve. ALTOP provides improved cylinder handling and safety in an innovative, easy-to-use design that increases on-the-job efficiency while reducing overall costs.Ergonomic design makes it easy to maneuver the cylinder Fixed shock-absorbing cap permanently protects valve and regulator from damage

Improve Safety Save Time and Money

No more regulators to buy or maintain. Eliminates downtime due to regulator damage. Positive ON/OFF lever prevents wasted gas due to partially closed traditional style valves. Visual reading of cylinder flowrate prevents accidental return of half-full cylinders.

ON/OFF lever opens valve quickly and provides unmistakable indication of valve status Built-in regulator* controls flow of gas and eliminates accidental exposure to high-pressure gas flow View pressure of cylinder at a glance without opening valve

Position cylinder faster and more easily.Shock-absorbing cap protects against accidental injury if cylinder falls.

Built-in check valve prevents backflow contamination during use and storage

Allows quick connection of hoses to outlet fitting

Air Liquide verifies proper function of regulator during each cylinder refill.

* Regulator rated up to 2900 psig (200 bar)

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PACKAGINGALTOP Lab for Specialty Gases

Exclusive ALTOP LabWith Built-In Stainless Steel Pressure RegulatorAvailable soon on small cylinders of calibration mixtures, our ALTOP Lab features a fully integrated pressure regulator, pressure gauges, ON/OFF knob, and preset and prepurged valve. It also includes a fixed ergonomic and shock-absorbing protective housing that makes it easier and safer to handle and move the cylinder.Ergonomic design makes it easy to maneuver the cylinder

Improve Safety, Save Time and Money

No more regulators to buy or maintain. Eliminates downtime due to regulator malfunction. Positive ON/OFF knob prevents wasted gas due to partially closed traditional style valves. Handle cylinder faster and more easily. Shock-absorbing cap protects against accidental injury if cylinder falls. Visual reading of cylinder contents prevents accidental return of half-full cylinders.

Built-in regulator* controls gas pressure without add-on regulator Positive ON/OFF and ergonomic knob opens and closes valve quickly Built-in high and low-pressure gauges show pressure at a glance

Stainless steel valve and connection tube for use with corrosive gases and low concentration reactive mixtures

Safety Note Move small, portable cylinders with care. Do not drop or hand carry cylinders over long distances. Use other means of transport such as a wagon or cart when appropriate.

Shock-absorbing housing protects valve and regulator; fixed design eliminates hard-to-remove or lost caps

Allows quick connection of hose to outlet fitting

Built-in Residual Pressure Valve (RPV) prevents backflow contamination during use and storage

Air Liquide verifies proper function of regulator during each cylinder refill.

* Regulator rated up to 2900 psig (200 bar)

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AIR LIQUIDE AMERICA SPECIALTY GASES LLC

800.217.2688

PuresAnd Other Support Gases

Air Liquide is one of the largest producers of pure gases globally. Because we produce most of these gases ourselves, we closely control the consistency and quality of each gas. Our customers can be sure of getting the best quality possible for every pure gas we deliver. We offer three grades of ALPHAGAZ pure products with specifications that meet typical application requirements and enable you to reduce the number of various pure gas cylinders you must keep on site. Three grades of CHEMGAZ products standardize grade selections for process gases as well as simplify your ordering process. Three electronic grades support a wide range of semiconductor, optoelectronic and other electronic applications, while our application-specific products provide additional application versatility.

Included in this section

ALPHAGAZ CHEMGAZ Electronic Grade Application-Specific Grades

PURES AND OTHER SUPPORT GASESALPHAGAZ Pure Gases

ALPHAGAZ Pure GasesChoosing the right gas products for a particular analytical instrument and application can be confusing. Air Liquide has simplified gas selection by reducing the complex and confusing matrix of available gas grades down to two levels of purity as represented in our ALPHAGAZ product line. Instead of focusing on the total purity of the gas, we set limits on the critical impurities that affect the performance of the instrument and application used.

Three Grades, Two Purity RangesAn Air Liquide research and development team surveyed major analytical instrument manufacturers to determine the recommended gas purity for their instrumentation. Studies were then conducted on many of these instruments to determine the effect of varying levels of impurities on their performance. Our findings indicated that two basic ranges for gas purity are necessary to ensure optimal performance of analytical instruments in most applications. ALPHAGAZ 2: The Highest Purity Level Possible ALPHAGAZ 2 products exhibit the absolute lowest impurity levels available in the industry, making them the best choice for laboratory, analytic and process control applications where uncompromised ultra-high-purity is needed. ALPHAGAZ 1: One Convenient Grade for Many Applications ALPHAGAZ 1 products exceed purity recommendations of most laboratory instrument manufacturers, making them an obvious choice for all-around use in the laboratory. Because they provide guaranteed low impurity levels, ALPHAGAZ 1 pures are ideal for most analytic and process control applications, including petrochemical, secondary electronics and optoelectronics as well as scientific research and many other applications. ALPHAGAZ 1000: Cryogenic Solutions ALPHAGAZ 1000 provides the same specifications as ALPHAGAZ 1, but is offered for those applications requiring cryogenic liquid argon, nitrogen and helium. Since large volumes of gaseous nitrogen or argon are needed for ICP and FTIR instruments, cryogenic supplies can be better suited than cylinders of compressed gas to fill this need. Liquid helium is often used to cool magnets in instruments such as NMR spectrophotometers.

Our customers get the best quality possible for every pure gas we deliver

The SMARTOP Cylinder Valve Exclusively from Air Liquide

Positive ON/OFF lever action prevents gas leaks common to traditional valves. ON/OFF lever opens and closes valve quickly in a single action and provides positive visualization of valve status. Built-in pressure gauge shows cylinder contents at a glance without having to open the valve. Air Liquide verifies proper function during each refill. Built-in gas flow restriction gives added protection in the event of accidental gas line breach.

Ergonomic SCANDINA cap improves cylinder handling safety.

Benefits and Features

Guaranteed low impurity levels protect instrument sensitivity ensuring peak performance. Residual Pressure Valve (RPV) integrated to prevent atmospheric contamination. Cylinder-to-cylinder consistency provides added performance reliability. Helps reduce cylinder inventory by eliminating need for supplemental pure gases. Color-coded cylinder shoulders for fast, positive visual ID of cylinder contents. Weatherproof and tear-resistant identification label on each cylinder or pack accurately indicates impurities. Lot number on each cylinder is traceable to our analytical records for added reliability. Exclusive SCANDINA cap and SMARTOP valve (see sidebar).

ALPHAGAZ Packaging Options

Lecture bottles Single high-pressure cylinders 6-pack of high-pressure cylinders 16-pack of high-pressure cylinders Tube trailers

VGLs

Not all products are available in all packages. Weight shown for all pure gases is gross weight.

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AIR LIQUIDE AMERICA SPECIALTY GASES LLC

800.217.2688

PURES AND OTHER SUPPORT GASESALPHAGAZ Specifications

ALPHAGAZ SpecificationsProduct Air Grade ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 1000 ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 1000 ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 1000 ALPHAGAZ 2 ALPHAGAZ 1 ALPHAGAZ 1 Purity % NA NA 99.9995 99.999 99.999 99.9998 99.999 99.999 99.9998 99.999 99.9998 99.999 99.999 99.9995 99.999 99.99 CO2 ppm