7 reagents
DESCRIPTION
reagentsTRANSCRIPT
Name Formula
Magnesium Sulfate, Anhydrous
Sodium Chloride NaClWater
Acetone
Hydrochloric Acid HCl
Dichloromethane (Methylene chloride)
Sucrose
Aspirin (Acetylsalicylic Acid, ASA)
Acetanilide
Phenacetin
Acetaminophen
MgSO4
H2O
C3H6O
Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3
CH2Cl2
C12H22O11
C9H8O4
C8H9NO or CH3CONHC6H5
C10H13NO2
C8H9NO2
MW (g/mol) MP (°C) BP (°C)
120.37 (SA)
58.44 (SA) 801 (SA) 1413 (SA)18.02 (SA) 0.0 (SA) 100 (SA)
58.08 (SA) MP -94 (SA) 56 (SA)
36.46 (SA) MP -30 (SA)
84.01 (SA) 300 (SA) decmp
84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)
342.30 (SA) 185-187 (SA)
180.16 (SA) 134-136 (SA)
135.2 (NB) 114 (NB) 304-305 (NB)
179.2 (NB) 135 (NB)
151.16 (SA) 168-172 (SA)
>100 (SA)
Decomposes (ScienceLab)
Density (g/ml) Flammability
2.66 Non-Flammable (SA)
2.165 (SA) Non-Flammable (SA)
Highly Flammable (SA)
Non-Flammable (SA)
2.160 (SA) Non-Flammable (SA)
Non-Flammable (SA)
1.587 (ScienceLab)
1.35 (ScienceLab) Non-Flammable (SA)
1.219 (NB)
1.293 (ScienceLab) Non-Flammable (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
1.18 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
Solubility Toxicity
Soluble in Water (SA) LD50 3,550mg/kg (Oral Rat) (SA)
LD50 5,800mg/kg (Oral, Rat) (SA)
Soluble in Water (SA)
LD50 4220 mg/kg (Oral, Rat) (SA)
Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)
LD50 29,700mg/kg (Oral, Rat) (SA)
LD50 1500mg/kg (Oral, Rat) (SA)
LD50 800mg/kg (Oral, Rat) (ScienceLab)
LD50 1650mg/kg (Oral, Rat) (SA)
LD50 1944mg/kg (Oral, Rat) (SA)
26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.h
tm)
2.6g/100mL H2O (SA)
50g/L H2O(SA)
342g/L H2O at 20°C - Completely Soluble (SA); Insoluble in Dichloromethane (NB)
Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble
in cold water (ScienceLab)
0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB)
0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB)
Safety/Comments
Hygroscopic (SA)
No Known OSHA Hazards (SA)No Known OSHA Hazards (SA)
No Known OSHA Hazards (SA)
No Known OSHA Hazards (SA)
Irritant, Harmful on Ingestion (SA)
Irritant - Minimize Contact (NB)
Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA)
Harmful by Ingestion, Irritant (SA)
Notes on Source of Information
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood
ACS Reagent 37% MSDS from SA
May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Name Formula
Water
Acetone
Dichloromethane (Methylene chloride)
Acetanilide
Phenacetin
Sucrose
Aspirin (Acetylsalicylic Acid, ASA)
H2O
C3H6O
CH2Cl2
C8H9NO or CH3CONHC6H5
C10H13NO2
C12H22O11
C9H8O4
MW (g/mol) MP (°C) BP (°C)
18.02 (SA) 0.0 (SA) 100 (SA)
58.08 (SA) MP -94 (SA) 56 (SA)
84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)
135.2 (NB) 114 (NB) 304-305 (NB)
179.2 (NB) 135 (NB)
342.30 (SA) 185-187 (SA)
180.16 (SA) 134-136 (SA)
Decomposes (ScienceLab)
Density (g/ml) Flammability
Highly Flammable (SA)
Non-Flammable (SA)
1.219 (NB)
1.587 (ScienceLab)
1.35 (ScienceLab) Non-Flammable (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
Solubility Toxicity
LD50 5,800mg/kg (Oral, Rat) (SA)
Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)
LD50 800mg/kg (Oral, Rat) (ScienceLab)
LD50 1650mg/kg (Oral, Rat) (SA)
LD50 29,700mg/kg (Oral, Rat) (SA)
LD50 1500mg/kg (Oral, Rat) (SA)
2.6g/100mL H2O (SA)
0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB)
0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB)
342g/L H2O at 20°C - Completely Soluble (SA); Insoluble in Dichloromethane (NB)
Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble
in cold water (ScienceLab)
Safety/Comments
No Known OSHA Hazards (SA)
Irritant - Minimize Contact (NB)
Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA)
No Known OSHA Hazards (SA)
Irritant, Harmful on Ingestion (SA)
Notes on Source of Information
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Name Formula MW (g/mol)
Water 18.02 (SA)
Acetone 58.08 (SA)
Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB)
Ethyl acetate 88.11 (SA)
Hexanes 86.18 (SA)
Anthracene 178.23 (SA)
Cholesterol 386.65 (SA)
1,4-napthoquinone 158.15 (SA)138.12 (SA)
Ferrocene 186.03 (SA)
Acetylferrocene 228.07 (SA)
1,1'-Diacetylferrocene 270.10 (SA)
Silica Gel
Iodine 253.81 (SA)
Sand
H2O
C3H6O
CH2Cl2
C4H8O2
C6H14
C14H10
C27H46O
C10H6O2
para-nitroaniline C6H6N2O2
C10H10FeC12H12FeO
C14H14FeO2
SiO2 X H2O 60.09 + xH2Og/mol (ScienceLab)
I2
SiO2
MP (°C) BP (°C) Density (g/ml)
0.0 (SA) 100 (SA)
MP -94 (SA) 56 (SA)
MP -97 (NB) 39.8-40 (SA); 40 (NB)
MP -84 (SA) 76.5-77.5 (SA)
MP -95 (SA) 69 (SA)
210-215 (SA) 340 (SA)
147-149 (SA) 360 (SA)
119-122 (SA) 1.422 (ScienceLab)146-149 (SA) 260 at 100mmHg (SA) 1.44 (SA)172-174 (SA) 249 (SA)
81-83 (SA)
125-127 (SA)
2.1 (ScienceLab)
113 (SA) 184 (SA) 4.930 (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
0.902 at 25°C (SA)
0.659 at 25°C (SA)
1.25-1.28 (Fisher http://fscimage.fishersci.com/msds/96670.htm)
1.067 at 25°C (SA)
1.8 to 2.5 Depending on Mineral Composition (ScienceLab)
Flammability Solubility
Highly Flammable (SA)
Non-Flammable (SA) Slightly Soluble in Water (SA)
Highly Flammable (SA) Water soluble (SA)
Highly Flammable (SA) Water Insoluble (SA)
Non-Flammable (SA) Insoluble in Cold Water (ScienceLab)
Non-Flammable (SA)
Water Soluble (SA)Non-Flammable (SA) Slightly Soluble in Water (SA)
Flammable (SA) Insoluble in Cold Water (ScienceLab)Non-Flammable (SA)
Non-Flammable (ScienceLab)
Non-Flammable (SA)
Non-Flammable (ScienceLab)
2.6g/100mL H2O (SA)
Soluble in Diethyl ether and Acetone. Very slightly soluble in Alcohol and Cold Water.
Solubility in Water 0.2mg/100mL H2O (ScienceLab)
Insoluble in Water (http://fscimage.fishersci.com/msds/10307.h
tm)
Insoluble in Cold Water. Soluble in Hot KOH and MaOH solutions. Insoluble in Ethanol and Acids, except Hydrofluoric Acid (ScienceLab)
Easily Soluble in Diethyl ether. Soluble in Methanol. Very Slightly Soluble in Water.
(ScienceLab)
Insoluble in Water, Methanol, Diethyl Ether, and n-Octanol. (ScienceLab)
Toxicity
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
LD50 5620mg/kg (Oral, Rat) (SA)
LD50 25,000mg/kg (Oral Rat) (SA)
LD50 190mg/kg (Oral, Rat) (SA)LD50 750mg/kg (Oral, Rat) (SA)
LD50 1320mg/kg (Oral, Rat) (SA)LD50 50mg/kg (Oral, Mouse) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
LD50 >31600mg/kg (Oral, Rat) (ScienceLab)
LD50 14,000mg/kg (Oral, Rat)
LD50 4900mg/kg (Oral, Mouse) (Fisher http://fscimage.fishersci.com/msds/96670.htm)
Safety/Comments
No Known OSHA Hazards (SA)
Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood
Carcinogen, Irritant (SA)
Irritant and Permeator (ScienceLab)
Highly Toxic by Inhalation, Toxic by Ingestion, Irritant. (SA) Work in Hood.Toxic by Inhalation, Toxic by Ingestion, and by Skin Absorption (SA)Harmful by Ingestion (SA)Highly Toxic by Ingestion - Fatal if Swallowed (SA)
Hamful by Ingestion. Hamful on contact with skin. (SA)
Slight Irritant (ScienceLab)
Notes on Source of Information
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood
Anhydrous Hexanes MSDS from SA
Carcinogen, Harmful to Respiratory Tract due to its Super Fine Nature. Do not stir silica gel excessively or breath in dust. Work in Hood. (Ghurbanyan Supplement)
Toxic by Inhalation. Harmful by Skin Absorption. Skin Sensitiser. Corrosive. (SA)
D Formula MW (g/mol) MP (°C)
Water 18.02 (SA) 0.0 (SA)
Acetone 58.08 (SA) MP -94 (SA)
Diethyl Ether (ethyl ether, ether) 74.1 (NB) MP -116 (NB)
Methanol (methyl alcohol) 32.0 (NB) MP -94 (NB)
136.23 (SA) 127 (NB)
Maleic Anhydride 98.1 (NB) 53 (NB)
H2O
C3H6O
C4H10O
CH3OH
α-Phellandrene (5-isopropyl-2-methyl-1,3-cyclohexadiene) C10H16
C4H2O3
BP (°C) Density (g/ml) Flammability
100 (SA)
56 (SA) Highly Flammable (SA)
34.5 (NB) 0.714 (NB)
65 (NB) 0.791 (NB) Highly Flammable (SA)
175 (MerckMillpore) Flammable and Combustible (SA)
202 (NB) Non-Flammable (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
Flammable (SA), Extremely Flammable (NB)
0.85 at 25°C (SA)
Solubility Toxicity
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1215mg/kg (Oral, Rat) (SA)
LD50 1187-2769mg/kg (Oral, Rat) (SA)
LD50 5700mg/kg (Oral, Rat) (Merck Millpore)
LD50 400mg/kg (Oral, Rat)
2.6g/100mL H2O (SA)
65g/L H2O at 20°C (SA)
Completely Miscible with Water (SA)
2.86mg/L H2O at 25°C (Merck Millpore)
Soluble in Cold and Hot Water. Very slightly soluble in
Methanol. (ScienceLab)
Safety/Comments
No Known OSHA Hazards (SA)
Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA)
Harmful by Ingestion. Respiratory Sensitiser. Irritant. (SA) Work in Hood.
Notes on Source of Information
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.
Corrosive. Can cause severe damage to eyes, skin, and upper respiratory tract. Avoid contact. Do not breath dust. Work in Hood (NB)
Name Formula MW (g/mol) MP (°C)
Water 18.02 (SA) 0.0 (SA)
Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)
Acetic Anhydride 102.1 (NB) MP -73 (NB)
Aluminum chloride 133.3 (NB) 193 (NB)
Sodium Hydroxide NaOH 40.00 (SA) 318 (SA)
Magnesium Sulfate, Anhydrous 120.37 (SA)
Sodium Chloride NaCl 58.44 (SA) 801 (SA)
Hydrochloric Acid HCl 36.46 (SA) MP -30 (SA)
Anisole 108.2 (NB) MP -38 (NB)
4'-Methoxyacetophenone 150.2 (NB) 39 (NB)
Acetone 58.08 (SA) MP -94 (SA)
H2O
CH2Cl2
C4H6O3
AlCl3
MgSO4
C7H8O
C9H10O2
C3H6O
BP (°C) Density (g/ml) Flammability
100 (SA)
39.8-40 (SA); 40 (NB) Non-Flammable (SA)
140 (NB) 1.082 (NB) Flammable (SA)
Sublimes (NB) 2.4400 (SA) Non-Flammable (SA)
1390 (SA) 2.1300 (SA) Non-Flammable (SA)
2.66 Non-Flammable (SA)
1413 (SA) 2.165 (SA) Non-Flammable (SA)
Non-Flammable (SA)
155 (NB) 0.996 (NB)
258 (NB) 1.082 (NB) Non-Flammable (SA)
56 (SA) Highly Flammable (SA)
1.000 at 3.98°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
>100 (SA) 1.18 at 25°C (SA)
Flammable and Combustible (SA)
0.791 at 25°C (SA)
Solubility Toxicity
Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)
LD50 1780mg/kg (Oral, Rat) (SA)
LD50 3450mg/kg (Oral, Rat) (SA)
Soluble in Water (SA) LD50 3,550mg/kg (Oral Rat) (SA)
Soluble in Water (SA)
LD50 3700mg/kg (Oral, Rat) (SA)
LD50 1720mg/kg (Oral, Rat) (SA)
LD50 5,800mg/kg (Oral, Rat) (SA)
26g/100L H2Oat 0°C (http://fscimage.fishersci.com/
msds/13510.htm)
Insoluble in Water. Soluble in Ethanol, Diethyl ether, and Acetone-Like Solvents. (SA)
2.474g/L H2O at 20°C (SA)
2.6g/100mL H2O (SA)
Safety/Comments
No Known OSHA Hazards (SA)
Corrosive (SA)
Hygroscopic (SA)
No Known OSHA Hazards (SA)
Irritant. (SA)
Harmful by Ingestion. Irritant. (SA)
Notes on Source of Information
May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant - Can Cause Severe Damage to Skin and Eyes. Use Gloves and Avoid Contact. Vapors are Harmful if Inhaled. Do Not Breath Vapors. Reacts Violently with Water. Keep away from Water. (NB) Work in Hood
Reacts with Atmospheric Moisture and Violently with Water to Generate HCl Vapors - Keep away from Water. Can cause painful burns on moist skin and eyes - Avoid Contact. Do not inhale dust or vapors, which can damage respiratory tract. (NB) Work in Hood
Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood
ACS Reagent 37% MSDS from SA
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)
Name Formula MW (g/mol) MP (°C)
114.2 (NB) MP -38 (Acros)
85% Phosphoric Acid 40 (SA)
84.01 (SA) 300 (SA)
Calcium Chloride, Anhydrous (Beads) 110.98 (SA) 772 (SA)
Bromine 159.81 (SA) 7.2 (SA)
Carbon Tetrachloride 153.82 (SA) MP -23 (SA)
Potassium Permanganate, Aqueous 1% 158.03 (SA) 240 (SA)
Ethanol 46.07 (SA) MP -114 (SA)
Water 18.02 (SA) 0.0 (SA)
Acetone 58.08 (SA) MP -94 (SA)
1-Methylcyclohexene 96.2 (NB)
3-Methylcyclohexene 96.2 (NB)
Methylenecyclohexane 96.17 (SA)
Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)
2-methylcyclohexanol (Cis and Trans Isomers) C7H14O
H3PO4
98.0 (NB for Pure Acid); 85% Phosphoric Acid is ~14.7M
(NB)
Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3
CaCl2
Br2
CCl4
KMnO4
C2H6O
H2O
C3H6O
C7H12
C7H12
C7H12
CH2Cl2
BP (°C) Density (g/ml) Flammability Solubility
166 (NB) 0.930 (NB)
158 (SA) 1.70 (NB); 1.685 (SA) Non-Flammable (SA)
decmp 2.160 (SA) Non-Flammable (SA)
1670 (SA) 2.150 (SA) Non-Flammable (SA)
58.8 (SA) 3.119 (SA) Non-Flammable (SA)
76-77 (SA) 1.594 (SA) Non-Flammable (SA)
2.710 (SA) Non-Flammable (SA)
78.3 (SA) 0.789 (SA) Flammable (SA)
100 (SA)
56 (SA) Highly Flammable (SA)
110 (NB) 0.813 (NB) Flammable (NB)
104 (NB) 0.801 (NB) Flammable (NB)
102-103 (SA) Flammable (SA)
39.8-40 (SA); 40 (NB) Non-Flammable (SA) Slightly Soluble in Water (SA)
Flammable and Combustible (SA)
Slighlty Soluble in Water (Acros)
Easily Soluble in Hot and Cold Water (ScienceLab)
50g/L H2O(SA)
36.5g/L H2O at 20°C
0.8461g/L H2O at 20°C (SA)
Completely Water Soluble (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA) 2.6g/100mL H2O (SA)
0.8 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
Toxicity Safety/Comments
LD50 1530mg/kg (Oral, Rat) (ScienceLab)
LD50 4220 mg/kg (Oral, Rat) (SA) No Known OSHA Hazards (SA)
LD50 2301 (Oral, Rat) (SA) Irritant (SA)
LD50 2600mg/kg (Oral, Rat) (SA)
LD50 2350mg/kg (Oral, Rat) (SA) Carcinogen; Work in Hood. (Ghurbanyan Supplement)
LD50 1090mg/kg (Oral, Rat) (SA) Oxidizaing Agent; Work in Hood (Ghurbanyan Supplement)
LD50 7060mg/kg (Oral, Rat) (SA)
No Known OSHA Hazards (SA)
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
Inhalation, Ingestion, or Skin Absorption May be Harmful. Avoid Contact. Do Not Breath Vapors. Keep away from Flames and Hot Surfaces (NB); Work in Hood
Can Cause Serious Burns, Particularly to Eyes. Avoid Skin and Eye Contact. (NB) Work in Hood.
Highly Corrosive. Do Not Remove Bromine Reagent Bottle from Fume Hood. (Ghurbanyan Supplement)
Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA)
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)Irritant - Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in Hood
Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in HoodMay be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
All MSDS Sources for 85%
Notes on Source of Information
ACS Reagent ≥99.0% MSDS from SA
ACS Reagent ≥99.5%, 200 Proof MSDS from SA
Name Formula MW (g/mol) MP (°C)
Isopentyl Alcohol (3-methyl-1-butanol) 88.1 (NB) MP -117 (SA)
Acetic Acid, Glacial 60.1 (NB) 16.2 (SA)
Sulfuric Acid (100%, Concentrated) 98.1 (NB) 3 (SA for 99%)
Water 18.02 (SA) 0.0 (SA)
84.01 (SA) 300 (SA)
Magnesium Sulfate, Anhydrous 120.37 (SA)
Sodium Sulfate, Anhydrous Granular 142.04 (SA) 884 (SA)Sodium Acetate 82.03 (SA) >300 (SA)
Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)
Acetone 58.08 (SA) MP -94 (SA)
130.2 (NB) MP -78 (SA)
C5H12O
C2H4O2
H2SO4
H2O
Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3
MgSO4
Na2O4SC2H3NaO2
CH2Cl2
C3H6O
Isopentyl Acetate (3-methylbutyl ester)(Isoamyl Acetate) C7H14O2
BP (°C) Density (g/ml) Flammability
130 (NB) 0.815 (NB)
118 (NB) 1.049 (NB)
290 (NB) 1.84 (NB) Non-Flammable (SA)
100 (SA)
decmp 2.160 (SA) Non-Flammable (SA)
2.66 Non-Flammable (SA)
1.528 (SA) Non-Flammable (SA)
39.8-40 (SA); 40 (NB) Non-Flammable (SA)
56 (SA) Highly Flammable (SA)
142 (NB) 0.876 (NB) Flammable (SA)
Flammable and Combustible (SA)
Flammable and Combustible (SA)
1.000 at 3.98°C (SA)
2.68 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
0.791 at 25°C (SA)
Solubility Toxicity
LD50 5000mg/kg (Oral, Rat)
Completely Miscible with Water (SA) LD50 3310mg/kg (Oral, Rat) (SA)
Miscible with Water (NB) LD50 2140mg/kg (Oral, Rat) (SA for 99%)
LD50 4220 mg/kg (Oral, Rat) (SA)
Water Soluble (SA) LD50 5989mg/kg (Oral, Mouse) (SA)LD50 3530mg/kg (Oral, Rat) (SA)
Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 7422 (Oral, Rabbit) (SA)
2.7g/100mL H2O (NB)
50g/L H2O(SA)26g/100L H2Oat 0°C
(http://fscimage.fishersci.com/msds/13510.htm)
246g/L H2O at 20°C - Completely Water Soluble (SA)
2.6g/100mL H2O (SA)
0.25g/100mL H2O (NB); Completely miscible with alcohol and ether (SA)
Safety/Comments Notes on Source of Information
Irritant - skin, eyes, and respiratory tract (NB)
No Known OSHA Hazards (SA)
No Known OSHA Hazards (SA)
Hygroscopic (SA)
No Known OSHA Hazards (SA)No Known OSHA Hazards (SA)
Irritant - skin, eyes, and respiratory tract (NB)
Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. Vapors Irritate Eyes and Respiratory Tract. Do not inhale vapors. Work
in Hood (NB)
Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. (NB)
May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)
Name FormulaDimethyl malonate
Sodium methoxide
Methanol (methyl alcohol)
25% Solution of Sodium Methoxide in Methanol
Mesityl Oxide (4-methyl-3-penten-2-one)
Sodium Hydroxide NaOH
Hydrochloric Acid HCl
Diethyl Ether (ethyl ether, ether)
Ethyl acetateWater
Acetone
Dichloromethane (Methylene chloride)
Dimedone (5,5-dimethyl-1,3-cyclohexanedione) (Methone)
Calcium Chloride, Anhydrous (Beads)
C5H8O4
CH3ONa
CH3OH
C6H10O
C4H10O
C4H8O2
H2O
C3H6O
CH2Cl2
C8H12O2
CaCl2
MW (g/mol) MP (°C) BP (°C)132.1 (NB) MP -62 (NB) 181 (NB)
54.0 (NB) 126 (Fisher) Decomposes (Fisher)
32.0 (NB) MP -94 (NB) 65 (NB)
98.2 (NB) MP -52 (NB) 129 (NB)
40.00 (SA) 318 (SA) 1390 (SA)
36.46 (SA) MP -30 (SA)
74.1 (NB) MP -116 (NB) 34.5 (NB)
88.11 (SA) MP -84 (SA) 76.5-77.5 (SA)18.02 (SA) 0.0 (SA) 100 (SA)
58.08 (SA) MP -94 (SA) 56 (SA)
84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)
140.2 (NB) 151 (NB), 146-148 (SA) 164-166 (SA)
110.98 (SA) 772 (SA) 1670 (SA)
>100 (SA)
Density (g/ml) Flammability1.154 (NB) Combustible (SA)
0.970 (SA)
0.791 (NB) Highly Flammable (SA)
Flammable (NB)
0.858 (NB) Flammable (SA)
2.1300 (SA) Non-Flammable (SA)
Non-Flammable (SA)
0.714 (NB)
Highly Flammable (SA)
Highly Flammable (SA)
Non-Flammable (SA)
Non-Flammable (SA)
2.150 (SA) Non-Flammable (SA)
Non-Flammable (SA); Flammable (Fisher)
For 25% Sodium Methoxide Solution in Methanol 0.945 (NB)
1.18 at 25°C (SA)
Flammable (SA), Extremely Flammable (NB)
0.902 at 25°C (SA)1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
SolubilityPartially soluble in cold water (ScienceLab)
Completely Miscible with Water (SA)
Soluble in Water (SA)
Water soluble (SA)
Slightly Soluble in Water (SA)
Soluble in Diethyl ether, Acetone, and Alcohol. Partially Soluble in Cold Water. Soluble in ~30 parts water. Slightly
soluble in Propylene Glycol. (SpectrumChemical)
65g/L Water at 20°C (SA)
2.6g/100mL H2O (SA)
Very slightly soluble in cold water. Solubility in Water is 0.416g/100mL H2O at 25°C (ScienceLab)
ToxicityLD50 5331mg/kg (Oral, Rat) (SA)
LD50 800mg/kg (Oral, Rat) (SA)
LD50 1187-2769mg/kg (Oral, Rat) (SA)
LD50 1120mg/kg (Oral, Rat) (SA)
LD50 1215mg/kg (Oral, Rat) (SA)
LD50 5620mg/kg (Oral, Rat) (SA)
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
LD50 5000mg/kg (Oral, Rat) (SA)
LD50 2301mg/kg (Oral, Rat) (SA)
Safety/Comments Notes on Source of Information Irritant (SA)
Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA)
Corrosive (SA)
ACS Reagent 37% MSDS from SA
Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood No Known OSHA Hazards (SA)
No Known OSHA Hazards (SA)
Irritant (SA)
Unstable Reactive, Harmful by Ingestion, Corrosive (SA); Work in Hood
Corrosive and Toxic. Contact or Inhalation can Cause Severe Damage to Skin, Eyes, and Respiratory Tract. Wear Gloves, Avoid Contact, Do Not Inhale its Vapors, and Keep Away from Flames. (NB); Work in HoodLachrymator and Strong Irritant, Inhalation and Skin Absorption are Harmful. Avoid Contact and Do Not Breath its Vapors. Forms Explosive Peroxides on Standing so, Never Distill to Dryness. (NB); Work in Hood
Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in HoodMay be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)
May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Name FormulaMagnesium Turnings MgBromobenezeDiethyl Ether (ethyl ether, ether)Benzophenone (Diphenyl Ketone)WaterHydrochloric Acid HClSodium Bicarbonate (Sodium hydrogen carbonate)Sodium Chloride NaClMagnesium Sulfate, Anhydrous
HexanesAcetone
Dichloromethane (Methylene chloride)
Triphenylmethanol (Trityl alcohol, Triphenylcarbinol)Sodium Sulfate, Anhydrous GranularEthyl acetateCalcium Chloride, Anhydrous (Beads)
Biphenyl
Benzene
C6H5BrC4H10O
(C6H5)2CO C13H10O (SA)H2O
NaHCO3
MgSO4
C6H14
C3H6O
CH2Cl2
C19H16ONa2O4SC4H8O2
CaCl2
C12H10
C6H6
MW (g/mol) MP (°C) BP (°C)24.3 (NB); 24.31 (SA) 648 (SA) 1090 (SA)
157.01 (SA) MP -31 (NB and SA) 156 (NB and SA)74.1 (NB) MP -116 (NB) 34.5 (NB)
182.2 (NB) 48 (NB) 306 (NB)18.02 (SA) 0.0 (SA) 100 (SA)36.46 (SA) MP -30 (SA)84.01 (SA) 300 (SA) decmp58.44 (SA) 801 (SA) 1413 (SA)
120.37 (SA)
86.18 (SA) MP -95 (SA) 69 (SA)
58.08 (SA) MP -94 (SA) 56 (SA)
84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)
260.3 (NB) 164 (NB) 380 (NB)142.04 (SA) 884 (SA)88.11 (SA) MP -84 (SA) 76.5-77.5 (SA)
110.98 (SA) 772 (SA) 1670 (SA)
154.21 (SA) 68-70 (SA) 255 (SA)
78.11 (SA) 5.5 (SA) 80 (SA)
>100 (SA)
Density (g/ml)1.74 (SA)
1.495 (NB)0.714 (NB)
2.160 (SA)2.165 (SA)
2.66
1.199 (Fischer http://fscimage.fishersci.com/msds/45870.htm)
2.150 (SA)
0.992 (SA)
1.000 at 3.98°C (SA)1.18 at 25°C (SA)
0.659 at 25°C (SA)
0.791 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
2.68 at 25°C (SA)0.902 at 25°C (SA)
0.874 at 25°C (SA)
FlammabilityFlammable
Flammable (SA)Flammable (SA), Extremely Flammable (NB)
Non-Flammable (SA)
Non-Flammable (SA)Non-Flammable (SA)Non-Flammable (SA)Non-Flammable (SA)
Highly Flammable (SA)Highly Flammable (SA)
Non-Flammable (SA)
Highly Flammable (SA)Non-Flammable (SA)
Non-Flammable (SA)
Flammable (SA)
SolubilityInsoluble in Water (Acros)
insoluble in Water (https://fscimage.fishersci.com/msds/03420.htm)
Soluble in Water (SA)
Soluble in Water (SA)
Water Insoluble (SA)
Slightly Soluble in Water (SA)
Water Insoluble (http://fscimage.fishersci.com/msds/45870.htm)Water Soluble (SA)Water soluble (SA)
65g/L H2O at 20°C (SA)Easily Soluble in Acetone, Soluble in Methanol, Diethyl Ether. Insoluble in Cold Water (ScienceLab)
50g/L H2O(SA)
26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.htm)
2.6g/100mL H2O (SA)
0.0075g/L H2O at 15°C (SA); Soluble in Diethyl ether. Very slightly soluble in n-octanol. Insoluble in Cold Water and Hot Water. (ScienceLab)
Miscible in Alcohol, Chloroform, Carbon Disulfide Oils, Carbon Tetrachloride, Glacial Acetic Acid, Diethyl Ether, and Acetone. Very slightly soluble in cold water. Water/Oil Dist. Coeff:
More Soluble in Oil; Log Oil/Water=2.1 (ScienceLab)
ToxicityLD50 300mg/kg (Oral, Mouse) (Clearsynth)
LD50 2,383mg/kg (Oral, Rat) (SA)LD50 1215mg/kg (Oral, Rat) (SA)
LD50 Greater than 10,000mg/kg (Oral, Rat) (SA)
LD50 4220 mg/kg (Oral, Rat) (SA)LD50 3,550mg/kg (Oral Rat) (SA)
LD50 25,000mg/kg (Oral Rat) (SA)LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
LD50 5989mg/kg (Oral, Mouse) (SA)LD50 5620mg/kg (Oral, Rat) (SA)LD50 2301mg/kg (Oral, Rat) (SA)
LD50 2140mg/kg (Oral, Rat) (SA)
LD50 2990mg/kg (Oral, Rat) (SA)
Safety/CommentsKeep Away from Flames and Hot Surfaces (NB)Eye and Skin Irritation; Inhalation, Ingestion, or Skin Absorptions May be Harmful. Avoid Contract with Liquid and Do Not Breath Vapors (NB)May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.
No Known OSHA Hazards (SA)Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in HoodNo Known OSHA Hazards (SA)No Known OSHA Hazards (SA)Hygroscopic (SA)
Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)
Irritant (SA)No Known OSHA Hazards (SA)Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood Irritant (SA)
Irritant, Mutagen (SA)
Irritant, Carcinogen, Mutagen (SA)
May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Notes on Source of Information
ACS Reagent 37% MSDS from SA
Anhydrous Hexanes MSDS from SA
Name Formula
Sodium Hydroxide NaOH
Water
Acetone
Dichloromethane (Methylene chloride)
Magnesium Sulfate, Anhydrous
Sodium Chloride NaClBenzyltriphenylphosphonium Chloride
Ethanol
Triphenylphosphine Oxide
(E, E)-1,4-diphenyl-1,3-butadiene
(E, Z)-1,4-diphenyl-1,3-butadiene
H2O
C3H6O
CH2Cl2
MgSO4
C25H22ClP
trans-Cinnamaldehyde C9H8O
C2H6O
C18H15OP Ph3PO
C16H14
C16H14
MW (g/mol) MP (°C) BP (°C)
40.00 (SA) 318 (SA) 1390 (SA)
18.02 (SA) 0.0 (SA) 100 (SA)
58.08 (SA) MP -94 (SA) 56 (SA)
84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)
120.37 (SA)
58.44 (SA) 801 (SA) 1413 (SA)388.9 (NB) ≥300 (SA)
132.2 (NB) MP -7.5 (NB) 246 (NB)
46.07 (SA) MP -114 (SA) 78.3 (SA)
278.28 (SA) 150-157 (SA)
206.3 (NB) 350 (SA)
206.3 (NB) 88 (NB)
153 (NB); 150-152 (SA) or 151-154 (SA)
Density (g/ml) Flammability
2.1300 (SA) Non-Flammable (SA)
Highly Flammable (SA)
Non-Flammable (SA)
2.66 Non-Flammable (SA)
2.165 (SA) Non-Flammable (SA)Non-Flammable (SA)
1.050 (NB) Combustible (SA and ScienceLab)
0.789 (SA) Flammable (SA)
1.000 at 3.98°C (SA)
0.791 at 25°C (SA)
1.325 at 25°C (SA); 1.327 (NB)
Solubility
Slightly Soluble in Water (SA)
Soluble in Water (SA)
Completely Water Soluble (SA)
Soluble in Alcohol, Sparingly Soluble in Ether (TCI)
2.6g/100mL H2O (SA)
26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.htm)
Soluble in Methanol and Diethyl Ether. Very slightly soluble in Cold Water (ScienceLab)
Almost insoluble in deionized water, cyclohexane, petroleum ether, and hexane. Readily soluble in ethanol,
formic acid, acetic acid, and dichloromethane. (Article Hu, F.H.; Wang, L.S.; Cal, S.F. Solubilities of
Triphenylphosphine Oxide in Selected Solvents. J. Chem. Eng. Data 2009, 54, 1382-1384.)
Toxicity
LD50 5,800mg/kg (Oral, Rat) (SA)
LD50 1600mg/kg (Oral, Rat) (SA)
LD50 3,550mg/kg (Oral Rat) (SA)LD50 43mg/kg (Oral, Rat) (SA)
LD50 2220mg/kg (Oral, Rat) (ScienceLab)
LD50 7060mg/kg (Oral, Rat) (SA)
LD50 1380mg/kg (Oral, Mouse) (SA)
Safety/Comments Notes on Source of Information
No Known OSHA Hazards (SA)
Hygroscopic (SA)
No Known OSHA Hazards (SA)Highly Toxic by Ingestion - Fatal if Swallowed (SA).
Skin Irritant - Avoid Contact (NB)
Harmful by Ingestion, Irritant (SA) Aldrich Reagent 98% MSDS from SA
Irritant (SA); Work in Hood Fluka HPLC Reagent ≥99.0% from SA
Corrosive (SA). Toxic and Corrosive - Causing Severe Damage to Skin, Eyes, and Mucous Membranes. Wear Gloves and Avoid Contact with the NaoH Solution. (NB)
Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.
Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA)
ACS Reagent ≥99.5%, 200 Proof MSDS from SA