7 reagents

65
Name Formula Magnesium Sulfate, Anhydrous Sodium Chloride NaCl Water Acetone Hydrochloric Acid HCl Dichloromethane (Methylene chloride) Sucrose Aspirin (Acetylsalicylic Acid, ASA) Acetanilide Phenacetin Acetaminophen MgSO4 H2O C3H6O Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3 CH2Cl2 C12H22O11 C9H8O4 C8H9NO or CH3CONHC6H5 C10H13NO2 C8H9NO2

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Page 1: 7 Reagents

Name Formula

Magnesium Sulfate, Anhydrous

Sodium Chloride NaClWater

Acetone

Hydrochloric Acid HCl

Dichloromethane (Methylene chloride)

Sucrose

Aspirin (Acetylsalicylic Acid, ASA)

Acetanilide

Phenacetin

Acetaminophen

MgSO4

H2O

C3H6O

Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3

CH2Cl2

C12H22O11

C9H8O4

C8H9NO or CH3CONHC6H5

C10H13NO2

C8H9NO2

Page 2: 7 Reagents

MW (g/mol) MP (°C) BP (°C)

120.37 (SA)

58.44 (SA) 801 (SA) 1413 (SA)18.02 (SA) 0.0 (SA) 100 (SA)

58.08 (SA) MP -94 (SA) 56 (SA)

36.46 (SA) MP -30 (SA)

84.01 (SA) 300 (SA) decmp

84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)

342.30 (SA) 185-187 (SA)

180.16 (SA) 134-136 (SA)

135.2 (NB) 114 (NB) 304-305 (NB)

179.2 (NB) 135 (NB)

151.16 (SA) 168-172 (SA)

>100 (SA)

Decomposes (ScienceLab)

Page 3: 7 Reagents

Density (g/ml) Flammability

2.66 Non-Flammable (SA)

2.165 (SA) Non-Flammable (SA)

Highly Flammable (SA)

Non-Flammable (SA)

2.160 (SA) Non-Flammable (SA)

Non-Flammable (SA)

1.587 (ScienceLab)

1.35 (ScienceLab) Non-Flammable (SA)

1.219 (NB)

1.293 (ScienceLab) Non-Flammable (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

1.18 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

Page 4: 7 Reagents

Solubility Toxicity

Soluble in Water (SA) LD50 3,550mg/kg (Oral Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

Soluble in Water (SA)

LD50 4220 mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 29,700mg/kg (Oral, Rat) (SA)

LD50 1500mg/kg (Oral, Rat) (SA)

LD50 800mg/kg (Oral, Rat) (ScienceLab)

LD50 1650mg/kg (Oral, Rat) (SA)

LD50 1944mg/kg (Oral, Rat) (SA)

26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.h

tm)

2.6g/100mL H2O (SA)

50g/L H2O(SA)

342g/L H2O at 20°C - Completely Soluble (SA); Insoluble in Dichloromethane (NB)

Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble

in cold water (ScienceLab)

0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB)

0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB)

Page 5: 7 Reagents

Safety/Comments

Hygroscopic (SA)

No Known OSHA Hazards (SA)No Known OSHA Hazards (SA)

No Known OSHA Hazards (SA)

No Known OSHA Hazards (SA)

Irritant, Harmful on Ingestion (SA)

Irritant - Minimize Contact (NB)

Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA)

Harmful by Ingestion, Irritant (SA)

Notes on Source of Information

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood

ACS Reagent 37% MSDS from SA

May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Page 6: 7 Reagents

Name Formula

Water

Acetone

Dichloromethane (Methylene chloride)

Acetanilide

Phenacetin

Sucrose

Aspirin (Acetylsalicylic Acid, ASA)

H2O

C3H6O

CH2Cl2

C8H9NO or CH3CONHC6H5

C10H13NO2

C12H22O11

C9H8O4

Page 7: 7 Reagents

MW (g/mol) MP (°C) BP (°C)

18.02 (SA) 0.0 (SA) 100 (SA)

58.08 (SA) MP -94 (SA) 56 (SA)

84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)

135.2 (NB) 114 (NB) 304-305 (NB)

179.2 (NB) 135 (NB)

342.30 (SA) 185-187 (SA)

180.16 (SA) 134-136 (SA)

Decomposes (ScienceLab)

Page 8: 7 Reagents

Density (g/ml) Flammability

Highly Flammable (SA)

Non-Flammable (SA)

1.219 (NB)

1.587 (ScienceLab)

1.35 (ScienceLab) Non-Flammable (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

Page 9: 7 Reagents

Solubility Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 800mg/kg (Oral, Rat) (ScienceLab)

LD50 1650mg/kg (Oral, Rat) (SA)

LD50 29,700mg/kg (Oral, Rat) (SA)

LD50 1500mg/kg (Oral, Rat) (SA)

2.6g/100mL H2O (SA)

0.54g/100mL Cold H2O, 5.0g/100mL in Boiling H2O (NB)

0.076g/100mL Cold H2O, 1.22g/100mL in Boiling H2O (NB)

342g/L H2O at 20°C - Completely Soluble (SA); Insoluble in Dichloromethane (NB)

Soluble in Dichloromethane, Relatively Insoluble in Water (NB); Very slightly soluble

in cold water (ScienceLab)

Page 10: 7 Reagents

Safety/Comments

No Known OSHA Hazards (SA)

Irritant - Minimize Contact (NB)

Irritant - Minimize Contact (NB); Carcinogen, Harmful by Ingestion (SA)

No Known OSHA Hazards (SA)

Irritant, Harmful on Ingestion (SA)

Notes on Source of Information

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Page 11: 7 Reagents

Name Formula MW (g/mol)

Water 18.02 (SA)

Acetone 58.08 (SA)

Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB)

Ethyl acetate 88.11 (SA)

Hexanes 86.18 (SA)

Anthracene 178.23 (SA)

Cholesterol 386.65 (SA)

1,4-napthoquinone 158.15 (SA)138.12 (SA)

Ferrocene 186.03 (SA)

Acetylferrocene 228.07 (SA)

1,1'-Diacetylferrocene 270.10 (SA)

Silica Gel

Iodine 253.81 (SA)

Sand

H2O

C3H6O

CH2Cl2

C4H8O2

C6H14

C14H10

C27H46O

C10H6O2

para-nitroaniline C6H6N2O2

C10H10FeC12H12FeO

C14H14FeO2

SiO2 X H2O 60.09 + xH2Og/mol (ScienceLab)

I2

SiO2

Page 12: 7 Reagents

MP (°C) BP (°C) Density (g/ml)

0.0 (SA) 100 (SA)

MP -94 (SA) 56 (SA)

MP -97 (NB) 39.8-40 (SA); 40 (NB)

MP -84 (SA) 76.5-77.5 (SA)

MP -95 (SA) 69 (SA)

210-215 (SA) 340 (SA)

147-149 (SA) 360 (SA)

119-122 (SA) 1.422 (ScienceLab)146-149 (SA) 260 at 100mmHg (SA) 1.44 (SA)172-174 (SA) 249 (SA)

81-83 (SA)

125-127 (SA)

2.1 (ScienceLab)

113 (SA) 184 (SA) 4.930 (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

0.902 at 25°C (SA)

0.659 at 25°C (SA)

1.25-1.28 (Fisher http://fscimage.fishersci.com/msds/96670.htm)

1.067 at 25°C (SA)

1.8 to 2.5 Depending on Mineral Composition (ScienceLab)

Page 13: 7 Reagents

Flammability Solubility

Highly Flammable (SA)

Non-Flammable (SA) Slightly Soluble in Water (SA)

Highly Flammable (SA) Water soluble (SA)

Highly Flammable (SA) Water Insoluble (SA)

Non-Flammable (SA) Insoluble in Cold Water (ScienceLab)

Non-Flammable (SA)

Water Soluble (SA)Non-Flammable (SA) Slightly Soluble in Water (SA)

Flammable (SA) Insoluble in Cold Water (ScienceLab)Non-Flammable (SA)

Non-Flammable (ScienceLab)

Non-Flammable (SA)

Non-Flammable (ScienceLab)

2.6g/100mL H2O (SA)

Soluble in Diethyl ether and Acetone. Very slightly soluble in Alcohol and Cold Water.

Solubility in Water 0.2mg/100mL H2O (ScienceLab)

Insoluble in Water (http://fscimage.fishersci.com/msds/10307.h

tm)

Insoluble in Cold Water. Soluble in Hot KOH and MaOH solutions. Insoluble in Ethanol and Acids, except Hydrofluoric Acid (ScienceLab)

Easily Soluble in Diethyl ether. Soluble in Methanol. Very Slightly Soluble in Water.

(ScienceLab)

Insoluble in Water, Methanol, Diethyl Ether, and n-Octanol. (ScienceLab)

Page 14: 7 Reagents

Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5620mg/kg (Oral, Rat) (SA)

LD50 25,000mg/kg (Oral Rat) (SA)

LD50 190mg/kg (Oral, Rat) (SA)LD50 750mg/kg (Oral, Rat) (SA)

LD50 1320mg/kg (Oral, Rat) (SA)LD50 50mg/kg (Oral, Mouse) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 >31600mg/kg (Oral, Rat) (ScienceLab)

LD50 14,000mg/kg (Oral, Rat)

LD50 4900mg/kg (Oral, Mouse) (Fisher http://fscimage.fishersci.com/msds/96670.htm)

Page 15: 7 Reagents

Safety/Comments

No Known OSHA Hazards (SA)

Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood

Carcinogen, Irritant (SA)

Irritant and Permeator (ScienceLab)

Highly Toxic by Inhalation, Toxic by Ingestion, Irritant. (SA) Work in Hood.Toxic by Inhalation, Toxic by Ingestion, and by Skin Absorption (SA)Harmful by Ingestion (SA)Highly Toxic by Ingestion - Fatal if Swallowed (SA)

Hamful by Ingestion. Hamful on contact with skin. (SA)

Slight Irritant (ScienceLab)

Notes on Source of Information

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood

Anhydrous Hexanes MSDS from SA

Carcinogen, Harmful to Respiratory Tract due to its Super Fine Nature. Do not stir silica gel excessively or breath in dust. Work in Hood. (Ghurbanyan Supplement)

Toxic by Inhalation. Harmful by Skin Absorption. Skin Sensitiser. Corrosive. (SA)

Page 16: 7 Reagents

D Formula MW (g/mol) MP (°C)

Water 18.02 (SA) 0.0 (SA)

Acetone 58.08 (SA) MP -94 (SA)

Diethyl Ether (ethyl ether, ether) 74.1 (NB) MP -116 (NB)

Methanol (methyl alcohol) 32.0 (NB) MP -94 (NB)

136.23 (SA) 127 (NB)

Maleic Anhydride 98.1 (NB) 53 (NB)

H2O

C3H6O

C4H10O

CH3OH

α-Phellandrene (5-isopropyl-2-methyl-1,3-cyclohexadiene) C10H16

C4H2O3

Page 17: 7 Reagents

BP (°C) Density (g/ml) Flammability

100 (SA)

56 (SA) Highly Flammable (SA)

34.5 (NB) 0.714 (NB)

65 (NB) 0.791 (NB) Highly Flammable (SA)

175 (MerckMillpore) Flammable and Combustible (SA)

202 (NB) Non-Flammable (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

Flammable (SA), Extremely Flammable (NB)

0.85 at 25°C (SA)

Page 18: 7 Reagents

Solubility Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1215mg/kg (Oral, Rat) (SA)

LD50 1187-2769mg/kg (Oral, Rat) (SA)

LD50 5700mg/kg (Oral, Rat) (Merck Millpore)

LD50 400mg/kg (Oral, Rat)

2.6g/100mL H2O (SA)

65g/L H2O at 20°C (SA)

Completely Miscible with Water (SA)

2.86mg/L H2O at 25°C (Merck Millpore)

Soluble in Cold and Hot Water. Very slightly soluble in

Methanol. (ScienceLab)

Page 19: 7 Reagents

Safety/Comments

No Known OSHA Hazards (SA)

Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA)

Harmful by Ingestion. Respiratory Sensitiser. Irritant. (SA) Work in Hood.

Notes on Source of Information

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.

Corrosive. Can cause severe damage to eyes, skin, and upper respiratory tract. Avoid contact. Do not breath dust. Work in Hood (NB)

Page 20: 7 Reagents

Name Formula MW (g/mol) MP (°C)

Water 18.02 (SA) 0.0 (SA)

Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)

Acetic Anhydride 102.1 (NB) MP -73 (NB)

Aluminum chloride 133.3 (NB) 193 (NB)

Sodium Hydroxide NaOH 40.00 (SA) 318 (SA)

Magnesium Sulfate, Anhydrous 120.37 (SA)

Sodium Chloride NaCl 58.44 (SA) 801 (SA)

Hydrochloric Acid HCl 36.46 (SA) MP -30 (SA)

Anisole 108.2 (NB) MP -38 (NB)

4'-Methoxyacetophenone 150.2 (NB) 39 (NB)

Acetone 58.08 (SA) MP -94 (SA)

H2O

CH2Cl2

C4H6O3

AlCl3

MgSO4

C7H8O

C9H10O2

C3H6O

Page 21: 7 Reagents

BP (°C) Density (g/ml) Flammability

100 (SA)

39.8-40 (SA); 40 (NB) Non-Flammable (SA)

140 (NB) 1.082 (NB) Flammable (SA)

Sublimes (NB) 2.4400 (SA) Non-Flammable (SA)

1390 (SA) 2.1300 (SA) Non-Flammable (SA)

2.66 Non-Flammable (SA)

1413 (SA) 2.165 (SA) Non-Flammable (SA)

Non-Flammable (SA)

155 (NB) 0.996 (NB)

258 (NB) 1.082 (NB) Non-Flammable (SA)

56 (SA) Highly Flammable (SA)

1.000 at 3.98°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

>100 (SA) 1.18 at 25°C (SA)

Flammable and Combustible (SA)

0.791 at 25°C (SA)

Page 22: 7 Reagents

Solubility Toxicity

Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 1780mg/kg (Oral, Rat) (SA)

LD50 3450mg/kg (Oral, Rat) (SA)

Soluble in Water (SA) LD50 3,550mg/kg (Oral Rat) (SA)

Soluble in Water (SA)

LD50 3700mg/kg (Oral, Rat) (SA)

LD50 1720mg/kg (Oral, Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

26g/100L H2Oat 0°C (http://fscimage.fishersci.com/

msds/13510.htm)

Insoluble in Water. Soluble in Ethanol, Diethyl ether, and Acetone-Like Solvents. (SA)

2.474g/L H2O at 20°C (SA)

2.6g/100mL H2O (SA)

Page 23: 7 Reagents

Safety/Comments

No Known OSHA Hazards (SA)

Corrosive (SA)

Hygroscopic (SA)

No Known OSHA Hazards (SA)

Irritant. (SA)

Harmful by Ingestion. Irritant. (SA)

Notes on Source of Information

May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood. Irritant - Can Cause Severe Damage to Skin and Eyes. Use Gloves and Avoid Contact. Vapors are Harmful if Inhaled. Do Not Breath Vapors. Reacts Violently with Water. Keep away from Water. (NB) Work in Hood

Reacts with Atmospheric Moisture and Violently with Water to Generate HCl Vapors - Keep away from Water. Can cause painful burns on moist skin and eyes - Avoid Contact. Do not inhale dust or vapors, which can damage respiratory tract. (NB) Work in Hood

Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in Hood

ACS Reagent 37% MSDS from SA

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)

Page 24: 7 Reagents

Name Formula MW (g/mol) MP (°C)

114.2 (NB) MP -38 (Acros)

85% Phosphoric Acid 40 (SA)

84.01 (SA) 300 (SA)

Calcium Chloride, Anhydrous (Beads) 110.98 (SA) 772 (SA)

Bromine 159.81 (SA) 7.2 (SA)

Carbon Tetrachloride 153.82 (SA) MP -23 (SA)

Potassium Permanganate, Aqueous 1% 158.03 (SA) 240 (SA)

Ethanol 46.07 (SA) MP -114 (SA)

Water 18.02 (SA) 0.0 (SA)

Acetone 58.08 (SA) MP -94 (SA)

1-Methylcyclohexene 96.2 (NB)

3-Methylcyclohexene 96.2 (NB)

Methylenecyclohexane 96.17 (SA)

Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)

2-methylcyclohexanol (Cis and Trans Isomers) C7H14O

H3PO4

98.0 (NB for Pure Acid); 85% Phosphoric Acid is ~14.7M

(NB)

Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3

CaCl2

Br2

CCl4

KMnO4

C2H6O

H2O

C3H6O

C7H12

C7H12

C7H12

CH2Cl2

Page 25: 7 Reagents

BP (°C) Density (g/ml) Flammability Solubility

166 (NB) 0.930 (NB)

158 (SA) 1.70 (NB); 1.685 (SA) Non-Flammable (SA)

decmp 2.160 (SA) Non-Flammable (SA)

1670 (SA) 2.150 (SA) Non-Flammable (SA)

58.8 (SA) 3.119 (SA) Non-Flammable (SA)

76-77 (SA) 1.594 (SA) Non-Flammable (SA)

2.710 (SA) Non-Flammable (SA)

78.3 (SA) 0.789 (SA) Flammable (SA)

100 (SA)

56 (SA) Highly Flammable (SA)

110 (NB) 0.813 (NB) Flammable (NB)

104 (NB) 0.801 (NB) Flammable (NB)

102-103 (SA) Flammable (SA)

39.8-40 (SA); 40 (NB) Non-Flammable (SA) Slightly Soluble in Water (SA)

Flammable and Combustible (SA)

Slighlty Soluble in Water (Acros)

Easily Soluble in Hot and Cold Water (ScienceLab)

50g/L H2O(SA)

36.5g/L H2O at 20°C

0.8461g/L H2O at 20°C (SA)

Completely Water Soluble (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA) 2.6g/100mL H2O (SA)

0.8 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

Page 26: 7 Reagents

Toxicity Safety/Comments

LD50 1530mg/kg (Oral, Rat) (ScienceLab)

LD50 4220 mg/kg (Oral, Rat) (SA) No Known OSHA Hazards (SA)

LD50 2301 (Oral, Rat) (SA) Irritant (SA)

LD50 2600mg/kg (Oral, Rat) (SA)

LD50 2350mg/kg (Oral, Rat) (SA) Carcinogen; Work in Hood. (Ghurbanyan Supplement)

LD50 1090mg/kg (Oral, Rat) (SA) Oxidizaing Agent; Work in Hood (Ghurbanyan Supplement)

LD50 7060mg/kg (Oral, Rat) (SA)

No Known OSHA Hazards (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

Inhalation, Ingestion, or Skin Absorption May be Harmful. Avoid Contact. Do Not Breath Vapors. Keep away from Flames and Hot Surfaces (NB); Work in Hood

Can Cause Serious Burns, Particularly to Eyes. Avoid Skin and Eye Contact. (NB) Work in Hood.

Highly Corrosive. Do Not Remove Bromine Reagent Bottle from Fume Hood. (Ghurbanyan Supplement)

Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA)

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)Irritant - Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in Hood

Avoid Contact with Skin and Eyes. Avoid Inhalation of Vapors or Mist. (SA) Work in HoodMay be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Page 27: 7 Reagents

All MSDS Sources for 85%

Notes on Source of Information

ACS Reagent ≥99.0% MSDS from SA

ACS Reagent ≥99.5%, 200 Proof MSDS from SA

Page 28: 7 Reagents

Name Formula MW (g/mol) MP (°C)

Isopentyl Alcohol (3-methyl-1-butanol) 88.1 (NB) MP -117 (SA)

Acetic Acid, Glacial 60.1 (NB) 16.2 (SA)

Sulfuric Acid (100%, Concentrated) 98.1 (NB) 3 (SA for 99%)

Water 18.02 (SA) 0.0 (SA)

84.01 (SA) 300 (SA)

Magnesium Sulfate, Anhydrous 120.37 (SA)

Sodium Sulfate, Anhydrous Granular 142.04 (SA) 884 (SA)Sodium Acetate 82.03 (SA) >300 (SA)

Dichloromethane (Methylene chloride) 84.93 (SA); 84.9 (NB) MP -97 (NB)

Acetone 58.08 (SA) MP -94 (SA)

130.2 (NB) MP -78 (SA)

C5H12O

C2H4O2

H2SO4

H2O

Sodium Bicarbonate (Sodium hydrogen carbonate) NaHCO3

MgSO4

Na2O4SC2H3NaO2

CH2Cl2

C3H6O

Isopentyl Acetate (3-methylbutyl ester)(Isoamyl Acetate) C7H14O2

Page 29: 7 Reagents

BP (°C) Density (g/ml) Flammability

130 (NB) 0.815 (NB)

118 (NB) 1.049 (NB)

290 (NB) 1.84 (NB) Non-Flammable (SA)

100 (SA)

decmp 2.160 (SA) Non-Flammable (SA)

2.66 Non-Flammable (SA)

1.528 (SA) Non-Flammable (SA)

39.8-40 (SA); 40 (NB) Non-Flammable (SA)

56 (SA) Highly Flammable (SA)

142 (NB) 0.876 (NB) Flammable (SA)

Flammable and Combustible (SA)

Flammable and Combustible (SA)

1.000 at 3.98°C (SA)

2.68 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

0.791 at 25°C (SA)

Page 30: 7 Reagents

Solubility Toxicity

LD50 5000mg/kg (Oral, Rat)

Completely Miscible with Water (SA) LD50 3310mg/kg (Oral, Rat) (SA)

Miscible with Water (NB) LD50 2140mg/kg (Oral, Rat) (SA for 99%)

LD50 4220 mg/kg (Oral, Rat) (SA)

Water Soluble (SA) LD50 5989mg/kg (Oral, Mouse) (SA)LD50 3530mg/kg (Oral, Rat) (SA)

Slightly Soluble in Water (SA) LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 7422 (Oral, Rabbit) (SA)

2.7g/100mL H2O (NB)

50g/L H2O(SA)26g/100L H2Oat 0°C

(http://fscimage.fishersci.com/msds/13510.htm)

246g/L H2O at 20°C - Completely Water Soluble (SA)

2.6g/100mL H2O (SA)

0.25g/100mL H2O (NB); Completely miscible with alcohol and ether (SA)

Page 31: 7 Reagents

Safety/Comments Notes on Source of Information

Irritant - skin, eyes, and respiratory tract (NB)

No Known OSHA Hazards (SA)

No Known OSHA Hazards (SA)

Hygroscopic (SA)

No Known OSHA Hazards (SA)No Known OSHA Hazards (SA)

Irritant - skin, eyes, and respiratory tract (NB)

Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. Vapors Irritate Eyes and Respiratory Tract. Do not inhale vapors. Work

in Hood (NB)

Causes Chemical Burns that can Seriously Damage Skin & Eyes. Avoid Contact and Wear Gloves. (NB)

May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)

Page 32: 7 Reagents

Name FormulaDimethyl malonate

Sodium methoxide

Methanol (methyl alcohol)

25% Solution of Sodium Methoxide in Methanol

Mesityl Oxide (4-methyl-3-penten-2-one)

Sodium Hydroxide NaOH

Hydrochloric Acid HCl

Diethyl Ether (ethyl ether, ether)

Ethyl acetateWater

Acetone

Dichloromethane (Methylene chloride)

Dimedone (5,5-dimethyl-1,3-cyclohexanedione) (Methone)

Calcium Chloride, Anhydrous (Beads)

C5H8O4

CH3ONa

CH3OH

C6H10O

C4H10O

C4H8O2

H2O

C3H6O

CH2Cl2

C8H12O2

CaCl2

Page 33: 7 Reagents

MW (g/mol) MP (°C) BP (°C)132.1 (NB) MP -62 (NB) 181 (NB)

54.0 (NB) 126 (Fisher) Decomposes (Fisher)

32.0 (NB) MP -94 (NB) 65 (NB)

98.2 (NB) MP -52 (NB) 129 (NB)

40.00 (SA) 318 (SA) 1390 (SA)

36.46 (SA) MP -30 (SA)

74.1 (NB) MP -116 (NB) 34.5 (NB)

88.11 (SA) MP -84 (SA) 76.5-77.5 (SA)18.02 (SA) 0.0 (SA) 100 (SA)

58.08 (SA) MP -94 (SA) 56 (SA)

84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)

140.2 (NB) 151 (NB), 146-148 (SA) 164-166 (SA)

110.98 (SA) 772 (SA) 1670 (SA)

>100 (SA)

Page 34: 7 Reagents

Density (g/ml) Flammability1.154 (NB) Combustible (SA)

0.970 (SA)

0.791 (NB) Highly Flammable (SA)

Flammable (NB)

0.858 (NB) Flammable (SA)

2.1300 (SA) Non-Flammable (SA)

Non-Flammable (SA)

0.714 (NB)

Highly Flammable (SA)

Highly Flammable (SA)

Non-Flammable (SA)

Non-Flammable (SA)

2.150 (SA) Non-Flammable (SA)

Non-Flammable (SA); Flammable (Fisher)

For 25% Sodium Methoxide Solution in Methanol 0.945 (NB)

1.18 at 25°C (SA)

Flammable (SA), Extremely Flammable (NB)

0.902 at 25°C (SA)1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

Page 35: 7 Reagents

SolubilityPartially soluble in cold water (ScienceLab)

Completely Miscible with Water (SA)

Soluble in Water (SA)

Water soluble (SA)

Slightly Soluble in Water (SA)

Soluble in Diethyl ether, Acetone, and Alcohol. Partially Soluble in Cold Water. Soluble in ~30 parts water. Slightly

soluble in Propylene Glycol. (SpectrumChemical)

65g/L Water at 20°C (SA)

2.6g/100mL H2O (SA)

Very slightly soluble in cold water. Solubility in Water is 0.416g/100mL H2O at 25°C (ScienceLab)

Page 36: 7 Reagents

ToxicityLD50 5331mg/kg (Oral, Rat) (SA)

LD50 800mg/kg (Oral, Rat) (SA)

LD50 1187-2769mg/kg (Oral, Rat) (SA)

LD50 1120mg/kg (Oral, Rat) (SA)

LD50 1215mg/kg (Oral, Rat) (SA)

LD50 5620mg/kg (Oral, Rat) (SA)

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5000mg/kg (Oral, Rat) (SA)

LD50 2301mg/kg (Oral, Rat) (SA)

Page 37: 7 Reagents

Safety/Comments Notes on Source of Information Irritant (SA)

Toxic by Inhalation, Toxic by Ingestion, Toxic by Skin Absorption (SA)

Corrosive (SA)

ACS Reagent 37% MSDS from SA

Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood No Known OSHA Hazards (SA)

No Known OSHA Hazards (SA)

Irritant (SA)

Unstable Reactive, Harmful by Ingestion, Corrosive (SA); Work in Hood

Corrosive and Toxic. Contact or Inhalation can Cause Severe Damage to Skin, Eyes, and Respiratory Tract. Wear Gloves, Avoid Contact, Do Not Inhale its Vapors, and Keep Away from Flames. (NB); Work in HoodLachrymator and Strong Irritant, Inhalation and Skin Absorption are Harmful. Avoid Contact and Do Not Breath its Vapors. Forms Explosive Peroxides on Standing so, Never Distill to Dryness. (NB); Work in Hood

Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in HoodMay be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)

May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Page 38: 7 Reagents

Name FormulaMagnesium Turnings MgBromobenezeDiethyl Ether (ethyl ether, ether)Benzophenone (Diphenyl Ketone)WaterHydrochloric Acid HClSodium Bicarbonate (Sodium hydrogen carbonate)Sodium Chloride NaClMagnesium Sulfate, Anhydrous

HexanesAcetone

Dichloromethane (Methylene chloride)

Triphenylmethanol (Trityl alcohol, Triphenylcarbinol)Sodium Sulfate, Anhydrous GranularEthyl acetateCalcium Chloride, Anhydrous (Beads)

Biphenyl

Benzene

C6H5BrC4H10O

(C6H5)2CO C13H10O (SA)H2O

NaHCO3

MgSO4

C6H14

C3H6O

CH2Cl2

C19H16ONa2O4SC4H8O2

CaCl2

C12H10

C6H6

Page 39: 7 Reagents

MW (g/mol) MP (°C) BP (°C)24.3 (NB); 24.31 (SA) 648 (SA) 1090 (SA)

157.01 (SA) MP -31 (NB and SA) 156 (NB and SA)74.1 (NB) MP -116 (NB) 34.5 (NB)

182.2 (NB) 48 (NB) 306 (NB)18.02 (SA) 0.0 (SA) 100 (SA)36.46 (SA) MP -30 (SA)84.01 (SA) 300 (SA) decmp58.44 (SA) 801 (SA) 1413 (SA)

120.37 (SA)

86.18 (SA) MP -95 (SA) 69 (SA)

58.08 (SA) MP -94 (SA) 56 (SA)

84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)

260.3 (NB) 164 (NB) 380 (NB)142.04 (SA) 884 (SA)88.11 (SA) MP -84 (SA) 76.5-77.5 (SA)

110.98 (SA) 772 (SA) 1670 (SA)

154.21 (SA) 68-70 (SA) 255 (SA)

78.11 (SA) 5.5 (SA) 80 (SA)

>100 (SA)

Page 40: 7 Reagents

Density (g/ml)1.74 (SA)

1.495 (NB)0.714 (NB)

2.160 (SA)2.165 (SA)

2.66

1.199 (Fischer http://fscimage.fishersci.com/msds/45870.htm)

2.150 (SA)

0.992 (SA)

1.000 at 3.98°C (SA)1.18 at 25°C (SA)

0.659 at 25°C (SA)

0.791 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

2.68 at 25°C (SA)0.902 at 25°C (SA)

0.874 at 25°C (SA)

Page 41: 7 Reagents

FlammabilityFlammable

Flammable (SA)Flammable (SA), Extremely Flammable (NB)

Non-Flammable (SA)

Non-Flammable (SA)Non-Flammable (SA)Non-Flammable (SA)Non-Flammable (SA)

Highly Flammable (SA)Highly Flammable (SA)

Non-Flammable (SA)

Highly Flammable (SA)Non-Flammable (SA)

Non-Flammable (SA)

Flammable (SA)

Page 42: 7 Reagents

SolubilityInsoluble in Water (Acros)

insoluble in Water (https://fscimage.fishersci.com/msds/03420.htm)

Soluble in Water (SA)

Soluble in Water (SA)

Water Insoluble (SA)

Slightly Soluble in Water (SA)

Water Insoluble (http://fscimage.fishersci.com/msds/45870.htm)Water Soluble (SA)Water soluble (SA)

65g/L H2O at 20°C (SA)Easily Soluble in Acetone, Soluble in Methanol, Diethyl Ether. Insoluble in Cold Water (ScienceLab)

50g/L H2O(SA)

26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.htm)

2.6g/100mL H2O (SA)

0.0075g/L H2O at 15°C (SA); Soluble in Diethyl ether. Very slightly soluble in n-octanol. Insoluble in Cold Water and Hot Water. (ScienceLab)

Miscible in Alcohol, Chloroform, Carbon Disulfide Oils, Carbon Tetrachloride, Glacial Acetic Acid, Diethyl Ether, and Acetone. Very slightly soluble in cold water. Water/Oil Dist. Coeff:

More Soluble in Oil; Log Oil/Water=2.1 (ScienceLab)

Page 43: 7 Reagents

ToxicityLD50 300mg/kg (Oral, Mouse) (Clearsynth)

LD50 2,383mg/kg (Oral, Rat) (SA)LD50 1215mg/kg (Oral, Rat) (SA)

LD50 Greater than 10,000mg/kg (Oral, Rat) (SA)

LD50 4220 mg/kg (Oral, Rat) (SA)LD50 3,550mg/kg (Oral Rat) (SA)

LD50 25,000mg/kg (Oral Rat) (SA)LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 5989mg/kg (Oral, Mouse) (SA)LD50 5620mg/kg (Oral, Rat) (SA)LD50 2301mg/kg (Oral, Rat) (SA)

LD50 2140mg/kg (Oral, Rat) (SA)

LD50 2990mg/kg (Oral, Rat) (SA)

Page 44: 7 Reagents

Safety/CommentsKeep Away from Flames and Hot Surfaces (NB)Eye and Skin Irritation; Inhalation, Ingestion, or Skin Absorptions May be Harmful. Avoid Contract with Liquid and Do Not Breath Vapors (NB)May be Harmful if Inhaled. Do not Breath Vapors. Keep Away from Flames and Hot Surfaces. (NB) Work in Hood.

No Known OSHA Hazards (SA)Corrosive - Avoid Contact, causes severe burns and eye damage, Avoid breathing vapors, mist, or gas (SA); Work in HoodNo Known OSHA Hazards (SA)No Known OSHA Hazards (SA)Hygroscopic (SA)

Irritant, Teratogen, May be Fatal if Swallowed or Inhaled, Do not breath dust/fume/gas/mist/vapors/spray (SA); Work in Hood

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)

Irritant (SA)No Known OSHA Hazards (SA)Irritant, Avoid Inhalation or Vapor or Mist (SA); Work in Hood Irritant (SA)

Irritant, Mutagen (SA)

Irritant, Carcinogen, Mutagen (SA)

May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Page 45: 7 Reagents

Notes on Source of Information

ACS Reagent 37% MSDS from SA

Anhydrous Hexanes MSDS from SA

Page 46: 7 Reagents

Name Formula

Sodium Hydroxide NaOH

Water

Acetone

Dichloromethane (Methylene chloride)

Magnesium Sulfate, Anhydrous

Sodium Chloride NaClBenzyltriphenylphosphonium Chloride

Ethanol

Triphenylphosphine Oxide

(E, E)-1,4-diphenyl-1,3-butadiene

(E, Z)-1,4-diphenyl-1,3-butadiene

H2O

C3H6O

CH2Cl2

MgSO4

C25H22ClP

trans-Cinnamaldehyde C9H8O

C2H6O

C18H15OP Ph3PO

C16H14

C16H14

Page 47: 7 Reagents

MW (g/mol) MP (°C) BP (°C)

40.00 (SA) 318 (SA) 1390 (SA)

18.02 (SA) 0.0 (SA) 100 (SA)

58.08 (SA) MP -94 (SA) 56 (SA)

84.93 (SA); 84.9 (NB) MP -97 (NB) 39.8-40 (SA); 40 (NB)

120.37 (SA)

58.44 (SA) 801 (SA) 1413 (SA)388.9 (NB) ≥300 (SA)

132.2 (NB) MP -7.5 (NB) 246 (NB)

46.07 (SA) MP -114 (SA) 78.3 (SA)

278.28 (SA) 150-157 (SA)

206.3 (NB) 350 (SA)

206.3 (NB) 88 (NB)

153 (NB); 150-152 (SA) or 151-154 (SA)

Page 48: 7 Reagents

Density (g/ml) Flammability

2.1300 (SA) Non-Flammable (SA)

Highly Flammable (SA)

Non-Flammable (SA)

2.66 Non-Flammable (SA)

2.165 (SA) Non-Flammable (SA)Non-Flammable (SA)

1.050 (NB) Combustible (SA and ScienceLab)

0.789 (SA) Flammable (SA)

1.000 at 3.98°C (SA)

0.791 at 25°C (SA)

1.325 at 25°C (SA); 1.327 (NB)

Page 49: 7 Reagents

Solubility

Slightly Soluble in Water (SA)

Soluble in Water (SA)

Completely Water Soluble (SA)

Soluble in Alcohol, Sparingly Soluble in Ether (TCI)

2.6g/100mL H2O (SA)

26g/100L H2Oat 0°C (http://fscimage.fishersci.com/msds/13510.htm)

Soluble in Methanol and Diethyl Ether. Very slightly soluble in Cold Water (ScienceLab)

Almost insoluble in deionized water, cyclohexane, petroleum ether, and hexane. Readily soluble in ethanol,

formic acid, acetic acid, and dichloromethane. (Article Hu, F.H.; Wang, L.S.; Cal, S.F. Solubilities of

Triphenylphosphine Oxide in Selected Solvents. J. Chem. Eng. Data 2009, 54, 1382-1384.)

Page 50: 7 Reagents

Toxicity

LD50 5,800mg/kg (Oral, Rat) (SA)

LD50 1600mg/kg (Oral, Rat) (SA)

LD50 3,550mg/kg (Oral Rat) (SA)LD50 43mg/kg (Oral, Rat) (SA)

LD50 2220mg/kg (Oral, Rat) (ScienceLab)

LD50 7060mg/kg (Oral, Rat) (SA)

LD50 1380mg/kg (Oral, Mouse) (SA)

Page 51: 7 Reagents

Safety/Comments Notes on Source of Information

No Known OSHA Hazards (SA)

Hygroscopic (SA)

No Known OSHA Hazards (SA)Highly Toxic by Ingestion - Fatal if Swallowed (SA).

Skin Irritant - Avoid Contact (NB)

Harmful by Ingestion, Irritant (SA) Aldrich Reagent 98% MSDS from SA

Irritant (SA); Work in Hood Fluka HPLC Reagent ≥99.0% from SA

Corrosive (SA). Toxic and Corrosive - Causing Severe Damage to Skin, Eyes, and Mucous Membranes. Wear Gloves and Avoid Contact with the NaoH Solution. (NB)

Irritant - mild skin and serious eye, May cause Drowsiness or Dizziness, Single Target Organ Toxicity for Liver and Kidneys (SA)May be harmful if ingested, inhaled, or absorbed through the skin. Possibility that prolonged inhalation may cause cancer. Minimize contact. Do not Breath Vapors. (NB Exp37) Carcinogen, Harmful if Swallowed, Irritant (SA); Work in Hood.

Irritant - Avoid Contant with Skin and Eyes. Avoid Inhalation of Vapor or Mist. (SA)

ACS Reagent ≥99.5%, 200 Proof MSDS from SA