6rd.26 w3 · 2016-10-04 · 6rd.26 - w3 july 2002 surface water monitoring report for washington...

6Rd.26 - w 3

JULY 2002 SURFACE WATER MONITORING REPORT FOR WASHINGTON WORKS FACILITY AND LOCAL, LETART AND DRY RUN LANDFILLS WASHINGTON, WV

Date: September 2002

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CORPORATE REMEDIATION GROUP An Alliance between

DuPont and URS Diamond

Barley Mill Plaza, Building 27 Wilmington, Delaware 19805

Project No.: D6WW7423.01 1 8983635.20000

.. - -4

I REGULATORY PROGRAM

Surface water Monitoring Report Table of Contents

TABLE OF CONTENTS

1 .O Introduction ................................................................................................................. 1

2.0 C-8 Analytical Reporting ............................................................................................ 2

3.0 Washington Works Facility ........................................................................................ 3

4.0 Local Landfill.. ............................................................................................................ 4

5.0 Letart Landfill ............................................................................................................. 5

6.0 Dry Run Landfill.. ...................................................................................................... .6

7.0 References ................................................................................................................... 7

TABLES

Table 1 .O

Table 2.0

Table 3.0

Table 4.0

C-8 in Surface Water - Washington Works Facility

C-8 in Surface Water - Local Landfill

C-8 in Surface Water - Letart Landfill

C-8 in Surface Water - Dry Run Landfill

Figure 1.0

Figure 1.1

Figure 1.2

Figure 2.0

Figure 2.1

Figure 2.2

Figure 3.0

Figure 3.1

Figure 3.2 Figure 4.0

Figure 4.1 Figure 4.2

FIGURES

Site Location Map - Washington Works Facility

Surface Water Sample Location Map - Washington Works Facility

C-8 Concentration Map July 2002 - Washington Works Facility Surface Water Site Location Map - Local Landfill

Surface Water Sample Location Map - Local Landfill

C-8 Concentration Map July 2002 - Local Landfill Outfalls

Site Location Map - Letart Landfill

Surface Water Sample Location Map - Letart Landfill

C-8 Concentration Map July 2002 - Letart Landfill Outfalls Site Location Map - Dry Run Surface Water Sample Location Map - Dry Run Landfill C-8 Concentration Map July 2002 - Dry Run Landfill Outfalls

JULGMR.doc Sep. 17,02 Wilmington, DE

i

000444

Surface water Monitoring Report Table of Contents

Appendix A

Appendix B Appendix C

Appendix D

Appendix E Appendix F Appendix G Appendix H

APPENDICES

Laboratory Analytical Data Reports - Washington Works Facility

Chain-of-Custody Records - Washington Works Facility

Laboratory Analytical Data Reports - Local Landfill

Chain-of-Custody Records - Local Landfill

Laboratory Analytical Data Reports - Letart Landfill

Chain-of-Custody Records - Letart Landfill

Laboratory Analytical Data Reports - Dry Run Landfill

Chain-of-Custody Records - Dry Run Landfill

JULGMR.doc Sep. 17.02 000445 ii Wilmington. DE

Surface water Monitoring Report Introduction

I .o INTRODUCTION A multi-media consent order (Order No. GWR-2001-019) was entered into between the West Virginia Department of Environmental Protection (WVDEP), the West Virginia Department of Health and Human Resources - Bureau for Public Health (WVDHHR- BPH) and DuPont on November 15,2001 (Consent Order). The Consent Order identified a series of requirements and tasks to be performed by the parties to determine whether there has been an impact on human health and the environment as a result of releases of ammonium perfluorooctanoate (C-8), CAS Number 3825-26-1, to the environment from DuPont operations at the Washington Works facility and the associated landfills (Local, Letart and Dry Run). The Consent Order established the C-8 Groundwater Investigation Steering Team (GIST) to oversee investigations and activities that will be conducted to assess the presence and extent of C-8 in drinking water, groundwater, and surface water at and around the Washington Works facility and the Local, Letart and Dry Run Landfills.

An additional component of the Consent Order relates to the National Pollutant Discharge Elimination System (NPDES) permit sampling requirements. In this portion of the Consent Order, specific outfalls and outlets (outfalls) are to be sampled monthly for C-8 by DuPont.

Pursuant to Attachment A of the Consent Order, three tasks will be performed by DuPont and evaluated by the GIST, Tasks A, B, and C. Task A: Groundwater Use and Well Survey/Groundwater Monitoring has been completed (DuPont, 2002a; 2002b). Task B: Assessment of Existing Groundwater and Surface Water Monitoring Data includes the compilation of historical C-8 data, monitoring all wells at the landfills and the development of a Groundwater Monitoring Plan (GMP) for the Washington Works facility. The first part of the task, the historical C-8 data compilation report has been submitted to the GIST for evaluation (DuPont, 2002~). The second part of this task, monitoring C-8 in groundwater at the landfills, began in December 2001 and was performed monthly for four months and quarterly thereafter. The third part of the task, the proposed GMP for the Washington Works facility, was submitted to the GIST for evaluation (DuPont, 2002d) and groundwater sampling on the Washington Works facility began in January 2002. Groundwater sampling at the Washington Works facility was conducted monthly for four months and continues quarterly. Task C: Plume IdentificatiodGroundwater Assessment is ongoing.

This report presents the results of the C-8 sampling that was performed in July 2002, Surface water results are presented for the Washington Works facility and the Local, Letart, and Dry Run Landfills.

JULGMR.doc Sep. 17,02 Wilmington, DE

000446 1

Surface water Monitoring Report C-8 Analytical Reporting

2.0 C-8 ANALYTICAL REPORTING The analytical method, method detection limit, and laboratory utilized for C-8 analysis has changed over time. Prior to 1991, DuPont performed C-8 analysis at the DuPont Experimental Station in Wilmington, Delaware. In 1991, when the RCRA Verification Investigation was conducted, the analysis was contracted to the CHZMHill Laboratory in Montgomery, Alabama. Both labs used a Gas ChromatographyElectron Capture Detector (GC-ECD) based analytical method with detection limits for C-8 that ranged from 0.1 to 1.0 ug/l.

CHZMHill conducted C-8 analysis for DuPont into the fall of 1998 when the laboratory ceased operation. At that time, DuPont had completed one round of analysis for the RCRA Facility Investigation (RFI). The analytical work was transferred to Lancaster Laboratories, Lancaster, PA, for the RFI second round analysis in March 1999. Lancaster Laboratories continued to conduct C-8 analysis using GC-ECD for DuPont until October 2001, when development and testing was completed on a new analytical method developed by Exygen Research, Inc. (Exygen; located in State College, PA) that utilizes Liquid Chromatography/Tandem Mass Spectrometry (LC/MS/MS). DuPont adopted the regular use of L C M S M S for C-8 analysis in water in November 2001 and Exygen was contracted to perform the analyses for DuPont.

Exygen reports C-8 results for the laboratory replicate of each field sample. These results are evaluated for precision by comparing the field sample result to the corresponding laboratory replicate result.

D

CI

CI

CI

If both results are less than the practical quantitation limit (PQL), the replicate sample for that analyte is considered to have passed the precision criteria.

If one or both results are between one and five times the PQL, the replicate is considered to have met the precision criteria if the two results differ by less than the PQL.

If one result is less than the PQL and the other is not, and if the two results differed by a value less than the PQL, the replicate is said to have met the acceptance criteria.

Finally, if both results are at least five times the PQL, the replicate is considered to have met the criteria if the relative percent difference (RPD) between the two results is less than or equal to 20%. The RPD is the absolute value of the difference of two measurements divided by their average.

When the precision criteria outlined above are met, Exygen reports the average of the field sample and lab replicate results reported by the laboratory. If criteria for precision are exceeded, Exygen reports the higher of the sample and lab replicate results. Finally, when one result (from the sample/lab replicate pair) is above the PQL and one below, the result that is above the PQLs is reported. C-8 results are recorded in the Corporate Environmental Database (CED) and are reported as FC-143 for consistency with historical results.

U r JULGMR.doc Sep. 17,02 2 Wilmington, DE

Surface water Monitoring Report Washington Works Facility

3.0 WASHINGTON WORKS FACILITY Figure 1.0 shows the location of the Washington Works facility. On July 23rd, 2002, six outfalls were sampled for C-8 (001,002,003, 005,007, and 105). All of these outfalls collect process water and stormwater runoff. Sampling of these outfalls is required by the Consent Order and WV NPDES permit No. WV0001279. The locations of these outfalls are shown in Figure 1.1.

Table 1 .O provides the C-8 analytical results for surface water. For each sampling point listed in this table, historical data is summarized with the most recent results listed first. Figure 1.2 presents the C-8 concentration map for the outfalls sampled in July 2002. Laboratory analytical data reports and the Chain-of-Custody records are included in Appendix A and B, respectively.

JULGMR.doc Sep. 17.02 Wilmington, DE

3 000448

TABLES

000458

Table 1.0 Summary of Analytical Results:

C-8 in Surface Water DuPont Washington Works Facility

Washington, WV

1 of2 000451 Table 1 .O.doc


C-8 in Surface Water DuPont Washington Works Facility Washington, WV

Note: Analytical method changed as of November 2001 (see Section 2.0 for details).

0911 7/02 000432

2 o f 2 Table 1 .O.doc


C-8 in Surface Water Local Landfill

Washington, WV

Note: Analfical method changed as of November 2001 (see Section 2.0 for details).

000433

Table 2.0.doc 0911 7/02 1 of 1


C-8 in Surface Water Letart Landfill

Letart, WV

Note: Analytical method changed as of November 2001 (see Section 2.0 for details).

* Samples were taken at the respective surface water locations. However, due to an error by the courier, the samples arrived at the lab warm and were not analyzed.

0911 7/02 1 of 1

000454

Table 3.0.doc


C-8 in Surface Water Dry Run Landfill

Lubeck, WV

000455

0911 7/02 1 of2 Table 4.0.doc


C-8 in Surface Water Dry Run Landfill

Lubeck, W

09/17/02 2 o f 2

000456

Table 4.0.doc

000457

FIGURES

. . .

Corporate Remediation Group A n All iance b e t w e e n

DuPonl and URS D i a m o n d

0 Barley Mill Plozo. Building 27 Wilrnington. Deloware 19805

Source: MAP TAKEN FROM THE LUBECK. WV USCS OUADRANCLE

T:

SITE LOCATION MAP

Washington, West Virginia DuPont Washington Works Facility

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Wash ing t o n , West Virg in ia K. DAWS A n Alliance between * p P R o M D ( D p I c N )

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C-8 IN SURFACE WATER

GgmJD JULY 2002

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lDL An Alliance between CHECKED Corporate Remediation Group DuPont Washington Works Facility

Washington, West Virginia DuPont and URS Diamond

Barley M i l l Plaza. Building 27 Whington. Delaware 19805

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SITE LOCATION MAP 49

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LANDFILL BWNDRY / PRWER'TY LINE

S C A L E

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OUTLET 101 / A SURFACE WATER SAMPLE

38.0 CONCENTRATION c8 (@)

NFC NO-FLOW CONDITIONS

C- 8 IN SURFACE WATER JULY 2002

I Corporate Remediation Group An Alliance between

DuPonl and URS D i a m o n d

Local Landfill Washington, WV

Barley , . , Mill Plaza, - Building 27

S C A L E

Corporate Remediation Gr An Alliance between

W o n t and The W-C Diamond Croup

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LEGEND

SURFACE WATER SAMPLE LOCATION 66.6 CONCENTRATION C-8 (ug/l)

S C A L E

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C- 8 IN SURFACE WATER JULY 2002

Dry Run Landfill Corporate A n Remedlatlon Alliance b a f w c e n Group I DuPont Washington Works

APPENDICES

000470

APPENDIX A

LABORATORY ANALYTICAL DATA REPORTS

WASHINGTON WORKS FACILITY

q$!gRRCH Precise Research.

Proven Results.

Analytical Results Washington Works C8 Sampling 7/02

DuPont Sample Identification APFO (ng/L)

WWK-Z-Outfall-001 WWK-Z-Outfall-002 WWK-Z-Outfall-003 WWK-Z-Outfall-005 WWK-Z-0 utfall-007 WWK-Z-Outfall-105 WWK-Z-Outfall-007-2 WWK-K-EQBLK-1

Limit of Detection (LOD) for the procedure is appoximately 10 ng/L

Limit of Quantitation (LOQ) for the procedure is 50 ng/L

8630 2290 29 1

19200 597

34700 544 ND

ND - Compound not detected

NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable.

ND e LOD e NQ e LOQ

Results are calculated according to the following criteria

If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported.

If the sample and laboratory duplicate are less tha 250 ng/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported.

000472

GO07

APPENDIX 6

CHAIN-OF-CUSTODY RECORDS

WASHINGTON WORKS FACILITY

-1 I n 1 1 1 WI LU~IVUT/HIVHLYSIS KttJUtSI t W K M Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com Page of -

SAMPLE ANALYSIS - --

CHAIN OF CUSTODY

OTHER INFORMATION

Results Deadline:

Laboratory Report Options: 0 Sample results only 0 Add case narrative 0 Add quality control summar) 0 Add calibration summary 0 Add raw data 0 Other

APPENDIX C


LOCAL LANDFILL

Proven Results.

Analytical Results Local Landfill C8 Sampling 7/02

DuPont Sample Identification

LCL-K-EQBLK-1 LCL-Z-Outfall 004 Old West Stream LCL-2-Outfall004 New West Stream LCL-2-Outfall005 Old Central Stream LCL-Z-Outlet 101

APFO (ng/L)

238 1 1600 11200 321 00 63000

Limit of Detection (LOD) for the procedure is appoxirnately 10 ng/L




ND e LOD c NQ e LOQ

Results are calculated according to the following criteria

If the sample and laboratory duplicate are greater than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported.


000476

0 0 0 7

Research Drive College, PA 16801, USA

T: 814.272.1039 F: 814.231.1580

exygen.com

APPENDIX D


LOCAL LANDFILL

000477

L n m I I v u r LUB II uuY /HNHLYSIS KEQ Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com

Client (name & address): E-mail Address):

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Ap, 5&~C*, f -a- j -

Phone: Fax:

Sampler:\&- - Quotation #:

l?m 1 -xi2 - Lsa n h

v - Please fill out this form comp/ete/y to ensure correct analysis and proper handling of your samples.

1 I

:UEST FORM

Laboratory Report Options:

0 Add quality control summary 0 Add calibration summary

Results Deadline:

0 Sample results only c] Add case narrative

0 Add raw data I - u Other I

ch Q c3 Q

LHAlN OF CUSTODY/ANALYSIS REQUEST e, PA 16801, USA

FORM

, 1.

Phone: ' ,--, Fax:

V Please fill out this form comp/ete/u to ensure correct analysis and proper handling of your samples.

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CHAIN OF CUSTODV - - - - I .

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Laboratory Report Options: 0 Sample results only 0 Add case narrative 0 Add quality control summary

Add calibration summary 0 Add raw data 0 Other

300479

CHAIN OF CUSTODY -

FORM

Results Deadline:

Laboratory Report Options, 0 Sample results only 0 Add case narrative 0 Add quality control summa9 0 Add calibration summary

Add raw data - 0 Other

-\var

v -

Please fill out this form comp/ete& to ensure correct analysis and proper handling of your samples.

0.5 n m

z'u" Specify Matrix Comments

2- k d r l P579r / z 5 9 9 6

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' V K M I R E S E A R C H Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA

T: 814.231.8032 F: 814.231.1580 exygenresearch.com u -

me & E-mail Address):

h t c L 4 . J . A A,&-a un . IJ&.af*dW 9- Project Name: r

Phone: Fax:

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Results Deadline:

Laboratory Report Options: 0 Sample results only 0 Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data 0 Other

000481

rypgen- f - CHAIN OF CUSTODY/ANALYSIS R

Client (name & address): Address): AbQ f i . A ~ ~ ~ & - u / c = F - D ~ - + A&/ B 16'

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CHAIN OF CUSTODY/ANALYSIS R R E S E A R C H Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801

T: 814.231.8032 F: 815.231.1580 exygenresearch.com

Client (name & address): Project Man er (Na e & E-mail Address):

AbQ f i . A ~ ~ ~ & - u / c = F - D ~ - + BL 2ucc7f4 A&/ B /,# . ? 7 & ~ . #f / f /4/ &# , /. .D . AJ,/ A e> UCI -/A 4 s a c .

c / 9 865 Project Name: I

Please fill out this form comp/ete/v to ensure correct analysis and proper handling of your samples.

I . I I

b 'EQl - v -

, USA

CHAIN OF CUSTODY'

I I I I L I I I

OTH ER I N F 0 RM AT1 0 N i

I I

JEST FORM Page of

Results Deadline:

Laboratory Report Options: c) Sample results only 0 Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data u Other

3004Ste

M

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v-

APPENDIX E


LETART LANDFILL

R E S E A R C H Precise Resardj.

Analytical Results LeTart Landfill C8 Sampling 7/02

DuPont Sample Identification APFO (ngA)

LTL-Z-Outlet 002 LTL-K-EQBLK-1

141 0000 ND

Limit of Detection (LOD) for th8 procedure is appoximately 10 ng/L




ND e LOD e NQ < LOQ

Results are calculated according to the fol1owin.g criteria

If the sample and laboratory duplicate are greater.,than 250 ng/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported.

If the sample and laboratory duplicate are less tha 250ty/L,* and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported.

O O C i 7

000484

exygen.com

APPENDIX F


LETART LANDFILL

LHAlIV Ut= LU3 I UUY/ANALYblb KtYlJtb I- F U K M Exygen Research Sample Receiving 3117 Research Drive State College, PA 16801, USA a- 1 T: 814.231.8032 * F 814.231.1580 - exygenresearch.com Page of

Client (name & address): Project Manager (Name & E-mail Address): 4hCh r’ /‘ $ e * ‘Y ‘ , / . . “ . * I f / -

I?

,-

._ / 7 r l / n ///. 1 > -,,*+ P’d &’+ ’J.’ /* /? /y, Aq ., ,:J{/-ir? P A , . , *, f

Project Name: - b b - .& , .f,.. , &L / 7i-d \-

Phone: ? - > - p 3 , - /[/ r* I‘ cu i, -\,a/ A,, I/. > Fax: \ Po. #: L!;;.; L V S C 6 A ’ / . , 1;’ L- -kCl /

Quotation #: Sampler: r, ,c, ,\&- ‘ . J

Please f i l l out this form cump/ete& to ensure correct analysis and proper handling of your samples.

SAMPLE ANALYSIS

Cooler ID # CA‘L w b t , , i . l . Cooler Temp. (“C) 01.1 Received by Date Time

7-.31-n .I o(=+ck, \

$L/L.L /A3

I ~~

I I I LAB USE ONLY

OTHER INFORMATION

1 I

!\

Results Deadline:

Laboratory Report Options: 0 Sample results only 0 Add case narrative 0 Add quality control summary 0 Add calibration summary 0 Add raw data

Other

000486

APPENDIX G


DRY RUN LANDFILL

000487

R E S E A R C H Precise Research. '.. ., Proven Results.

Analytical Results Dry Run Landfill C8 Sampling 7/02

APFO (ng/L) DuPont Sample identification

DRL-Z-Outlet 003 DRL-Z-Outlet 004

Limit of Detection (LOD) for the, procedure is appoximately 10 ng/L

. .

25300 700

Limit of Quantitation (LOQ) for the. procedure is 50 ngR



ND c LOD c NQ c LOQ

Results are calculated according to the followmg criteria

If the sample and laboratory duplicate are greater than 250 ng/L, and the relative peroent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than 20, the higher value is reported.


, 0007 College, PA 16801, USA

exygen.com

APPENDIX H


DRY RUN LANDFILL

000489

v u R E S E A R C H Exygen Research Sample Receiving 3117 Research Drive State College, PA 1680 T: 814.231.8032 F: 814.231 .I 580 exygenresearch.com

Client (name & address): Project’ Manager (Name 81 E-mail Address):

Quotation #:

Please fill out this form comp/ete/y to ensure correct analysis and proper handling of your samples. - SAMPLE ANALYSIS

, USA Page of

:, E , I., ,. . )L‘ I. ’! I I I 1 I I I I I

LAB USE ONLY

CHAIN OF CUSTODY Cooler ID # (:&LCXSIZJ- Cooler Temp. (“C) /I J-

LAB USE ONLY

OT H E R I N F 0 R MAT1 0 N

Results Deadline:

Laboratory Report Options: 0 Sample results only

0 Add case narrative 0 Add quality control summary 0 Add calibration summary

Add raw data 0 Other

000439

Grab

Composite

ber of ainers

6rd.26 w3 · 2016-10-04 · 6rd.26 - w3 july 2002 surface water monitoring report for washington...

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