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Raw Materials Hazardous Substances Criteria

ECS-001, Version 9

22 August 2016

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Hazardous Substances Criteria 1. Conflict Minerals------------------------------------------------------------------------2 2. RoHS---------------------------------------------------------- 2 3. Aromatic Amines from Azo Dyes ----------------------------------------- 3 4. / Ozone Depletion/ Greenhouse Gas ----------------------- 4 5. Miscellaneous Items ---------------------------------------------------------- 4 6. Substances of Very High Concern ---------------------------------------- 5 7. CMR Carcinogenic,Mutagenic or Toxic for Reproduction -------------------------14 8. _ ZDHC_MRSL (December 2015) -------20 9. bluesign system substances list (BSSL)

Consumer safety limits (Version 5.1 November 01 ,2015) -----------------------------37

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Hazardous Substances Criteria 1. Conflict Minerals

Hazardous Substance

CAS No.

Criteria

1 Tantalum 7440-25-7 N.D. 2 Tin 7440-31-5 N.D. 3 Tungsten 7440-33-7 N.D. 4 Gold 7440-57-5 N.D.

2. RoHS2 (Directive 2011/65/EU on the Restriction of the

use of certain Hazardous Substances in Electrical and Electronic Equipment)

Hazardous Substance

Criteria

/ Law/ Test method

1 Cadmium and Cadmium compounds

< 100 ppm Everlights criteria (RoHS Directive 2011/65/EU)

2 Lead and Lead compounds

< 1000 ppm

3 Mercury and Mercury compounds

< 1000 ppm

4 Hexavalent Chromium compounds

< 1000 ppm

5 (PBB) PolyBrominated Biphenyls

< 1000 ppm

6 (DecaBDE)(PBDE) Polybrominated diphenylethers(PBDE) including decabromodiphenyl ether [DecaBDE]

< 1000ppm

7 (2-) (DEHP) Bis(2-ethylhexyl) phthalate < 1000ppm

8 (BBP) Butyl benzyl phthalate < 1000ppm

9 (DBP) Dibutyl phthalate < 1000ppm

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10 (DIBP) Diisobutyl phthalate < 1000ppm

3 Aromatic Amines from Azo Dyes

Hazardous Substance

CAS No.

Criteria

/ Law/ Test method

1 4 - 4-Aminobiphenyl

92-67-1 < 150 ppm

Everlights criteria

Ref: EC No. 552/2009 REACH Annex XVII (< 30 ppm in the articles or dye parts)

2 Benzidine

92-87-5 < 150 ppm

3 4-4--2- 4-Chloro-o-toluidine

95-69-2 < 150 ppm

4 2- 2-Naphthylamine

91-59-8 < 150 ppm

5 o-Aminoazotoluene 97-56-3

< 150 ppm

6 2--4- 2-Amino-4-nitrotoluene

99-55-8 < 150 ppm

7 4- 4-Chloroaniline (para-)

106-47-8 < 150 ppm

8 2,4- 2,4- Diaminoanisole

615-05-4 < 150 ppm

9 4,4- 4,4- Diaminobiphenylmethane

101-77-9 < 150 ppm

10 3,3- 3,3- Dichlorobenzidine

91-94-1 < 150 ppm

11 3,3- 3,3-Dimethoxybenzidine

119-90-4 < 150 ppm

12 3,3- 3,3-Dimethylbenzidine

119-93-7 < 150 ppm

13 3,3--4,4- 3,3Dimethyl-4,4-diaminobiphenylmethane

838-88-0 < 150 ppm

14 2--5- p-Cresidine

120-71-8 < 150 ppm

15 4,4--(2-) 4,4- Methylene-bis-(2-chloroaniline)

101-14-4 < 150 ppm

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16 4,4- 4,4-Oxydianiline

101-80-4 < 150 ppm

17 4,4- 4,4 Thiodianiline

139-65-1 < 150 ppm

18 -2-SVHC o- Toluidine

95-53-4 < 150 ppm

19 2,4- 2,4- Toluylendiamine

95-80-7 < 150 ppm

20 2,4,5- 2,4,5- Trimethylaniline

137-17-7 < 150 ppm

21 -2- o-Anisidine (2-Methoxyaniline)

90-04-0 < 150 ppm

22 2,4- 2,4 - Xylidine

95-68-1 < 150 ppm

23 2,6- 2,6- Xylidine

87-62-7 < 150 ppm

24 4- SVHC 4-aminoazobenzene

60-09-3 < 150 ppm

4 / Ozone Depletion/ Greenhouse Gas

Hazardous Substance

CAS No.

Criteria

/ Law/ Test method

1 (ODS) Ozone depleting substances (ODS)

N.D. REGULATION (EC) No

1005/2009 2 (HFC)(PFC)

Hydrofluorocarbon (HFC)Perfluorocarbon(PFC)

N.D. REGULATION (EC) No

842/2006

5 Miscellaneous Items

Hazardous Substance

CAS No.

Criteria

/ Law/ Test method

1 Asbestos N.D. EC No. 552/2009 REACH Annex XVII

2 Formaldehyde; formalin; formic aldehyde;formol

50-00-0

< 30 ppm

Directive 2002/72/EC

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3

Dimethyl fumarate (DMF) 624-49-7 < 0.1 ppm

Directive 2009/251/EC

Specific phthalates (DEHPDBPBBP

4 DINPDIDPDNOPDNHPDIHPDHNUPDMEP)

< 1,000 ppm EC No. 552/2009 REACH Annex XVII

()5

PFOS; Perfluorooctane sulfonates

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7 Bis(tributyltin)oxide (TBTO) 200-268-0 56-35-9 8 Cobalt dichloride 231-589-4 7646-79-9 9 Diarsenic pentaoxide 215-116-9 1303-28-2

10 Diarsenic trioxide 215-481-4 1327-53-3 11 Dibutyl phthalate (DBP) 201-557-4 84-74-2 12 Hexabromocyclododecane (HBCDD) and all major

diastereoisomers identified: 247-148-4 and 221-695-9

25637-99-4, 3194-55-6

Alpha-hexabromocyclododecane 134237-50-6 Beta-hexabromocyclododecane 134237-51-7 Gamma-hexabromocyclododecane 134237-52-8

13 Lead hydrogen arsenate 232-064-2 7784-40-9 14 Sodium dichromate 234-190-3 7789-12-0,

10588-01-9 15 Triethyl arsenate 427-700-2 15606-95-8 16 2,4-Dinitrotoluene 204-450-0 121-14-2 17 Anthracene oil () 292-602-7 90640-80-5 18 Anthracene oil, anthracene-low 292-604-8 90640-82-7 19 Anthracene oil, anthracene paste 292-603-2 90640-81-6 20 Anthracene oil, anthracene paste, anthracene

fraction 295-275-9 91995-15-2

21 Anthracene oil, anthracene paste,distn. lights 295-278-5 91995-17-4

22 Diisobutyl phthalate 201-553-2 84-69-5 23 Lead chromate 231-846-0 7758-97-6

24 Lead chromate molybdate sulphate red (C.I. Pigment Red 104)

235-759-9 12656-85-8

25 Lead sulfochromate yellow (C.I. Pigment Yellow 34) 215-693-7 1344-37-2

26 Pitch, coal tar, high temp. 266-028-2 65996-93-2

27 Tris(2-chloroethyl)phosphate 204-118-5 115-96-8

28 Acrylamide 201-173-7 79-06-1

29 Trichloroethylene 201-167-4 79-01-6

30 Boric acid 233-139-2 ( 234-343-4)

10043-35-3, 11113-50-1

31 Disodium tetraborate, anhydrous 215-540-4 1303-96-4, 1330-43-4,

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32 Tetraboron disodium heptaoxide, hydrate 235-541-3 12267-73-1

33 Potassium dichromate 231-906-6 7778-50-9

34 Ammonium dichromate 232-143-1 7789-09-5

35 Potassium chromate 232-140-5 7789-00-6

36 Sodium chromate 231-889-5 7775-11-3

37 Cobalt(II) sulphate 233-334-2 10124-43-3

38 Cobalt(II) dinitrate 233-402-1 (10141-05-6)

10141-05-6

39 Cobalt(II) carbonate 208-169-4 513-79-1 40 Cobalt(II) diacetate 200-755-8 71-48-7

41 2-Methoxyethanol 203-713-7 109-86-4

42 2-Ethoxyethanol 203-804-1 110-80-5

43 Chromium trioxide 215-607-8 1333-82-0

44 Acids generated from chromium trioxide and their oligomers. Group containing: Chromic acid, Dichromic acid, Dichromic acid, Oligomers of chromic acid and dichromic acid

231-801-5 / 7738-94-5 236-881-5 / 13530-68-2

7738-94-5, 13530-68-2

45 2-Ethoxyethyl acetate 203-839-2 111-15-9

46 Strontium chromate 232-142-6 7789-06-2

47 1,2-Benzenedicarboxylic acid, di-C7-11-branched and linear alkyl esters

271-084-6 68515-42-4

48 Hydrazine 206-114-9 302-01-2 7803-57-8

49 1-Methyl-2-pyrrolidone 212-828-1 872-50-4

50 1,2,3-Trichloropropane 202-486-1 96-18-4

51 1,2-Benzenedicarboxylic acid, di-C6-8-branched alkyl esters, C7-rich

276-158-1 71888-89-6

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52 Zirconia Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI, part 3, table 3.1 of Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium, silicon and zirconium are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (m). c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight

53 Calcium arsenate 231-904-5 7778-44-1

54 Bis(2-methoxyethyl) ether 203-924-4 111-96-6

55 Aluminosilicate Refractory Ceramic Fibres are fibres covered by index number 650-017-00-8 in Annex VI,part 3, table 3.1 of Regulation (EC) No 1272/2008 ofthe European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, and fulfil the three following conditions: a) oxides of aluminium and silicon are the main components present (in the fibres) within variable concentration ranges b) fibres have a length weighted geometric mean diameter less two standard geometric errors of 6 or less micrometres (m) c) alkaline oxide and alkali earth oxide (Na2O+K2O+CaO+MgO+BaO) content less or equal to 18% by weight

56 Potassium hydroxyoctaoxodizincatedichromate 234-329-8 11103-86-9

57 Lead dipicrate 229-335-2 6477-64-1

58 N,N-dimethylacetamide 204-826-4 127-19-5

59 Arsenic acid 231-901-9 7778-39-4

60 2-Methoxyaniline; o-Anisidine 201-963-1 90-04-0

61 Trilead diarsenate 222-979-5 3687-31-8

62 1,2-dichloroethane 203-458-1 107-06-2

63 Pentazinc chromate octahydroxide 256-418-0 49663-84-5

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64 4-(1,1,3,3-tetramethylbutyl)phenol 205-426-2 140-66-9

65 Formaldehyde, oligomeric reaction products with aniline

500-036-1 25214-70-4

66 Bis(2-methoxyethyl) phthalate 204-212-6 117-82-8

67 Lead diazide, Lead azide 236-542-1 13424-46-9

68 Lead styphnate 239-290-0 15245-44-0

69 2,2'-dichloro-4,4'-methylenedianiline 202-918-9 101-14-4

70 Phenolphthalein 201-004-7 77-09-8

71 Dichromium tris(chromate) 246-356-2 24613-89-6

72 [4-[4,4'-bis(dimethylamino)benzhydrylidene]cyclohe xa-2,5-dien-1-ylidene] dimethylammonium chloride(C.I. Basic Violet 3) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)]

208-953-6 548-62-9

73 1,3,5-tris[(2S and 2R)-2,3-epoxypropyl]-1,3,5-triazine-2,4,6-(1H,3H,5

423-400-0 59653-74-6

74 1,2-bis(2-methoxyethoxy)ethane (TEGDME; triglyme)

203-977-3 112-49-2

75 4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol [with0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)]

209-218-2 561-41-1

76 Lead(II) bis(methanesulfonate) 401-750-5 17570-76-2

77 1,2-dimethoxyethane; ethylene glycol dimethyl ether(EGDME)

203-794-9 110-71-4

78 Diboron trioxide 215-125-8 1303-86-2 79 ,-Bis[4-(dimethylamino)phenyl]-4

(phenylamino)naphthalene-1-methanol (C.I. SolventBlue 4) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)]

229-851-8 6786-83-0

80 1,3,5-Tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione (TGIC)

219-514-3 2451-62-9

81 4,4'-bis(dimethylamino)benzophenone (Michlers ketone)

202-027-5 90-94-8

82 N,N,N',N'-tetramethyl-4,4'-methylenedianiline (Michlers base)

202-959-2 101-61-1

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83 Formamide 200-842-0 75-12-7

84 [4-[[4-anilino-1-naphthyl][4-(dimethylamino)phenyl] methylene]cyclohexa-2,5-dien-1-ylidene] dimethylammonium chloride (C.I. Basic Blue 26) [with 0.1% of Michler's ketone (EC No. 202-027-5) or Michler's base (EC No. 202-959-2)]

219-943-6 2580-56-5

85 Pyrochlore, antimony lead yellow 232-382-1 8012-00-8

86 6-methoxy-m-toluidine (p-cresidine) 204-419-1 120-71-8

87 Henicosafluoroundecanoic acid 218-165-4 2058-94-8

88 Hexahydromethylphthalic anhydride [1], Hexahydro-4-methylphthalic anhydride [2], Hexahydro-1-methylphthalic anhydride [3], Hexahydro-3-methylphthalic anhydride [4] [The individual isomers [2], [3] and [4] (including their cis- and trans- stereo isomeric forms) and all possible combinations of theisomers [1] are covered by this entry]

247-094-1, 243-072-0, 256-356-4, 260-566-1

25550-51-0, 19438-60-9, 48122-14-1, 57110-29-9

89 Cyclohexane-1,2-dicarboxylic anhydride [1], cis-cyclohexane-1,2-dicarboxylic anhydride [2], trans-cyclohexane-1,2-dicarboxylic anhydride [3] [The individual cis- [2] and trans- [3] isomer substances and all possible combinations of the cis-and trans-isomers [1] are covered by this entry]

201-604-9, 236-086-3, 238-009-9

85-42-7, 13149-00-3, 14166-21-3

90 Dibutyltin dichloride (DBTC) 211-670-0 683-18-1

91 Lead bis(tetrafluoroborate) 237-486-0 13814-96-5

92 Lead dinitrate 233-245-9 10099-74-8

93 Silicic acid, lead salt 234-363-3 11120-22-2

94 4-Aminoazobenzene 200-453-6 60-09-3

95 Lead titanium zirconium oxide 235-727-4 12626-81-2

96 Lead monoxide (lead oxide) 215-267-0 1317-36-8

97 o-Toluidine (*Aromatic Amine item18) 202-429-0 95-53-4

98 3-ethyl-2-methyl-2-(3-methylbutyl)-1,3-oxazolidine 421-150-7 143860-04-2

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99 Silicic acid (H2Si2O5), barium salt (1:1), lead-doped[with lead (Pb) content above the applicable generic concentration limit for toxicity for reproduction Repr. 1A (CLP) or category 1 (DSD); the substance is a member of the group entry of lead compounds, with index number 082-001-00-6 begin_of_the_skype_highlighting

272-271-5 68784-75-8

100 Trilead bis(carbonate)dihydroxide 215-290-6 1319-46-6

101 Furan 203-727-3 110-00-9

102 N,N-dimethylformamide 200-679-5 68-12-2

103 4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated [covering well-defined substances and UVCB substances, polymers and homologues]

- -

104 4-Nonylphenol, branched and linear [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 tophenol, covering also UVCB- and well-defined substances which include any of the individual isomers or a combination thereof]

- -

105 4,4'-methylenedi-o-toluidine 212-658-8 838-88-0

106 Diethyl sulphate 200-589-6 64-67-5

107 Dimethyl sulphate 201-058-1 77-78-1

108 Lead oxide sulfate 234-853-7 12036-76-9

109 Lead titanium trioxide 235-038-9 12060-00-3

110 Acetic acid, lead salt, basic 257-175-3 51404-69-4 111 [Phthalato(2-)]dioxotrilead 273-688-5 69011-06-9

112 Bis(pentabromophenyl) ether (decabromodiphenyl ether; DecaBDE)

214-604-9 1163-19-5

113 N-methylacetamide 201-182-6 79-16-3 114 Dinoseb (6-sec-butyl-2,4-dinitrophenol) 201-861-7 88-85-7

115 1,2-Diethoxyethane 211-076-1 629-14-1

116 Tetralead trioxide sulphate 235-380-9 12202-17-4

117 N-pentyl-isopentylphthalate - 776297-69-9

118 Dioxobis(stearato)trilead 235-702-8 12578-12-0

119 Tetraethyllead 201-075-4 78-00-2

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120 Pentalead tetraoxide sulphate 235-067-7 12065-90-6

121 Pentacosafluorotridecanoic acid 276-745-2 72629-94-8

122 Tricosafluorododecanoic acid 206-203-2 307-55-1

123 Heptacosafluorotetradecanoic acid 206-803-4 376-06-7

124 1-bromopropane (n-propyl bromide) 203-445-0 106-94-5

125 Methoxyacetic acid 210-894-6 625-45-6

126 4-methyl-m-phenylenediamine (toluene-2,4-diamine)

202-453-1 95-80-7

127 Methyloxirane (Propylene oxide) 200-879-2 75-56-9 128 Trilead dioxide phosphonate 235-252-2 12141-20-7

129 o-aminoazotoluene 202-591-2 97-56-3

130 1,2-Benzenedicarboxylic acid, dipentylester, branched and linear

284-032-2 84777-06-0

131 4,4'-oxydianiline and its salts 202-977-0 101-80-4

132 Orange lead (lead tetroxide) 215-235-6 1314-41-6

133 Biphenyl-4-ylamine 202-177-1 92-67-1

134 Diisopentylphthalate 210-088-4 605-50-5

135 Fatty acids, C16-18, lead salts 292-966-7 91031-62-8

136 Diazene-1,2-dicarboxamide (C,C'-azodi(formamide))

204-650-8 123-77-3

137 Sulfurous acid, lead salt, dibasic 263-467-1 62229-08-7 138 Lead cyanamidate 244-073-9 20837-86-9

139 Cadmium 231-152-8 7440-43-9

140 Ammonium pentadecafluorooctanoate (APFO) 223-320-4 3825-26-1

141 Pentadecafluorooctanoic acid (PFOA) 206-397-9 335-67-1

142 Dipentyl phthalate (DPP) 205-017-9 131-18-0

143 4-Nonylphenol, branched and linear, ethoxylated [substances with a linear and/or branched alkyl chain with a carbon number of 9 covalently bound in position 4 to phenol, ethoxylated covering UVCB- and well-defined substances, polymers and homologues, which include any of the individual isomers and/or combinations thereof]

- -

144 Cadmium oxide 215-146-2 1306-19-0

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145 Cadmium sulphide 215-147-8 1306-23-6

146 Disodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4-aminonap hthalene-1-sulphonate) (C.I. Direct Red 28)

209-358-4 573-58-0

147 Disodium 4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphen yl]-4-yl]azo] -5-hydroxy-6-(phenylazo)naphthalene-2,7-disulphonate (C.I. Direct Black 38)

217-710-3 1937-37-7

148 Dihexyl phthalate 201-559-5 84-75-3

149 Imidazolidine-2-thione (2-imidazoline-2-thiol) 202-506-9 96-45-7

150 Lead di(acetate) 206-104-4 301-04-2

151 Trixylyl phosphate 246-677-8 25155-23-1

152 1,2-Benzenedicarboxylic acid, dihexyl ester, branched and linear

271-093-5 68515-50-4

153 Cadmium chloride 233-296-7 10108-64-2 154 Sodium perborate; perboric acid, sodium salt 239-172-9

234-390-0 -

155 Sodium peroxometaborate 231-556-4 7632-04-4

156 Cadmium fluoride 232-222-0 7790-79-6

157 Cadmium sulphate 233-331-6 10124-36-4; 31119-53-6

158 2-benzotriazol-2-yl-4,6-di-tert-butylphenol (UV-320) 223-346-6 3846-71-7

159 2-(2H-benzotriazol-2-yl)-4,6-ditertpentylphenol (UV-328)

247-384-8 25973-55-1

160 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stanna tetradecanoate (DOTE)

239-622-4 15571-58-1

161 reaction mass of 2-ethylhexyl 10-ethyl-4,4-dioctyl-7-oxo-8-oxa-3,5-dithia-4-stanna tetradecanoate and 2-ethylhexyl 10-ethyl-4-[[2-[(2-ethylhexyl)oxy]-2-oxoethyl]thio]-4- octyl-7-oxo-8-oxa-3,5-dithia-4-stannatetradecanoate (reaction mass of DOTE and MOTE)

- -

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162 1,2-benzenedicarboxylic acid, di-C6-10-alkyl esters; 1,2-benzenedicarboxylic acid, mixed decyl and hexyl and octyl diesters with 0.3% of dihexyl phthalate

271-094-0 272-013-1

68515-51-5 68648-93-1

163 5-sec-butyl-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [1], 5-sec-butyl-2-(4,6-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane [2] [covering any of the individual isomers of [1] and [2] or any combination thereof]

- -

164 1,3-propanesultone 214-317-9 1120-71-4

165 2,4-di-tert-butyl-6-(5-chlorobenzotriazol-2-yl)phenol (UV-327)

223-383-8 3864-99-1

166 2-(2H-benzotriazol-2-yl)-4-(tert-butyl)-6-(sec-butyl)phenol (UV-350)

253-037-1 36437-37-3

167 Nitrobenzene 202-716-0 98-95-3

168 Perfluorononan-1-oic-acid and its sodium and ammonium salts

206-801-3 375-95-1 21049-39-8 4149-60-4

169 Benzo[def]chrysene (Benzo[a]pyrene)

200-028-5 50-32-8

7 CMR Carcinogenic,Mutagenic or Toxic for Reproduction

Hazardous Substance

Criteria

/ Law/ Test method

CMR Carcinogenic,Mutagenic or Toxic for Reproduction

ND REACH Annex XVII

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CMR Carcinogenic,Mutagenic or Toxic for Reproduction Item Substance name EC number CAS number

1 Polychlorinated terphenyls (PCTs) - - 2 Chloroethylene (Vinyl chloride) 200-831-0 75-01-4 3 Liquid substances or mixtures, which are regarded

as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: (a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14 categories 1 and 2, 2.15 types A to F; (b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8 effects other than narcotic effects, 3.9 and 3.10; (c)

- -

4 Tris (2,3 dibromopropyl) phosphate - 126-72-7 5 Benzene 200-753-7 71-43-2 6 Asbestos fibres, (a) Crocidolite - 12001-28-4 7 Asbestos fibres (b) Amosite - 12172-73-5 8 Asbestos fibres (c) Anthophyllite - 77536-67-5 9 Asbestos fibres (d) Actinolite - 77536-66-4

10 Asbestos fibres (e) Tremolite - 77536-68-6 11 Asbestos fibres (f) Chrysotile - 12001-29-5 12 Asbestos fibres (f) Chrysotile - 132207-32-0 13 Tris(aziridinyl)phosphinoxide 208-892-5 545-55-1 14 Polybromobiphenyls; Polybrominatedbiphenyls - 59536-65-1 15 (a) Soap bark powder (Quillaja saponaria) and its 273-620-4 68990-67-0 16 (b) Powder of the roots of Helleborus viridis and - - 17 (c) Powder of the roots of Veratrum album and - - 18 (d) Benzidine and/or its derivatives 202-199-1 92-87-5 19 (e) o-Nitrobenzaldehyde 209-025-3 552-89-6 20 (f) Wood powder - - 21 (a) Ammonium sulphide 235-223-4 12135-76-1 22 (b) Ammonium hydrogen sulphide 235-184-3 12124-99-1 23 (c) Ammonium polysulphide 232-989-1 9080-17-5

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24 Volatile esters of bromoacetic acids: (a) Methyl 202-499-2 96-32-2 25 Volatile esters of bromoacetic acids: (b) Ethyl 203-290-9 105-36-2 26 Volatile esters of bromoacetic acids: (c) Propyl - 35223-80-4 27 Volatile esters of bromoacetic acids: (d) Butyl 242-729-9 18991-98-5 28 2-Naphthylamine 202-080-4 91-59-8 29 Benzidine 202-199-1 92-87-5 30 4-Nitrobiphenyl 202-204-7 92-93-3 31 4-Aminobiphenyl xenylamine 202-177-1 92-67-1 32 Lead carbonates: (a) Neutral anhydrous carbonate 209-943-4 598-63-0 33 Lead carbonates: (b) Trilead-bis(carbonate)- 215-290-6 1319-46-6 34 Lead sulphates: (a) PbSO4 231-198-9 7446-14-2 35 Lead sulphates: (b) PbxSO4 239-831-0 15739-80-7 36 Mercury compounds - - 37 Mercury 231-106-7 7439-97-6 38 Arsenic compounds - - 39 Organostannic compounds - - 40 Di--oxo-di-n-butylstanniohydroxyborane/ Dibutyltin 401-040-5 75113-37-0 41 Pentachlorophenol 201-778-6 87-86-5 42 Cadmium 231-152-8 7440-43-9 43 Monomethyl tetrachlorodiphenyl methane Trade - 76253-60-6 44 Monomethyl-dichloro-diphenyl methane Trade - - 45 Monomethyl-dibromo-diphenyl methane - 99688-47-8 46 Nickel 231-111-4 7440-02-0 47 Substances which appear in Part 3 of Annex VI to - - 48 Substances which appear in Part 3 of Annex VI to

Regulation (EC) No 1272/2008 classified as germ cell mutagen category 1A or 1B (Table 3.1) or mutagen category 1 or 2 (Table 3.2) and listed as follows: Mutagen category 1A (Table 3.1)/mutagen category 1 (Table 3.2) listed in Appendix 3 Mutagen category 1B (Table 3.1)/mutagen category 2 (Table 3.2) listed in Appendix 4

- -

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49 Substances which appear in Part 3 of Annex VI to Regulation (EC) No 1272/2008 classified as toxic to reproduction category 1A or 1B (Table 3.1) or toxic to reproduction category 1 or 2 (Table 3.2) and listedas follows: Reproductive toxicant category 1A adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 1 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 5 Reproductive toxicant category 1B adverse effects on sexual function and fertility or on development (Table 3.1) or reproductive toxicant category 2 with R60 (May impair fertility) or R61 (May cause harm to the unborn child) (Table 3.2) listed in Appendix 6

- -

50 (a) Creosote; wash oil 232-287-5 8001-58-9 51 (b) Creosote oil; wash oil 263-047-8 61789-28-4 52 (c) Distillates (coal tar), naphthalene oils; 283-484-8 84650-04-4 53 (d) Creosote oil, acenaphthene fraction; wash oil 283-484-8, 90640-84-9 54 (e) Distillates (coal tar), upper; heavy anthracene oil 266-026-1 65996-91-0 55 (f) Anthracene oil 292-602-7 90640-80-5 56 (g) Tar acids, coal, crude; crude phenols 266-019-3 65996-85-2 57 (h) Creosote, wood 232-419-1 8021-39-4 58 (i) Low temperature tar oil, alkaline; extract residues 310-191-5 122384-78-5 59 Chloroform 200-663-8 67-66-3 60 1,1,2-Trichloroethane 201-166-9 79-00-5 61 1,1,2,2-Tetrachloroethane 201-197-8 79-34-5 62 1,1,1,2-Tetrachloroethane - 630-20-6 63 Pentachloroethane 200-925-1 76-01-7 64 1,1-Dichloroethene 200-864-0 75-35-4 65 Substances classified as flammable gases category - - 66 Hexachloroethane 200-666-4 67-72-1 67 Azocolourants and Azodyes - - 68 Diphenylether, octabromo derivative C12H2Br8O - - 69 (a) Nonylphenol C6H4(OH)C9H19 246-672-0 25154-52-3 70 (b) Nonylphenol ethoxylates (C2H4O)nC15H24O - - 71 Chromium VI compounds - - 72 Toluene 203-625-9 108-88-3

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73 Trichlorobenzene 204-428-0 120-82-1 74 Polycyclic-aromatic hydrocarbons (PAH) (a) - 50-32-8 75 Polycyclic-aromatic hydrocarbons (PAH) (b) - 192-97-2 76 Polycyclic-aromatic hydrocarbons (PAH) ( c ) - 56-55-3 77 Polycyclic-aromatic hydrocarbons (PAH) (d) - 218-01-9 78 Polycyclic-aromatic hydrocarbons (PAH) (e) - 205-99-2 79 Polycyclic-aromatic hydrocarbons (PAH) (f) - 205-82-3 80 Polycyclic-aromatic hydrocarbons (PAH) (g) - 207-08-9 81 Polycyclic-aromatic hydrocarbons (PAH) (h) - 53-70-3 82 The following phthalates (or other CAS and EC

numbers covering the substance): (a) Bis (2-ethylhexyl) phthalate (DEHP)

204-211-0 117-81-7

83 The following phthalates (or other CAS and EC numbers covering the substance): (b) Dibutyl phthalate (DBP)

201-557-4 84-74-2

84 The following phthalates (or other CAS and EC numbers covering the substance): (c) Benzyl butyl phthalate (BBP)

201-622-7 85-68-7

85 The following phthalates (or other CAS- and EC numbers covering the substance): (a) Di-isononyl phthalate (DINP)

249-079-5 and 271-090-9

28553-12-0 and 68515-48-0

86 The following phthalates (or other CAS- and EC numbers covering the substance): (b) Di-isodecyl phthalate (DIDP)

247-977-1 and 271-091-4

26761-40-0 and 68515-49-1

87 The following phthalates (or other CAS- and EC numbers covering the substance): (c) Di-n-octyl phthalate (DNOP)

204-214-7 117-84-0

88 2-(2-methoxyethoxy)ethanol (DEGME) 203-906-6 111-77-3 89 2-(2-butoxyethoxy)ethanol (DEGBE) 203-961-6 112-34-5 90 Methylenediphenyl diisocyanate (MDI) including the

following specific isomers: 247-714-0 26447-40-5

91 a) 4,4-Methylenediphenyl diisocyanate 202-966-0 101-68-8 92 b) 2,4-Methylenediphenyl diisocyanate 227-534-9 5873-54-1 93 c) 2,2-Methylenediphenyl diisocyanate 219-799-4 2536-05-2 94 Cyclohexane 203-806-2 110-82-7 95 Ammonium nitrate (AN) 229-347-8 6484-52-2 96 Dichloromethane 200-838-9 75-09-2 97 Acrylamide - 79-06-1

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98 Dimethylfumarate (DMF) 210-849-0 624-49-7 99 Phenylmercury acetate 200-532-5 62-38-4 100 Phenylmercury propionate 203-094-3 103-27-5 101 Phenylmercury 2-ethylhexanoate 236-326-7 13302-00-6 102 Phenylmercury octanoate - 13864-38-5 103 Phenylmercury neodecanoate 247-783-7 26545-49-3 104 Lead and its compounds 231-100-4 7439-92-1

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8 _ ZDHC_MRSL (December 2015)

CHAPTER 1: MRSL for Textiles and Synthetic Leather Processing

CAS No. Substance

Group A: Raw Material and

Finished Product Supplier Guidance

Group B: Chemical Supplier Commercial Formulation Limit

Potential Uses in Apparel and Footwear Textile Processing

General Techniques for Analysing Chemicals

Alkylphenol (AP) and Alkylphenol Ethoxylates (APEOs): including all isomers104-40-5

11066-49-2 25154-52-3 84852-15-3

Nonylphenol (NP), mixed isomers

No intentional use

250 ppm

APEOs can be used as or found in: detergents, scouring agents, spinning oils, wetting agents, softeners, emulsifier/dispersing agents for dyes and prints, impregnating agents, de- gumming for silk production, dyes and pigment preparations, polyester padding and down/feather fillings.

Liquid chromatography- mass spectrometry (LC- MS), gas chromatography- mass spectrometry (GC- MS)

140-66-9 1806-26-4

27193-28-8 Octylphenol (OP), mixed isomers 250 ppm

9002-93-1 9036-19-5

68987-90-6 Octylphenol ethoxylates (OPEO) 500 ppm

9016-45-9 26027-38-3 37205-87-1 68412-54-4

127087-87-0

Nonylphenol ethoxylates (NPEO)

500 ppm

Chlorobenzenes and Chlorotoluenes 95-50-1 1,2-dichlorobenzene

No intentional use

1000 ppm Chlorobenzenes and chlorotoluenes (chlorinated aromatic hydrocarbons) can be used as carriers in the dyeing process of polyester or wool/polyester fibres. They can also be used as solvents.

GC-MS Other isomers of mono-, di-, tri-, tetra-, penta- and hexachlorobenzene and mono-, di-, tri-, tetra- and pentachlorotoluene

Sum = 200 ppm

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CAS No. Substance






Chlorophenols 25167-83-3 Tetrachlorophenol (TeCP)

No intentional use

Sum = 20 ppm

Chlorophenols are polychlorinated compounds used as preservatives or pesticides.

Pentachlorophenol (PCP) and tetrachlorophenol (TeCP) have been used in the past to prevent mould when storing/ transporting, raw hides and leather. They are now regulated and should not be used.

GC-MS

EN ISO 17070

87-86-5 Pentachlorophenol (PCP)

Sum = 50 ppm

4901-51-3 2,3,4,5-tetrachlorophenol58-90-2 2,3,4,6-tetrachlorophenol

935-95-5 2,3,5,6-tetrachlorophenol95-57-8 2-chlorophenol

120-83-2 2,4-dichlorophenol583-78-8 2,5-dichlorophenol87-65-0 2,6-dichlorophenol95-95-4 2,4,5-trichlorophenol88-06-2 2,4,6-trichlorophenol

591-35-5 3,5-dichlorophenol576-24-9 2,3-dichlorophenol95-77-2 3,4-dichlorophenol

108-43-0 3-chlorophenol106-48-9 4-chlorophenol

15950-66-0 2,3,4-trichlorophenol933-78-8 2,3,5-trichlorophenol609-19-8 3,4,5-trichlorophenol

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CAS No. Substance






Dyes Azo (Forming Restricted Amines) 101-14-4 4,4-methylene-bis-(2-chloro-aniline)

No intentional use

150 ppm

Azo dyes and pigments are colourants that incorporate one or several azo groups (-N=N-) bound with aromatic compounds. Thousands of azo dyes exist, but only those that degrade to form the listed cleavable amines are restricted. Azo dyes that release these amines are regulated and should no longer be used for dyeing of textiles.

LC, GC

101-77-9 4,4-methylenedianiline 150 ppm 101-80-4 4,4-oxydianiline 150 ppm 106-47-8 4-chloroaniline 150 ppm 119-90-4 3,3-dimethoxylbenzidine 150 ppm 119-93-7 3,3-dimethylbenzidine 150 ppm 120-71-8 6-methoxy-m-toluidine 150 ppm 137-17-7 2,4,5-trimethylaniline 150 ppm 139-65-1 4,4-thiodianiline 150 ppm 60-09-3 4-aminoazobenzene 150 ppm

615-05-4 4-methoxy-m-phenylenediamine 150 ppm 838-88-0 4,4-methylenedi-o-toluidine 150 ppm 87-62-7 2,6-xylidine 150 ppm 90-04-0 o-anisidine 150 ppm 91-59-8 2-naphthylamine 150 ppm 91-94-1 3,3-dichlorobenzidine 150 ppm 92-67-1 4-aminodiphenyl 150 ppm 92-87-5 Benzidine 150 ppm 95-53-4 o-toluidine 150 ppm 95-68-1 2,4-xylidine 150 ppm 95-69-2 4-chloro-o-toluidine 150 ppm 95-80-7 4-methyl-m-phenylenediamine 150 ppm 97-56-3 o-aminoazotoluene 150 ppm 99-55-8 5-nitro-o-toluidine 150 ppm

Dyes Navy Blue Colourant118685-33-9 Component 1: C39H23ClCrN7O12S2Na

No intentional use 250 ppm Navy Blue colourants are regulated and should no longer be used for dyeing of textiles.

LC Not Allocated Component 2: C46H30CrN10O20S23Na

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CAS No. Substance






Dyes Carcinogenic or Equivalent Concern 1937-37-7 C.I. Direct Black 38

No intentional use

250 ppm

Most of these substances are regulated and should no longer be used for dyeing of textiles.

LC

2602-46-2 C.I. Direct Blue 6 250 ppm 3761-53-3 C.I. Acid Red 26 250 ppm 569-61-9 C.I. Basic Red 9 250 ppm 573-58-0 C.I. Direct Red 28 250 ppm 632-99-5 C.I. Basic Violet 14 250 ppm

2475-45-8 C.I. Disperse Blue 1 250 ppm 2475-46-9 C.I. Disperse Blue 3 250 ppm 2580-56-5 C.I. Basic Blue 26 (with Michlers Ketone > 0.1%) 250 ppm 569-64-2 C.I. Basic Green 4 (malachite green chloride) 250 ppm

2437-29-8 C.I. Basic Green 4 (malachite green oxalate) 250 ppm 10309-95-2 C.I. Basic Green 4 (malachite green) 250 ppm

82-28-0 Disperse Orange 11 250 ppm Dyes Disperse (Sensitising)

119-15-3 Disperse Yellow 1

No intentional use

250 ppm

Disperse dyes are a class of water- insoluble dyes that penetrate the fibre system of synthetic or manufactured fibres and are held in place by physical forces without forming chemical bonds. Disperse dyes are used in synthetic fibre (e.g., polyester, acetate, polyamide). Restricted disperse dyes are suspected of causing allergic reactions and should no longer be used for dyeing of textiles.

LC

12222-97-8 Disperse Blue 102 250 ppm 12223-01-7 Disperse Blue 106 250 ppm 12236-29-2 Disperse Yellow 39 250 ppm 13301-61-6 Disperse Orange 37/59/76 250 ppm 23355-64-8 Disperse Brown 1 250 ppm 2581-69-3 Disperse Orange 1 250 ppm 2832-40-8 Disperse Yellow 3 250 ppm 2872-48-2 Disperse Red 11 250 ppm 2872-52-8 Disperse Red 1 250 ppm 3179-89-3 Disperse Red 17 250 ppm 3179-90-6 Disperse Blue 7 250 ppm 3860-63-7 Disperse Blue 26 250 ppm

54824-37-2 Disperse Yellow 49 250 ppm 12222-75-2 Disperse Blue 35 250 ppm 61951-51-7 Disperse Blue 124 250 ppm 6373-73-5 Disperse Yellow 9 250 ppm 730-40-5 Disperse Orange 3 250 ppm

56524-77-7 Disperse Blue 35 250 ppm

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CAS No. Substance






Flame Retardants 115-96-8 Tris(2-chloroethyl)phosphate (TCEP)

No intentional use

250 ppm

Flame retardant chemicals are rarely used to meet flammability requirements in childrens clothing and adult products. They should no longer be used in apparel and footwear.

GC-MS

1163-19-5 Decabromodiphenyl ether (DecaBDE) 250 ppm 126-72-7 Tris(2,3,-dibromopropyl)-phosphate (TRIS) 250 ppm

32534-81-9 Pentabromodiphenyl ether (PentaBDE) 250 ppm 32536-52-0 Octabromodiphenyl ether (OctaBDE) 250 ppm 5412-25-9 Bis(2,3-dibromopropyl)phosphate (BIS) 250 ppm 545-55-1 Tris(1-aziridinyl)phosphine oxide) (TEPA) 250 ppm

59536-65-1 Polybromobiphenyls (PBB) 250 ppm 79-94-7 Tetrabromobisphenol A (TBBPA) 250 ppm

3194-55-6 Hexabromocyclodecane (HBCDD) 250 ppm 3296-90-0 2,2-bis(bromomethyl)-1,3-propanediol (BBMP) 250 ppm

13674-87-8 Tris(1,3-dichloro-isopropyl) phosphate (TDCP) 250 ppm 85535-84-8 Short-chain chlorinated Paraffins (SCCP)

(C10-C13) 50 ppm Glycols

111-96-6 Bis(2-methoxyethyl)-ether

No intentional use

50 ppm In apparel and footwear, glycols have a wide range of uses including as solvents for finishing/cleaning, printing agents, and dissolving and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations).

High-performance liquid chromatography (HPLC), LC- MS

110-80-5 2-ethoxyethanol 50 ppm 111-15-9 2-ethoxyethyl acetate 50 ppm 110-71-4 Ethylene glycol dimethyl ether 50 ppm 109-86-4 2-methoxyethanol 50 ppm 110-49-6 2-methoxyethylacetate 50 ppm

70657-70-4 2-methoxypropylacetate 50 ppm 112-49-2 Triethylene glycol dimethyl ether 50 ppm

Halogenated Solvents107-06-2 1,2-dichloroethane

No intentional use

5 ppm In apparel and footwear, solvents are used as finishing/cleaning and printing agents, for dissolving and diluting fats, oils and adhesives (e.g., in degreasing orcleaning operations).

GC-MS

75-09-2 Methylene chloride 5 ppm 79-01-6 Trichloroethylene 40 ppm

127-18-4 Tetrachloroethylene 5 ppm

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CAS No. Substance






Organotin CompoundsMultiple Dibutyltin (DBT)

No intentional use

20 ppm Organotins are a class of chemicals combining tin and organics such as butyland phenyl groups. Organotins are predominantly found in the environmentas antifoulants in marine paints, but theycan also be used as biocides (e.g., antibacterials), catalysts in plastic and glue production and heat stabilisers in plastics/rubber. In textiles and apparel, organotins are associated with plastics/rubber, inks, paints, metallic glitter, polyurethane products and heat transfer material.

GC-MS, low resolution mass spectrometry (LRMS)

Multiple Mono-, di- and tri-methyltin derivatives 5 ppm Multiple Mono-, di- and tri-butyltin derivatives 5 ppm Multiple Mono-, di- and tri-phenyltin derivatives 5 ppm

Multiple

Mono-, di- and tri-octyltin derivatives

5 ppm

Polycyclic Aromatic Hydrocarbons (PAHs) 50-32-8 Benzo[a]pyrene (BaP)

No intentional use

20 ppm

GC-MS

120-12-7 Anthracene

Sum = 200 ppm

Polycyclic aromatic hydrocarbons (PAHs)are natural components of crude oil andare a common residue from oil refining.PAHs have a characteristic smell similar to the smell of car tires or asphalt. Oil residues containing PAHs are added to rubber and plastics as a softener or extender and may be found in rubber, plastics, lacquers and coatings. PAHs areoften found in the outsoles of footwear and in printing pastes of screen prints. PAHs can be present as impurities in Carbon Black. They also may be formed from thermal decomposition of recycledmaterials during reprocessing.

Naphthalene: Dispersing agents for textile dyes may contain high residual naphthalene concentrations due to the use of low quality naphthalene derivatives (e.g., poor quality naphthalene sulphonate formaldehyde condensation products).

129-00-0 Pyrene 191-24-2 Benzo[ghi]perylene192-97-2 Benzo[e]pyrene193-39-5 Indeno[1,2,3-cd]pyrene205-82-3 Benzo[j]fluoranthene205-99-2 Benzo[b]fluoranthene206-44-0 Fluoranthene207-08-9 Benzo[k]fluoranthene208-96-8 Acenaphthylene218-01-9 Chrysene 53-70-3 Dibenz[a,h]anthracene56-55-3 Benzo[a]anthracene83-32-9 Acenaphthene85-01-8 Phenanthrene86-73-7 Fluorene

91-20-3

Naphthalene

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CAS No. Substance






Perfluorinated and Polyfluorinated Chemicals (PFCs)Durable water, oil and stain repellent finishes and soil release finishes (fluorinated polymers) based on long-chain technology are banned from intentional use. Long-chain compounds according to the Organisation for Economic Co-operation and Development (OECD) definition (http://www.oecd.org/ehs/pfc/) are based on long-chain perfluorocarboxylic acids (C8 and higher) and on long-chain perfluoroalkyl sulfonates (C6 and higher).

The main contaminants of this technology include: Perfluoroalkyl sulfonates (PFSAs) with carbon chain lengths C6 and higher (e.g., PFOS, perfluorooctane sulfonate) Perfluorocarboxylic acids with carbon chain lengths C8 and higher (e.g., PFOA, perfluorooctanoic acid)

Multiple Perfluorooctane sulfonate (PFOS) and related substances

No intentional use

Sum = 2 ppm PFOA and PFOS may be present as unintended by-products in long-chain commercial water, oil and stain repellent agents. PFOA also may be in use for polymers like polytetrafluoroethylene (PTFE).

LC-MS Multiple Perfluorooctanoic acid (PFOA) and related

substances 2 ppm

Phthalates including all other esters of ortho-phthalic acid117-81-7 Di(ethylhexyl) phthalate (DEHP)

No intentional use

Sum of all phthalates = 250 ppm

Esters of ortho-phthalic acid (phthalates) are a class of organic compounds commonly added to plastics to increase flexibility. They sometimes are used to facilitate moulding of plastic by decreasing its melting temperature.

Phthalates can be found in: Flexible plastic components

(e.g., PVC) Print pastes Adhesives Plastic buttons Plastic sleevings Polymeric coatings

GC-MS

117-82-8 Bis(2-methoxyethyl) phthalate (DMEP)117-84-0 Di-n-octyl phthalate (DNOP)

26761-40-0 Di-iso-decyl phthalate (DIDP)28553-12-0 Di-isononyl phthalate (DINP)

84-75-3 Di-n-hexyl phthalate (DnHP)84-74-2 Dibutyl phthalate (DBP)85-68-7 Butyl benzyl phthalate (BBP)84-76-4 Dinonyl phthalate (DNP)84-66-2 Diethyl phthalate (DEP)

131-16-8 Di-n-propyl phthalate (DPRP)84-69-5 Di-isobutyl phthalate (DIBP)84-61-7 Di-cyclohexyl phthalate (DCHP)

27554-26-3 Di-iso-octyl phthalate (DIOP)68515-42-4 1,2-benzenedicarboxylic acid, di-C7-11-branched

and linearalkyl esters (DHNUP)

71888-89-6 1,2-benzenedicarboxylic acid,di-C6-8-branchedalkyl esters,C7-rich (DIHP)

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CAS No. Substance






Total Heavy MetalsListed metals are banned from intentional use in textile manufacturing/finishing. Additionally, residual traces of antimony, zinc, copper, nickel, tin, barium, cobalt, iron, manganese, selenium and silver in colourants are expected to comply with the Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers (ETAD) concentration limits (http://www.etad.com/).

7440-38-2

Arsenic (As)

No intentional use

50 ppm

Arsenic and its compounds can be used in some preservatives, pesticides and defoliants for cotton. It is also associated with synthetic fibres, paints, inks, trims and plastics.

Inductively coupled plasma- optical emission spectrometry (ICP-OES), atomic absorption spectroscopy (AAS)

7440-43-9

Cadmium (Cd)

20 ppm (50 ppm for pigments)

Cadmium compounds are found in or used as: pigments (particularly red, orange, yellow and green), a stabiliser for PVC plastic and in fertilisers, biocides and paints (e.g., surface paints on zippers and buttons).

7439-97-6

Mercury (Hg)


Mercury compounds can be present in pesticides and can be found as contamination in caustic soda (NaOH). Mercury compounds may be used in paints (e.g., surface paints on zippers and buttons).

7439-92-1 Lead (Pb) 100 ppm

In apparel and footwear, lead may be associated with plastics, paints, inks, pigments and surface coatings.

18540-29-9 Chromium (VI) 10 ppm

Although typically associated with leather tanning, chromium VI also may be used in the dyeing of wool (after the chroming process).

Volatile Organic Compounds (VOC) 71-43-2 Benzene

No intentional use

50 ppm These volatile organic compounds should not be used in textile auxiliary chemical preparations. They are associated with solvent-based processes like solvent- based polyurethane coatings and glues/adhesives. They should not be used for any kind of facility cleaning or spot cleaning.

GC-MS

1330-20-7 Xylene 500 ppm95-48-7 o-cresol 500 ppm

106-44-5 p-cresol 500 ppm

108-39-4

m-cresol

500 ppm

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Chapter 2: MRSL for Leather Processing

CAS No. Substance

Group A: Raw Material and Finished Product

Supplier Guidance

Group B: Chemical Supplier Commercial

Formulation Limit Potential Uses in Leather Processing for

Apparel and Footwear General Techniques for

Analysing Chemicals within commercial formulations

Alkylphenol (AP) and Alkylphenol Ethoxylates (APEOs): including all isomers104-40-5

11066-49-2 25154-52-3 84852-15-3

Nonylphenol (NP), mixed isomers

No intentional use

250 ppm

APEOs can be used in leather processing or found in a variety of formulations such as detergents, wetting agents, emulsifier/ dispersing agents/dedusting agents for dyes and prints, dyes and pigment preparations, degreasing and fur scouring agents, fat liquors and greases, water borne dispersions and emulsions used in the beamhouse and finishing agents.

NP and OP are not used by the leather industry, but could be present as contaminants.

Liquid chromatography-mass spectrometry (LC-MS), gas chromatography-mass spectrometry (GC-MS)

EN ISO 18219 -1 EN ISO 18219 2

140-66-9 1806-26-4

27193-28-8 Octylphenol (OP), mixed isomers 250 ppm

9002-93-1 9036-19-5

68987-90-6 Octylphenol ethoxylates (OPEO) 500 ppm

9016-45-9 26027-38-3 37205-87-1 68412-54-4

127087-87-0

Nonylphenol ethoxylates (NPEO)

500 ppm

Chlorobenzenes and Chlorotoluenes 95-50-1 1,2-dichlorobenzene

No intentional use 1000 ppm Chlorobenzenes and chlorotoluenes can be

used for degreasing sheep and pig skins. They can also be used as solvents (e.g., in chemical synthesis).

GC-MS Other isomers of mono-, di-, tri-, tetra-, penta- and hexachlorobenzene and mono-, di-, tri-, tetra- and pentachlorotoluene

Sum = 200 ppm

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CAS No. Substance


Supplier Guidance





Chlorophenols 25167-83-3 Tetrachlorophenol (TeCP)

No intentional use

Sum = 20 ppm

Chlorophenols are polychlorinated compounds used as preservatives or pesticides.

Pentachlorophenol (PCP) and tetrachlorophenol (TeCP) have been used in the past to prevent mould when storing/transporting, raw hides and leather. They are now regulated and should not be used.

GC-MS

EN ISO 17070

87-86-5 Pentachlorophenol (PCP)4901-51-3 2,3,4,5-tetrachlorophenol

Sum = 50 ppm

58-90-2 2,3,4,6-tetrachlorophenol935-95-5 2,3,5,6-tetrachlorophenol95-57-8 2-chlorophenol

120-83-2 2,4-dichlorophenol583-78-8 2,5-dichlorophenol87-65-0 2,6-dichlorophenol95-95-4 2,4,5-trichlorophenol88-06-2 2,4,6-trichlorophenol

591-35-5 3,5-dichlorophenol576-24-9 2,3-Dichlorophenol95-77-2 3,4-Dichlorophenol

108-43-0 3-Chlorophenol106-48-9 4-Chlorophenol

15950-66-0 2,3,4-Trichlorophenol933-78-8 2,3,5-Trichlorophenol609-19-8 3,4,5-Trichlorophenol

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CAS No.

Substance



Group B: Chemical Supplier

Commercial Formulation Limit


General Techniques for

Analysing Chemicals

Dyes Azo (Forming Restricted Amines) 101-14-4 4,4-methylene-bis-(2-chloro-aniline)

No intentional use

150 ppm

Azo dyes and pigments are colourants that incorporate one or several azo groups (-N=N-) bound with aromatic compounds. Thousands of azo dyes exist, but only those that degrade to form the listed cleavable amines are restricted. Azo dyes that release these amines are regulated and should no longer be used for dyeing of textiles.

LC, GC

101-77-9 4,4-methylenedianiline 150 ppm101-80-4 4,4-oxydianiline 150 ppm106-47-8 4-chloroaniline 150 ppm119-90-4 3,3-dimethoxylbenzidine 150 ppm119-93-7 3,3-dimethylbenzidine 150 ppm120-71-8 6-methoxy-m-toluidine 150 ppm137-17-7 2,4,5-trimethylaniline 150 ppm139-65-1 4,4-thiodianiline 150 ppm60-09-3 4-aminoazobenzene 150 ppm

615-05-4 4-methoxy-m-phenylenediamine 150 ppm838-88-0 4,4-methylenedi-o-toluidine 150 ppm87-62-7 2,6-xylidine 150 ppm90-04-0 o-anisidine 150 ppm91-59-8 2-naphthylamine 150 ppm91-94-1 3,3-dichlorobenzidine 150 ppm92-67-1 4-aminodiphenyl 150 ppm92-87-5 Benzidine 150 ppm95-53-4 o-toluidine 150 ppm95-68-1 2,4-xylidine 150 ppm95-69-2 4-chloro-o-toluidine 150 ppm95-80-7 4-methyl-m-phenylenediamine 150 ppm97-56-3 o-aminoazotoluene 150 ppm99-55-8 5-nitro-o-toluidine 150 ppm

Dyes Navy Blue Colourant118685-33-9 Component 1: C39H23ClCrN7O12S2Na

No intentional use

250 ppm Navy Blue colourants are regulated and should no longer be used for dyeing of textiles.

LC Not Allocated Component 2: C46H30CrN10O20S23Na

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CAS No. Substance


Supplier Guidance





Dyes Carcinogenic or Equivalent Concern 1937-37-7 C.I. Direct Black 38

No intentional use

250 ppm

Most of these substances are regulated in many countries. All should no longer be used for dyeing of leather.

LC

2602-46-2 C.I. Direct Blue 6 250 ppm 3761-53-3 C.I. Acid Red 26 250 ppm 569-61-9 C.I. Basic Red 9 250 ppm 573-58-0 C.I. Direct Red 28 250 ppm 632-99-5 C.I. Basic Violet 14 250 ppm

2475-45-8 C.I. Disperse Blue 1 250 ppm 2475-46-9 C.I. Disperse Blue 3 250 ppm 2580-56-5 C.I. Basic Blue 26 (with Michlers Ketone >

0.1%) 250 ppm

569-64-2 C.I. Basic Green 4 (malachite green chloride) 250 ppm

2437-29-8 C.I. Basic Green 4 (malachite green oxalate) 250 ppm 10309-95-2 C.I. Basic Green 4 (malachite green) 250 ppm

82-28-0 Disperse Orange 11 250 ppm Dyes Disperse (Sensitizing)

Disperse dyes have no applicability to leather processing. Fat liquoring agents

85535-84-8

Short-chain chlorinated paraffin (C10 C13)

No intentional use

250 ppm Short-chain chlorinated paraffins can be found as contaminants within long-chain chlorinated paraffins and sulfo-chlorinated paraffins, used as fat liquoring agents.

Gas chromatography/ electron capture negative

ion-mass spectrometry (GC/ECNI-MS)

EN ISO 18219

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CAS No. Substance


Supplier Guidance





Flame Retardants115-96-8 Tris(2-chloroethyl)phosphate (TCEP)

No intentional use

250 ppm

Flame retardant chemicals are rarely used to meet flammability requirements in childrens clothing and adult products, but they could be used in processing leather for technical/ industrial purposes (e.g., drive belts) and upholstery leather for trains and planes. The mentioned substances should no longer be used in apparel and footwear.

GC-MS

1163-19-5 Decabromodiphenyl ether (DecaBDE) 250 ppm 126-72-7 Tris(2,3,-dibromopropyl)-phosphate (TRIS) 250 ppm

32534-81-9 Pentabromodiphenyl ether (PentaBDE) 250 ppm 32536-52-0 Octabromodiphenyl ether (OctaBDE) 250 ppm 5412-25-9 Bis(2,3-dibromopropyl)phosphate (BIS) 250 ppm 545-55-1 Tris(1-aziridinyl)phosphine oxide) (TEPA) 250 ppm

59536-65-1 Polybromobiphenyls (PBB) 250 ppm 79-94-7 Tetrabromobisphenol A (TBBPA) 250 ppm

3194-55-6 Hexabromocyclodecane (HBCDD) 250 ppm 3296-90-0 2,2-bis(bromomethyl)-1,3-propanediol

(BBMP) 250 ppm

13674-87-8 Tris(1,3-dichloro-isopropyl) phosphate (TDCP) 250 ppm

Glycol Ethers 111-96-6 Bis(2-methoxyethyl)-ether

No intentional use

50 ppm In apparel and footwear, glycol ethers have a wide range of uses including as solvents for finishing/cleaning, printing agents and dissolving and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations). Some polar solvents (glycol ethers) are necessary for the use of water-based leather finishing systems.

The mentioned glycol ethers are classified as carcinogenic, mutagenic or reprotoxic substances and should not be used in processing leather.

High-performance liquid chromatography (HPLC), LC- MS

110-80-5 2-ethoxyethanol 50 ppm 111-15-9 2-ethoxyethyl acetate 50 ppm 110-71-4 Ethylene glycol dimethyl ether 50 ppm 109-86-4 2-methoxyethanol 50 ppm 110-49-6 2-methoxyethylacetate 50 ppm

112-49-2

Triethylene glycol dimethyl ether

50 ppm

70657-70-4 2-methoxypropylacetate 1000 ppm Halogenated Solvents

107-06-2 1,2-dichloroethane No intentional use

5 ppm In apparel and footwear, solvents are used as finishing/cleaning and printing agents, for dissolving and diluting fats, oils and adhesives (e.g., in degreasing or cleaning operations).

GC-MS 75-09-2 Methylene chloride 5 ppm

79-01-6 Trichloroethylene 40 ppm 127-18-4 Tetrachloroethylene 5 ppm

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Supplier Guidance





Organotin Compounds

Multiple

Dibutyltin (DBT)

No intentional use

20 ppm (*EXCEPTION* 100 ppm for

polyurethane based thickeners used at

ECS-001 9 version 9

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CAS No. Substance


Supplier Guidance





Perfluorinated and Polyfluorinated Chemicals (PFCs)Durable water, oil and stain repellent finishes and soil release finishes (fluorinated polymers) based on long-chain technology are banned from intentional use. Long-chain compounds according to the Organisation for Economic Co-operation and Development (OECD) definition (http://www.oecd.org/ehs/pfc/) are based on long-chain perfluorocarboxylic acids (C8 and higher) and on long-chain perfluoroalkyl sulfonates (C6 and higher).

The main contaminants of this technology include: Perfluoroalkyl sulfonates (PFSAs) with carbon chain lengths C6 and higher (e.g., PFOS, perfluorooctane sulfonate) Perfluorocarboxylic acids with carbon chain lengths C8 and higher (e.g., PFOA, perfluorooctanoic acid)

Multiple Perfluorooctane sulfonate (PFOS) and related substances

No intentional use Sum = 2 ppm PFOA and PFOS may be present as unintended

by-products in long-chain commercial water, oiland stain repellent agents. PFOA also may be in use for polymers like polytetrafluoroethylene (PTFE).

LC-MS

Multiple Perfluorooctanoic acid (PFOA) and related substances 2 ppm

Phthalates including all other esters of ortho-phthalic acid117-81-7 Di(ethylhexyl) phthalate (DEHP)

No intentional use

Sum of all phthalates = 250 ppm

Esters of ortho-phthalic acid (phthalates) are a class of organic compounds commonly added to plastics to increase flexibility. They are sometimes used to facilitate moulding of plastic by decreasing its melting temperature.

Polymeric coatings for leather finishing, dedusting agents in colourants, fat liquors and greases could be a source for phthalates in formulations for leather processing.

GC-MS

117-82-8 Bis(2-methoxyethyl) phthalate (DMEP)117-84-0 Di-n-octyl phthalate (DNOP)

26761-40-0 Di-iso-decyl phthalate (DIDP)28553-12-0 Di-isononyl phthalate (DINP)

84-75-3 Di-n-hexyl phthalate (DnHP)84-74-2 Dibutyl phthalate (DBP)85-68-7 Butyl benzyl phthalate (BBP)84-76-4 Dinonyl phthalate (DNP)84-66-2 Diethyl phthalate (DEP)

131-16-8 Di-n-propyl phthalate (DPRP)84-69-5 Di-isobutyl phthalate (DIBP)84-61-7 Di-cyclohexyl phthalate (DCHP)

27554-26-3 Di-iso-octyl phthalate (DIOP)68515-42-4 1,2-benzenedicarboxylic acid, di-C7-11-

branched and linearalkyl esters (DHNUP)

71888-89-6 1,2-benzenedicarboxylic acid,di-C6-8- branched alkyl esters,C7-rich (DIHP)

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CAS No. Substance


Supplier Guidance





Total Heavy MetalsListed metals are banned from intentional use in textile manufacturing/finishing. Additionally, residual traces of antimony, zinc, copper, nickel, tin, barium, cobalt, iron, manganese, selenium and silver in colourants are expected to comply with the Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers (ETAD) concentration limits (http://www.etad.com/).

7440-38-2

Arsenic (As)

No intentional use

50 ppm

Arsenic and its compounds can be used in somepreservatives, pesticides and defoliants for cotton. It is also associated with synthetic fibres, paints, inks, trims and plastics.

Arsenic is not a typical residue in leather chemicals.

Inductively coupled plasma- optical emission spectrometry (ICP-OES), atomic absorption spectroscopy (AAS)

Cr (III) Tanning agents can be monitored for Cr(VI)

EN ISO 17075 (Current Use)

ISO/DIS 19071 (Draft)

7440-43-9

Cadmium (Cd) 20 ppm (50 ppm for pigments)

Cadmium compounds are found in or used as: pigments (particularly red, orange, yellow and green), a stabiliser for PVC plastic and in fertilisers, biocides and paints (e.g., surface paints on zippers and buttons).

7439-97-6

Mercury (Hg)


Mercury compounds can be present in pesticides and can be found as contamination incaustic soda (NaOH). Mercury compounds may be used in paints (e.g., surface paints on zippersand buttons).

Mercury is not a typical residue in leather chemicals.

7439-92-1 Lead (Pb) 100 ppm

In apparel and footwear, lead may be associated with plastics, paints, inks, pigments and surface coatings.

18540-29-9

Chromium (VI)

10 ppm

The two-bath process for tanning using potassium dichromate (VI) is no longer used by the leather industry.

Potassium dichromate (VI) and other chromium (VI) compounds are banned and chromium (VI) residues in chromium (III) tanning agents are restricted.

ECS-001 9 version 9

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CAS No. Substance


Supplier Guidance





Volatile Organic Compounds (VOC) 71-43-2 Benzene

No intentional use

50 ppm These volatile organic compounds should not be used in textile and leather auxiliary chemical preparations. They are associated with solvent- based processes like solvent-based polyurethane coatings and glues/adhesives. They should not be used for any kind of facility cleaning or spot cleaning.

GC-MS 95-48-7 o-cresol 500 ppm

106-44-5 p-cresol 500 ppm

108-39-4 m-cresol 500 ppm

ECS-001 9 version 9

p.37

9. bluesign system substances list (BSSL) Consumer safety limits(Version 5.1 November 01 ,2015)

Aldehydes

Chemical Substances

CAS Number

Limit Value [mg/kg] Usage range

Recommended Sample Preparation //

Test Method A B C

Acrolein 107-02-8 Usage ban // Traces: 1.0 Extraction with MeOH // HPLC

Acetaldehyde 75-07-0 10 10 100 Extraction with MeOH // HPLC

Formaldehyde

50-00-0

DL: 15

75

300

Textile: ISO 14184-1 (2011)

Leather: ISO 17226-1 (2008) or ISO 17226-2 (2008)

Monitoring

Glyoxal

107-22-2

5 10 10 Extraction with MeOH // HPLC

Leather: Monitoring

Alkylphenols and Alkylphenolethoxylates

Chemical Substances

CAS Number Limit Value [mg/kg]

Usage range Recommended

Sample Preparation // Test Method A B C

Alkylphenols (APs) Several

Usage ban // Traces: 10 for every

single substance

2-Step extraction with DCM and MeOH/Acetonitrile // GC-MS, LC-MS

Nonylphenol, mixed isomers 25154-52-3

Isononylphenol 11066-49-2

4-Nonylphenol 104-40-5

4-Nonylphenol, branched 84852-15-3

Octylphenol 27193-28-8

4-Octylphenol 1806-26-4

4-tert-Octylphenol 140-66-9

Alkylphenolethoxylates (APEOs) (EO)3-20 Several

Usage ban // Traces: 100 for every

single substance

(If traces above 10 are

Textile: Draft ISO/DIS 18254 (2014)

Isononylphenol, ethoxylated 37205-87-1

Nonylphenol, branched, ethoxylated 68412-54-4

4-Nonylphenol, branched, ethoxylated 127087-87-0

Octylphenol, ethoxylated 9036-19-5

Octyl phenol ethoxylate, branched 9.5EO 68987-90-6

ECS-001 9 version 9

p.38

Polyoxyethylated octyl phenol

9002-93-1

detected; source of contamination has to

be identified and phased out)

Leather: ISO 18218-1 (2015)

Polyoxyethylated nonyl phenol

9016-45-9

Polyoxyethylated p-nonyl phenol

26027-38-3

4-(1,1,3,3-tetramethylbutyl)phenol, ethoxylated

-

Amines

Chemical Substances




2-Aminoethanol

141-43-5

10 10 100 Extraction with MeOH // GC-MS

Monitoring

Aminoethylethanolamine (AEEA) 111-41-1 Usage Ban Monitoring

Extraction with MeOH // GC-MS

Aniline 62-53-3 Monitoring Exreation with MeOH//GC-MS or HPLC

Fatty acid condensation products with AEEA which may cleave to AEEA

Several

Usage ban // DL: 10

Extraction with MeOH and derivatisation with acetylacetone/water // HPLC-MS

Dicyclohexylamine

101-83-7

500 500 500


Monitoring

Diethanolamine 111-42-2 10 10 10

Diethylenetriamine

111-40-0

1.0 10 50

Monitoring

Diphenylamine

122-39-4

100 100 100

Monitoring

Dipropylenetriamine

56-18-8

50 50 50

Monitoring

Ethylenediamine 107-15-3 10 50 50

Hexamethylenetetramine 100-97-0 10 50 50

N-Methylaniline (Methylphenylamine) 100-61-8 20 20 20

2-Naphthylphenylamine 135-88-6 Usage ban // DL: 1.0

p-Phenylenediamine 106-50-3 Usage ban // DL: 20

p-Phenylenediamine-dihydrochloride 624-18-0 Usage ban // DL: 20

Triethanolamine 102-71-6 50 100 100

Triethylamine 121-44-8 2.0 10 10

ECS-001 9 version 9

p.39

Trimethylamine 75-50-3 10 10 10

Arylamines (as substance, for example in PU, and as decomposition product of azo colorants which, by reductive cleavage of one or more azo groups, may release one or more of the aromatic amines)

Chemical Substances

CAS Number



Test Method A B C p-Aminoazobenzene 60-09-3

Usage ban // DL: 20 mg/kg for every single aromatic amine

Textile : EN 14362-1 (2012) EN 14362-3 (2012) (for azo colorants which may release 4- Aminoazobenzene)

Leather : EN ISO 17234-1 (2015) EN ISO 17234-2 (2011) (for azo colorants which may release 4- Aminoazobenzene)

o-Aminoazotoluene 97-56-3

4-Aminobiphenyl 92-67-1

6-Amino-2-ethoxynaphthalene 293733-21-8

4-Amino-3-fluorophenol 399-95-1

2-Amino-4-nitrotoluene 99-55-8

2-Anisidine 90-04-0

Benzidine 92-87-5

4-Chloroaniline 106-47-8

4-Chlor-2-toluidine 95-69-2

p-Cresidine 120-71-8

2,4-Diaminoanisole 615-05-4

4,4'-Diaminodiphenylmethane 101-77-9

2,4-Diaminotoluene 95-80-7

3,3'-Dichlorobenzidine 91-94-1

3,3'-Dimethoxybenzidine 119-90-4

4-Dimethylaminoazobenzene 60-11-7

3,3'-Dimethylbenzidine 119-93-7

3,3'-Dimethyl-4,4'-diaminodiphenylmethane 838-88-0

4,4'-Methylenebis-(2-chloroaniline) 101-14-4

2-Naphthylamine 91-59-8

4,4'-Oxydianiline 101-80-4

4,4'-Thiodianiline 139-65-1

2-Toluidine 95-53-4

2,4,5-Trimethylaniline 137-17-7

2,4-Xylidine 95-68-1

2,6-Xylidine 87-62-7

p-Toluidine 106-49-0

m-Toluidine 108-44-1

Asbestos

Chemical Substances

CAS Number Limit Value

[mg/kg] Recommended


ECS-001 9 version 9

p.40

Asbestos (Single substances listed in Annex I)

Several

Usage ban // Not detected

REM/EDX BGI 505-46 or U.S. EPA/600/R-93/116

Biocides Part 1

Chemical Substances

CAS Number



Test Method A B C

2-Chloroacetamide

79-07-2

Usage ban // DL: 1.0

Traces from a preservative in

auxiliaries. Currently acceptable: 10


Dichlorophen

97-23-4


Derivatisation with acetic anhydride // GC-MS

Chlorinated and non-chlorinated Isothiazolinone-derivatives

Several

Usage ban

Traces from preservatives in auxiliaries acceptable

Extraction with MeOH // HPLC

5-Chloro-2-methyl-4-isothiazolin-3-one (CIT) 26172-55-4 1

2-Methyl-4-isothiazolin-3-one (MIT) 2682-20-4 50

Mixture (3:1) of CIT and MIT 55965-84-9 See limits for single

substances

2-n-Octyl-4-isothiazolin-3-one (OIT) 26530-20-1 25

1,2-Benzoisothiazol-3(2H)-one (BIT) 2634-33-5 25

Dichlorooctylisothiazolinone 64359-81-5 15

N-Methylol-chloroacetamide

2832-19-1


Traces from a preservative in

auxiliaries. Currently acceptable: 10


Biocides Part 2

Chemical Substances

CAS Number



Test Method A B C

Permethrin

52645-53-1

Usage ban for A and B // DL: 0.2

Usage range C // See bluesign criteria for biocidal products and

antimicrobial active substances

ASE or Soxhlet Extraction with Acetone/Hexane // GC-MS or LC-MC

ECS-001 9 version 9

p.41

Triclosan (5-Chloro-2-(2,4-dichlorophenoxy)phenol)

3380-34-5

Usage ban for A and B // DL: 1.0

Usage range C // See bluesign criteria for biocidal products and

antimicrobial active substances

Extraction with DCM // GC-MS

Chlorinated Aromatic Hydrocarbons

Chemical Substances




Chlorinated aromatic hydrocarbons Several

Usage ban // DL: 1.0 for every single

substance

For sum of all chlorinated aromatic

hydrocarbons: 5.0

DIN 54232 (2010)

Monochlorobenzene 108-90-7

Dichlorobenzenes, all isomers Several

1,2-Dichlorobenzene 95-50-1



Trichlorobenzenes, all isomers Several

1,2,3-Trichlorobenzene 87-61-6



Tetrachlorobenzenes, all isomers Several

1,2,3,4-Tetrachlorobenzene 634-66-2



Pentachlorobenzene 608-93-5

Hexachlorobenzene 118-74-1

Monochlorotoluenes, all isomers Several

2-Chlorotoluene 95-49-8



Dichlorotoluenes, all isomers Several

2,4-Dichlorotoluene 95-73-8



Trichlorotoluenes, all isomers Several

2,3,6-Trichlorotoluene 2077-46-5

a,a,a-Trichlorotoluene 98-07-7

Tetrachlorotoluenes, all isomers Several

a,a,a,2-Tetrachlorotoluene 2136-89-2

a,a,a,4-Tetrachlorotoluene 5216-25-1

Pentachlorotoluene 877-11-2

ECS-001 9 version 9

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Chlorinated Phenols Part 1

Chemical Substances

CAS Number



Test Method A B C

Monochlorophenols (MonoCPs), all isomers

25167-80-0

Usage ban

Extraction with KOH* // GC-MS*

*In case of results close to limit value (+/- 10 %) re-test with reference method: 64 LFGB BVL B 82.02-8(2001) (for textiles) or ISO 17070(2015) (for leather)

Traces:

1 1 1

Sum of all Mono-and DiCPs

2-Chlorophenol 95-57-8 3-Chlorophenol 108-43-0 4-Chlorophenol 106-48-9

Dichlorophenols (DiCP), all isomers

25167-81-1

2,3-Dichlorophenol 576-24-9






Trichlorophenols (TriCP), all isomers

25167-82-2

Usage ban

Traces:

0.05 0.5 0.5

Sum of all TriCPs

2,3,4-Trichlorophenol 15950-66-0






Chlorinated Phenols Part 2

Chemical Substances

CAS Number



Test Method A B C

Tetrachlorophenol (TeCP), salts and compounds

25167-83-3

Usage ban

Extraction with KOH* // GC-MS*

*In case of results close to limit value (+/- 10 %) re-test with reference method: 64 LFGB BVL B 82.02-8(2001) (for textiles) or ISO 17070

Traces:

0.05 0.5 0.5

Sum of all TeCPs

2,3,4,5-Tetrachlorophenol 4901-51-3



Usage ban

ECS-001 9 version 9

p.43

Pentachlorophenol (PCP), salts, esters and compounds

87-86-5

Traces:

0.05 0.5 0.5

Sum of all PCPs

(2015) (for leather)

Colorants Colorants with carcinogenic potential

Chemical Substances

CAS Number



Test Method A B C

Acid Red 26 3761-53-3

Usage ban // DL: 20 for every single

substance

DIN 54231 (2005)

Basic Red 9 569-61-9

Basic Violet 14 632-99-5

Direct Black 38 1937-37-7

Direct Blue 6 2602-46-2

Direct Red 28 573-58-0

Direct Yellow 1 6472-91-9

Disperse Blue 1 2475-45-8

Disperse Orange 11 82-28-0

Disperse Yellow 3 2832-40-8

Pigment Black 25 68186-89-0

Pigment Yellow 34 1344-37-2

Pigment Yellow 157 68610-24-2

Pigment Red 104 12656-85-8

Colorants with allergenous potential

Chemical Substances







Disperse Blue 35 12222-75-2 56524-77-7




Disperse Brown 1 23355-64-8


ECS-001 9 version 9

p.44

Disperse Orange 3 730-40-5 Usage ban // DL: 20 for every single

substance

DIN 54231 (2005)

Disperse Orange 37/59/76 12223-33-5 13301-61-6

Disperse Red 1 2872-52-8







Solvent Yellow 14 842-07-9

Colorants banned for other reasons:

Chemical Substances




Acid Orange 24 1320-07-6


substance

DIN 54231 (2005)

Acid Violet 49 1694-09-3

Basic Blue 26 2580-56-5

Basic Green 4 Several

Malachit green 10309-95-2

Malachit green chloride 569-64-2

Malachit green oxalate 2437-29-8

Basic Violet 1 8004-87-3

Basic Violet 3

548-62-9 603-48-5 14426-25-6

Direct Black 91 6739-62-4

Direct Blue 76 16143-79-6

Direct Blue 218 28407-37-6



Navy Blue: A mixture of: disodium (6-(4- anisidino)-3-sulfonato-2-(3,5-dinitro-2- oxidophenylazo)-1-naphtholato)(1-(5-chloro-2- oxidophenylazo)-2-naphtholato)chromate(1-); trisodium bis(6-(4-anisidino)-3-sulfonato-2-(3,5- dinitro-2-oxidophenylazo)-1- naphtholato)chromate(1-)

Component 1: 118685-33-9

Component 2: Not allocated

Solvent Blue 4 6786-83-0

ECS-001 9 version 9

p.45

Colorants which can cleave in carcinogenic amines:

Chemical Substances




Colorants which can cleave in carcinogenic amines (Single substances listed in Annex I)

Several


substance

DIN 54231 (2005)

Dioxins and Furans

Chemical Substances




Group 1 (Single substances listed in Annex I)

Several Usage ban //

Sum of all traces group 1: 1 [g/kg]

EPA 8290A



Sum of all traces group 1 and 2: 5 [g/kg]


Several

Usage ban // Sum of all traces group 1, 2 and 3:

100 [g/kg]



Sum of all traces group 4: 1 [g/kg]



Sum of all traces group 4 and 5: 5 [g/kg]

Flame Retardants Part 1

Chemical Substances

CAS Number



Test Method A B C

2,2-Bis(bromomethyl)-1,3-propanediol 3296-90-0 Usage ban // DL: 5 Extraction following IEC 62321-6 (2015) // LC-MS, GC-MS, GC-NCI

Bis(2,3-dibromopropyl)phosphate 5412-25-9 Usage ban // DL: 5 Extraction following IEC 62321-6 (2015) // LC-MS, GC-MS, GC-NCI

Chlorinated paraffins, all chain lengths Several


Draft DIN EN ISO 18219 (2012)

Paraffin wax, chlorinated, C24 63449-39-8

Paraffin, C10-C13, chlorinated (SCCP) 85535-84-8

ECS-001 9 version 9

p.46

Paraffin, C14-C17, chlorinated (MCCP) 85535-85-9 substance

Paraffin, C18-C28, chlorinated (LCCP) 85535-86-0

Hexabromocyclododecan

25637-99-4 3194-55-6 134237-50-6 134237-51-7 134237-52-8

Usage ban for A and B // DL: 5

Technical textiles

currently reviewed.

See bluesign criteria for flame retardants

Extraction following IEC 62321-6 (2015) // LC-MS, GC-MS, GC-NCI

Polybrominated diphenyl ethers (PBDE) Several


substance


Tetrabromodiphenyl ether (TetraBDE) 40088-47-9

Pentabromodiphenyl ether (PentaBDE) 32534-81-9

Hexabromodiphenyl ether (HexaBDE) 36483-60-0

Heptabromodiphenyl ether (HeptaBDE) 68928-80-3

Octabromodiphenyl ether (OctaBDE) 32536-52-0

Decabromodiphenyl ether (DecaBDE) 1163-19-5

Tetrabromobisphenol A 79-94-7 Usage ban // DL: 5


Tetrabromobisphenol A bis(2,3- dibromopropylether)

21850-44-2 Usage ban // DL: 5

Triethylenephosphoramide (TEPA) 545-55-1 Usage ban // DL: 5

Flame Retardants Part 2

Chemical Substances

CAS Number



Test Method A B C

Trimethyl phosphate 512-56-1 Usage ban // DL: 5


Tri-o-cresyl phosphate 78-30-8 Usage ban // DL: 5

Tris(chloroethyl)phosphate 115-96-8 Usage ban // DL: 5

Tris-(2-chloro-1-methylethyl)phosphate (TCPP) 13674-84-5 Usage ban // DL: 5

Tris-[2-chloro-1-(chloromethyl)ethyl]phosphate (TDCP)

13674-87-8 Usage ban // DL: 5

Tris(2,3-dibromopropyl) phosphate (TRIS) 126-72-7 Usage ban // DL: 5

Trixylyl phosphate 25155-23-1 Usage ban // DL: 5

Fluorinated Substances Part 1

Chemical Substances

CAS Number



Test Method A B C

PFAS Chemicals*

ECS-001 9 version 9

p.47

Perfluoroalkylsulfonates (PASF) F(CF2)nSO3-

[n 5] Several

Usage ban // Traces: 20 [g/kg]

CEN/TS 15968 (2010)

Perluorohexane sulfonic acid / Perfluorohexane sulfonate (PFHxS)

355-46-4 / 432-50-7


Perfluorooctane sulfonic acid / Perfluorooctane sulfonate (PFOS)

1763-23-1 Usage ban //

Traces: 1 [g/m] Perfluoroalkylsulfonamides F(CF2)nSO2NH2 [n 5]


Traces: 20 [g/kg] Perfluoroalkylsulfonamidoethanols F(CF2)nSO2N(R)CH2CH2OH2 [n 5, R = H, -CH3, - CH2CH3]

Several


Perfluoroalkylsulfonamidoethyl (meth)acrylates F(CF2)nSO2N(R)CH2CH2OC(O)CH(R)=CH2 [n 5, R = H, -CH3, -CH2CH3]

Several

Usage ban // Traces. 20 [g/kg]

PFBS Chemicals

Perfluorobutane sulfonic acid / Perfluorobutanesulfonates (PFBS) F(CF2)4SO3-

29420-49-3 / 29420-43-3

1.0 mg/kg

Monitoring

CEN/TS 15968 (2010)

Perfluorobutanesulfonamide F(CF2)4SO2NH2

50 mg/kg Monitoring

Perfluorobutanesulfonamidoethanols F(CF2)4SO2N(R)CH2CH2OH2

[R = H, -CH3, -CH2CH3]

Several 15 mg/kg

Monitoring

Perfluorobutanesulfonamidoethyl (meth)acrylates

F(CF2)4SO2N(R)CH2CH2OC(O)CH(R)=CH2 [R = H, -CH3, -CH2CH3]

Several 15 mg/kg

Monitoring

Fluorotelomer alcohols (FTOHs) F(CF2)nCH2CH2OH

Several Sum of all 50 mg/kg

6:2 FTOH, Perfluorohexylethanol 647-42-7 Monitoring Extraction with MTBE // GC-MS

8:2 FTOH, Perfluorooctylethanol** 678-39-7 Monitoring

Fluorotelomer Olefins (FTOs) Several Sum of all 50 mg/kg

Perfluorohexylethene 25291-17-2 Monitoring ASE with Ethyl acetate // GC-MS or LC-MS Perfluorooctylethene** 21652-58-4 Monitoring

Fluorinated Substances Part 2

Chemical Substances

CAS Number



Test Method A B C

Fluorotelomer (Meth)Acrylates Several Sum of all 50 mg/kg

Perfluorohexylethylacrylate or methacrylate Several Monitoring

Extraction with MTBE // GC-MS Perfluorooctylethylacrylate or methacrylate** Several Monitoring

Perfluorocarboxylic acid and salts (PFCA) Several Sum of all 0.1 mg/kg

Perfluorobutanoic acid (PFBA)

375-22-4

Usage ban // Traces: 0.05 mg/kg

Monitoring

ECS-001 9 version 9

p.48

Perfluorohexanoic acid (PFHxA)

307-24-4


Monitoring

CEN/TS 15968 (2010)

Perfluorooctanoic acid (PFOA)**

335-67-1

Usage ban // Traces: 1 [g/m]

(corresponds to

0.01 mg/kg for textile weight of 100 g/m2)

Perfluorononanoic acid (PFNA)**

375-95-1


Monitoring

Perfluoroisobutylene 382-21-8 0.1 mg/kg Headspace GC-MS

Tetrafluoroethylene 116-14-3 1.0 mg/kg Headspace GC-MS

* Ban on long-chain compounds in manufacturing based on long-chain electrofluorination chemistry (C6 and higher). ** Phase-out of long-chain compounds in manufacturing based on long-chain telomer chemistry (C8 and higher) until end of 2014.

Glycols

Chemical Substances

CAS Number



Test Method A B C

Bis(2-methoxyethyl)-ether 111-96-6 Usage ban // DL: 5

Textile: Extraction with MeOH // GC-MS

Plastic: 2-Step extraction with THF and MeOH // GC-MS

2-Butoxyethanol 111-76-2 1.0 10 100

2-Butoxyethylacetate 112-07-2 10 100 100

2-Ethoxyethanol 110-80-5 Usage ban // DL: 5

2-Ethoxyethyl acetate 111-15-9 Usage ban // DL: 5

Ethylene glycol dimethyl ether 110-71-4 Usage ban // DL: 5

2-Methoxyethanol 109-86-4 Usage ban // DL: 5

2-Methoxyethylacetate 110-49-6 Usage ban // DL: 5

2-(2-Methoxyethoxy)-ethanol 111-77-3 1.0 10 100

1-Methoxy-2-propanol 107-98-2 1.0 5 10

2-Methoxy-1-propanol 1589-47-5 Usage ban // DL: 5

2-Methoxypropylacetate 70657-70-4 Usage ban // DL: 5

Triethylene glycol dimethyl ether 112-49-2 Usage ban // DL: 5

Greenhouse Gases, fluorinated

Chemical Substances




Greenhouse gases, fluorinated (Single substances listed in Annex I)

Several

Usage ban for direct use in manufacturing

of articles // DL: 0.1 for every single

substance

Headspace GC-MS

ECS-001 9 version 9

p.49

Halogenated Biphenyls, halogenated Terphenyls and halogenated Naphthalenes

Chemical Substances

CAS Number



Test Method A B C

Polybrominated biphenyls (PBBs) 59536-65-1 Usage ban // DL: 5

Extraction following IEC 62321-6 (2015) // GC-MS

Hexabromo biphenyl 36355-01-8 Usage ban // DL: 5

Polychlorinated biphenyls (PCBs) 1336-36-3 Usage ban // DL: 1.0

Polychlorinated terphenyls (PCTs) 61788-33-8 Usage ban // DL: 1.0

Polybrominated terphenyls (PBTs) Several Usage ban // DL: 1.0

Polychlorinated naphthalenes (PCNs) Several

Monochloronaphthalene 25586-43-0

Usage ban // DL: 1.0 for every single substance

Dichloronaphthalene 28699-88-9

Trichloronaphthalene 1321-65-9

Tetrachloronaphthalene 1335-88-2

Pentachloronaphthalene 1321-64-8

Hexachloronaphthalene 1335-87-1

Heptachloronaphthalene 32241-08-0

Octachloronaphthalene 2234-13-1

Polybrominated naphthalenes (PBNs) Several Usage ban // DL: 1.0

Halogenated Diarylalkanes

Chemical Substances




Halogenated diarylalkanes Several

Usage ban // DL: 1.0 for every single

substance

Extraction following IEC 62321-6 (2015) // GC-MS

Monomethyl-dibromo-diphenyl methane 99688-47-8

Monomethyl-dichloro-diphenyl methane 81161-70-8

Monomethyl-tetrachloro-diphenyl methane 76253-60-6

Isocyanates

Chemical Substances

CAS Number



Test Method A B C

Isocyanates Several

Diphenylmethane-4,4-di-isocyanate (MDI) 101-68-8

Diphenylmethan-2,2-di-isocyanate (2,2-MDI) 2536-05-2

Diphenylmethan-2,4-di-isocyanate (2,4-MDI) 5873-54-1

ECS-001 9 version 9

p.50

MDI mixed isomers 26447-40-5

Free content applies to sum of all isocyanates:

1.0 1.0 1.0

PU coating and plastics: Monitoring

EN 13130-8 (2004)

Technical grade MDI 9016-87-9

Hexamethylene diisocyanate (HMDI) 822-06-0

Isophorone diisocyanate (IPDI) 4098-71-9

Tetramethylxylene diisocyanate (TMXDI) 2778-42-9

Toluene-2,4-diisocyanate (2,4-TDI) 584-84-9

Toluene-2,6-diisocyanate (2,6-TDI) 91-08-7

2,4-/2,6-TDI mixture 26471-62-5

2,6-Diisopropylphenyl-isocyanate 28178-42-9

4,4-Methylendicyclohexyl-di-isocyanate (4,4-MDI)

5124-30-1

Napthylene-1,5-di-isocyanate (1,5-NDI) 3173-72-6

Phenylisocyanate 103-71-9

Metals Part 1

Chemical Substances

CAS Number



Test Method A B C

Antimony

7440-36-0

Usage as flame retardant: bluesign criteria for flame

retardants have to be followed

In other cases:

Polyester raw fibre:

原材料管制物質規範 - ecic.com v9.pdf · 化學文摘編號 cas no. 管制標準 criteria 1...

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